Blend functionalized polyolefin adhesive
    31.
    发明授权
    Blend functionalized polyolefin adhesive 有权
    混合功能化聚烯烃粘合剂

    公开(公告)号:US07541402B2

    公开(公告)日:2009-06-02

    申请号:US10825635

    申请日:2004-04-15

    IPC分类号: C08L51/00

    摘要: Disclosed herein is an adhesive composition comprising a blend functionalized with a functional group, wherein the blend comprises a C3 to C40 olefin polymer and an additive, the C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the C3 to C40 olefin polymer has: a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of 10,000 to 100,000; and a branching index (g′) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index (g′) of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000. A process of producing the adhesive composition, as well as methods of utilizing the adhesive composition are also disclosed.

    摘要翻译: 本文公开了一种粘合剂组合物,其包含用官能团官能化的共混物,其中所述共混物包含C 3至C 40烯烃聚合物和添加剂,所述C 3至C 40烯烃聚合物包含至少50摩尔%的一种或多种C 3至C 40烯烃, 并且其中C3至C40烯烃聚合物具有:在牛皮纸上具有1牛顿或更多的点T皮; 10,000至100,000的Mw; 以及当聚合物的Mw为10,000至60,000时聚合物的Mz测量的支化指数(g')为0.98或更小,或在聚合物的Mz下测量的支化指数(g')为0.95或更低 该聚合物的Mw为10,000至100,000。 还公开了制备粘合剂组合物的方法以及使用粘合剂组合物的方法。

    Polymer production at supercritical conditions

    公开(公告)号:US20060025545A1

    公开(公告)日:2006-02-02

    申请号:US11177004

    申请日:2005-07-08

    IPC分类号: C08F2/00

    摘要: This invention relates to a process to polymerize olefins comprising contacting, in a polymerization system, olefins having three or more carbon atoms with a catalyst compound, activator, optionally comonomer, and optionally diluent or solvent, at a temperature above the cloud point temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system, where the polymerization system comprises any comonomer present, any diluent or solvent present, the polymer product, where the olefins having three or more carbon atoms are present at 40 weight % or more, wherein the metallocene catalyst compound is represented by the formula: where M is a transition metal selected from group 4 of the periodic table; each R1 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and functional group, and any two R1 groups may be linked, provided that if the two R1 groups are linked, then they do not form a butadiene group when M is Zr; each R2 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and two or more R2 groups may be linked together to form an aliphatic or aromatic ring; R3 is carbon or silicon; R4 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; a is 0, 1, or 2; R5 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, R4 and R5 may be bound together to form a ring, and R5 and R3 may be bound together to form a ring; b is 0, 1, or 2; R6 is carbon or silicon; and R4 and R6 may be bound together to form a ring; each R7 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and a functional group; each R8 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and a functional group, and R7 and R8 may be linked together to form an aliphatic or aromatic ring; each R9 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and a functional group, and two R9 groups may be linked together to form a ring, R9 and R8 may be linked together to form a ring, R9 and R16 may be linked together to form a ring, R9 and R11 may be linked together to form a ring; c is 0, 1 or 2; R10 is -M2(R16)h- where M2 is B, Al, N, P, Si or Ge, h is an integer from 1 to 2, such that the valence of M2 is filled, and R16 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and two R16 groups may be linked together to form a ring; d is 0, 1, or 2; each R11 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and a functional group, and two R11 groups may be linked together to form a ring. R11 and R8 may be linked together to form a ring. R11 and R16 may be linked together to form a ring; e is 0, 1, or 2; where the sum of c, d, and e is 1, 2 or 3; R12 is carbon or silicon; R13 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and R13 and R14 may be bound together to form a ring, and R13 and R15 may be bound together to form a ring, when g is 0; f is 0, 1, or 2; R14 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and R14 and R12 may be bound together to form a ring, when f is 0; g is 0, 1, or 2; and R15 is carbon or silicon.

    Polyoelfin films having increased gas permeability and method for making
    39.
    发明授权
    Polyoelfin films having increased gas permeability and method for making 失效
    具有增加的透气性和制备方法的多孔菲林膜

    公开(公告)号:US5958319A

    公开(公告)日:1999-09-28

    申请号:US686042

    申请日:1996-07-24

    申请人: Patrick Brant

    发明人: Patrick Brant

    IPC分类号: C08J5/18 C08L23/08 B29C35/02

    摘要: Films, made of polyethylenes, and articles made therefrom exhibit, for a given density, improved oxygen transmission. The polyethylenes are produced in a metallocene-catalyzed production process. The films may be made by a cast film process, and may be made under conditions that raise the birefringence and the oxygen transmission rate of the film, such as increasing strain rate decreasing melt temperature, increasing quench rates, or may be post-extrusion treated, for instance annealed or cold drawn. Combinations of both extrusion techniques and post-extrusion techniques may also be used. Polyethylenes utilized for making such films typically have a Composition Distribution Breadth Index above 50%, a M.sub.w /M.sub.n below 3, and a M.sub.z /M.sub.w below 2. The permeability of the films so made will be 50% or more above the permeability of films based on similar resins based on previously used film formation techniques.

    摘要翻译: 由聚乙烯制成的薄膜以及由此制成的制品对于给定的密度显示出改进的氧气透过性。 聚乙烯在金属茂催化的生产过程中制备。 膜可以通过流延膜制备,并且可以在提高膜的双折射和氧气透过速率的条件下制备,例如增加应变速率降低熔融温度,提高淬火速率,或者可以是后挤出处理 ,例如退火或冷拉。 也可以使用挤出技术和挤出后技术的组合。 用于制造这种膜的聚乙烯通常具有高于50%的组分分布宽度指数,Mw / Mn低于3,Mz / Mw低于2。所制成的膜的渗透性将比膜的渗透率高50%或更高 基于基于先前使用的成膜技术的类似树脂。