摘要:
The invention relates to ultrasensitive bioanalytical assays based on the use of high-gain catalytic chemical amplification methods. The ultrasensitive bioanalytical assays of the invention utilize high gain catalytic chemical amplification methods to detect the presence and to quantify the concentrations of target analytes labeled with specific binding reagents or biomarkers comprising a catalyst or a catalyst precursor.
摘要:
An element for making patterns on an electroconductive substrate, the element comprising a support, on which is disposed: a) a conductive layer containing an electrically conductive polymer, a polyanion and a conductivity enhancing agent; and b) a mixing layer containing a thermally mobile material; wherein, upon imagewise heating the mixing layer, the thermally mobile material mixes with the conductive layer, thereby causing the initial surface resistivity (SR) of the conductive layer to imagewise increase from an initial value SRi, which is lower than 105 Ω/square, to SRiΔ, Δ being at least 102.
摘要:
Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n (II) Pd(X2)2[Te(R′)2]2 (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.
摘要:
A thermally imageable element can be imaged using heat alone without the need for photosensitivity or post-imaging processing. The element contains image-forming chemistry that comprises i) image precursor chemistry and ii) a catalyst or a catalyst precursor that upon imagewise heating is capable of promoting thermally induced image formation with the image precursor chemistry. The image-forming chemistry i) and ii) components are in reactive association and uniformly dispersed or dissolved within a binder in one or more layers of the element. Thus, the element is capable of being thermally addressed to provide a visible image as a result of thermally induced catalytic transformation of the image-forming chemistry.
摘要:
An imagewise polarizable imaging member can be used to print the same or different images with an electrically responsive marking media. The imaging member includes a matrix-addressable microelectronic layer in proximate relationship with an imagewise polarizable ferroelectric layer. Imaging is accomplished by forming an imagewise electrical pattern in the ferroelectric layer using signals from the matrix-addressable microelectronic layer, and applying the electrically responsive marking media to the electrically polarized ferroelectric layer, creating thereon an identifiable image pattern. The marking media can then be transferred to a suitable receiver material to form the desired printed image.
摘要:
Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer produced by coating a layer comprised of a metallo-organic compound and a film-forming binder and subjecting such layer to glow discharge treatment to render it electrically conductive. Use of a metallo-organic compound in combination with a glow discharge treatment provides a controlled degree of electrical conductivity and beneficial chemical, physical and optical properties which adapt the electrically-conductive layer for such purposes as providing protection against static or serving as an electrode which takes part in an image-forming process.
摘要:
A dye-forming electrothermographic element comprises an electrically activatable recording layer comprising (a) a reducing agent or reducing agent precursor capable of being activated by a Lewis base; (b) a cobalt(III) Lewis base complex; and (c) at least one of (i) a reducible dye-forming compound that has an oxidation state above that of the conjugate dye, (ii) a dye capable of changing its wavelength of absorption by reaction with a Lewis base, and (iii) a dye-forming coupler capable of reacting with the oxidized form of the reducing agent in (a) to form a dye. A negative or positive dye image is formed in such a dye-forming electrothermographic element by applying an electrical potential imagewise to the element of a magnitude and for a time sufficient to produce in the image areas a charge density sufficient to produce a latent image; and, then, heating the element to a temperature and for a time sufficient to form a dye image in the element. The dye-forming electrothermographic element can be a multicolor, multilayer electrothermographic element.
摘要:
In an electrically activatable recording element and process comprising a polymeric electrically active conductive layer improvements are provided wherein the polymeric electrically active conductive layer comprises a polymer that has recurring units represented by the structure: ##STR1## wherein R is hydrogen or alkyl containing 1 to 20 carbon atoms;R.sup.1 and R.sup.3 are individually hydrogen or methyl;R.sup.2 is alkyl containing 2 to 20 carbon atoms;x is 0 or 1;y is 0 to 4;R.sup.4 is C.sub.6 H.sub.5-z X.sub.z ; wherein z is 1 to 5;X is chlorine, bromine or iodine;n is 40 to 100 weight percent;and the polymer has a glass transition temperature within the range of 20.degree. C. to 40.degree. C.Such a polymeric electrically active conductive layer is useful in, for example, an electrically activatable recording element comprising an electrically conductive support having thereon, in sequence:(a) a polymeric electrically active conductive layer, as described,(b) an electrically activatable recording layer comprising:(A) a dye-forming coupler, and(B) an oxidation-reduction combination comprising:(i) an organic silver salt oxidizing agent consisting essentially of a silver salt of a 1,2,4-mercaptotriazole derivative with(ii) a reducing agent which, in its oxidized form, forms a dye with said dye-forming coupler,(c) a photoconductive layer separated from (b) by an air gap of up to 20 microns or separated from (b) by an electrically conductive interlayer, and(d) an electrically conductive layer.The recording element is light handleable and provides a dye image and silver image by dry development processing.
摘要:
In an electrically activatable recording element, such as one comprising an electrically conductive support having thereon, in sequence: (a) a polymeric electrically active conductive (EAC) layer, (b) an electrically activatable recording layer comprising (A) a dye-forming coupler, and (B) an oxidation-reduction combination comprising (i) an organic silver salt oxidizing agent consisting essentially of a silver salt of a 1,2,4-mercaptotriazole derivative, with (ii) a reducing agent which, in its oxidized form, forms a dye with the dye-forming coupler, (c) a photoconductive layer separated from (b) by an air gap of up to 20 microns, and (d) an electrically conductive layer; improvements are provided by means of a polymeric EAC layer (a) consisting essentially of a vinyl addition polymer, such as poly(methyl acrylate-co-vinylidene chloride). The recording element is room light handleable and provides a dye image and silver image by dry development processing.
摘要:
A non-silver, charge-sensitive recording composite element having an ohmic resistivity of at least about 1.times.10.sup.10 ohm-cm comprising (a) a first electrically conducting layer in association with (b) a photoconductor layer, (c) a non-silver, electrically activated recording layer comprising an image-forming combination of (i) a certain tellurium (II) coordination complex with (ii) a reducing agent, and a binder and (d) a second electrical conducting layer can provide a non-silver image having a density equal to silver images. Silica, especially colloidal silica, is also very useful in the recording layer. The recording element can be room light handleable and can provide a developed image by dry development processes.