Method for preparing lithium manganese spinel oxide having improved electrochemical performance
    33.
    发明授权
    Method for preparing lithium manganese spinel oxide having improved electrochemical performance 有权
    制备具有改善的电化学性能的锂锰尖晶石氧化物的方法

    公开(公告)号:US06929788B2

    公开(公告)日:2005-08-16

    申请号:US09913428

    申请日:2000-12-15

    摘要: The present invention relates to a method for preparing a lithium manganese complex oxide Li1+xMn2−xO4 (0≦x≦0.12) used as a cathode active material of a lithium or lithium ion secondary battery.The present invention provides a method for preparing a manganese compound comprising the step of simultaneously applying a mechanical force and heat energy to a manganese compound to remove defects present in particles of the manganese compound and to control the aggregation of particles and the shape of the aggregated particles, a method for preparing a lithium manganese complex oxide with a spinel structure using the manganese compound prepared by the above method as a raw material, and a lithium or lithium ion secondary battery using the lithium manganese complex oxide with a spinel structure prepared by the above method as a cathode active material.A lithium or lithium ion secondary battery using the lithium manganese complex oxide with a spinel structure prepared from the manganese compound without defects inside particles as a cathode active material has excellent charge/discharge characteristics and cyclic performance.

    摘要翻译: 本发明涉及一种锂锰复合氧化物Li 1 + x 2 O 2-x O 4(0≤x≤0.4)的制备方法, <= 0.12)用作锂或锂离子二次电池的正极活性物质。 本发明提供一种锰化合物的制备方法,包括同时向锰化合物施加机械力和热能以除去锰化合物颗粒中存在的缺陷并控制颗粒的聚集和聚集的形状的步骤 颗粒,使用通过上述方法制备的锰化合物作为原料制备具有尖晶石结构的锂锰复合氧化物的方法,以及使用具有尖晶石结构的锂锰复合氧化物的锂或锂离子二次电池,其由尖晶石结构 作为阴极活性物质。 使用由锰化合物制备的具有尖晶石结构的锂锰复合氧化物的锂或锂离子二次电池在颗粒内没有缺陷作为正极活性材料具有优异的充电/放电特性和循环性能。

    Additive for electrochemical element to improve safety
    34.
    发明授权
    Additive for electrochemical element to improve safety 有权
    电化学元素添加剂提高安全性

    公开(公告)号:US09225036B2

    公开(公告)日:2015-12-29

    申请号:US12843471

    申请日:2010-07-26

    摘要: Disclosed herein is an additive for improvement in safety of an electrochemical device, including an inner core and an outer coating layer, wherein the inner core is formed using a volume-expandable material fused at more than a predetermined temperature while the outer coating layer is formed using a conductive material with higher conductivity than that of the inner core and covers an outer face of the inner core. The disclosed additive rapidly increases resistance of the electrochemical device before ignition/explosion of the device caused by temperature rise, thereby effectively preventing ignition/explosion of the electrochemical device without deterioration in performance of the electrochemical device.

    摘要翻译: 本文公开了一种用于改进电化学装置的安全性的添加剂,其包括内芯和外涂层,其中内芯使用在大于预定温度下熔化的体积可膨胀材料形成,同时外涂层形成 使用导电性高于内芯导电性的导电材料,并覆盖内芯的外表面。 所公开的添加剂在由温度升高引起的装置点火/爆炸之前快速增加电化学装置的电阻,从而有效地防止电化学装置的点火/爆炸,而不会使电化学装置的性能下降。

    Battery system containing phase change material-containing capsules in interior configuration thereof
    36.
    发明授权
    Battery system containing phase change material-containing capsules in interior configuration thereof 有权
    含有相变材料的胶囊的内部结构的电池系统

    公开(公告)号:US08758925B2

    公开(公告)日:2014-06-24

    申请号:US13369480

    申请日:2012-02-09

    IPC分类号: H01M10/50

    摘要: Provided is a battery system in which an interior part of a battery structure includes phase-change particles including a capsule and phase-change materials. The phase-change materials have a high latent heat of phase change at a specific temperature, and are encapsulated in the capsule. The capsule is made of an inert material. The battery system in accordance with the present invention can prolong a service life of the battery by inhibiting temperature elevation inside the battery under normal operating conditions without substantial effects on size, shape and performance of the battery, and further, can inhibit the risk of explosion resulting from a sharp increase in temperature inside the battery under abnormal operating conditions, thereby contributing to battery safety.

    摘要翻译: 提供一种电池系统,其中电池结构的内部包括包括胶囊和相变材料的相变颗粒。 相变材料在特定温度下具有高的相变潜热,并且被封装在胶囊中。 胶囊由惰性材料制成。 根据本发明的电池系统可以通过在正常操作条件下抑制电池内的温度升高而延长电池的使用寿命,而不会对电池的尺寸,形状和性能产生实质影响,并且还可以抑制爆炸的风险 这是由于在异常操作条件下电池内部的温度急剧升高,从而有助于电池安全。

    Method of preparing material for lithium secondary battery of high performance
    38.
    发明授权
    Method of preparing material for lithium secondary battery of high performance 有权
    高性能锂二次电池材料的制备方法

    公开(公告)号:US08540961B2

    公开(公告)日:2013-09-24

    申请号:US12914142

    申请日:2010-10-28

    IPC分类号: C01G15/00

    摘要: Provided is a method for preparing a lithium mixed transition metal oxide, comprising subjecting Li2CO3 and a mixed transition metal precursor to a solid-state reaction under an oxygen-deficient atmosphere with an oxygen concentration of 10 to 50% to thereby prepare a powdered lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 wherein M, x and y are as defined in the specification. Therefore, since the high-Ni lithium mixed transition metal oxide having a given composition can be prepared by a simple solid-state reaction in air, using a raw material that is cheap and easy to handle, the present invention enables industrial-scale production of the lithium mixed transition metal oxide with significantly decreased production costs and high production efficiency. Further, the thus-produced lithium mixed transition metal oxide is substantially free of impurities, and therefore can exert a high capacity and excellent cycle stability, in conjunction with significantly improved storage stability and high-temperature stability.

    摘要翻译: 提供一种制备锂混合过渡金属氧化物的方法,包括在氧气浓度为10至50%的氧缺乏气氛下使Li 2 CO 3和混合过渡金属前体进行固态反应,从而制备混合的粉末状锂 具有由式I表示的组合物的过渡金属氧化物,其中M,x和y如说明书中所定义。 因此,由于具有给定组成的高Ni锂混合过渡金属氧化物可以通过在空气中简单的固态反应来制备,使用廉价且易于处理的原料,本发明使得能够工业规模生产 锂混合过渡金属氧化物的生产成本显着降低,生产效率高。 此外,这样制造的锂混合过渡金属氧化物基本上不含杂质,因此可以发挥高容量和优异的循环稳定性,同时显着提高储存稳定性和高温稳定性。

    Cathode active material for lithium secondary battery
    39.
    发明授权
    Cathode active material for lithium secondary battery 有权
    锂二次电池用阴极活性物质

    公开(公告)号:US08497039B2

    公开(公告)日:2013-07-30

    申请号:US13050730

    申请日:2011-03-17

    摘要: Provided is a cathode active material which is lithium transition metal oxide having an α-NaFeO2 layered crystal structure, wherein the transition metal is a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is more than +3, and lithium transition metal oxide satisfies the Equation m(Ni)≧m(Mn) (in which m (Ni) and m (Mn) represent an molar number of manganese and nickel, respectively). The lithium transition metal oxide has a uniform and stable layered structure through control of oxidation number of transition metals to a level higher than +3, thus advantageously exerting improved overall electrochemical properties including electric capacity, in particular, superior high-rate charge/discharge characteristics.

    摘要翻译: 提供了具有α-NaFeO 2层状晶体结构的锂过渡金属氧化物的正极活性物质,其中过渡金属是Ni和Mn的共混物,除锂之外的过渡金属的平均氧化数大于+3,并且 锂过渡金属氧化物满足公式m(Ni)> = m(Mn)(其中m(Ni)和m(Mn)分别表示锰和镍的摩尔数)。 锂过渡金属氧化物通过将过渡金属的氧化数控制到高于+ 3的水平,具有均匀且稳定的层状结构,因此有利地实现包括电容在内的改进的整体电化学性质,特别是优异的高速率充电/放电特性 。

    Cathode active material for lithium secondary battery
    40.
    发明授权
    Cathode active material for lithium secondary battery 有权
    锂二次电池用阴极活性物质

    公开(公告)号:US08277980B2

    公开(公告)日:2012-10-02

    申请号:US12833518

    申请日:2010-07-09

    摘要: Provided is a cathode active material which is lithium transition metal oxide having an α-NaFeO2 layered crystal structure, wherein the transition metal is a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is +3 or higher, and lithium transition metal oxide satisfies the Equation m(Ni)≧m(Mn) (in which m (Ni) and m (Mn) represent an molar number of manganese and nickel, respectively). The lithium transition metal oxide has a uniform and stable layered structure through control of oxidation number of transition metals to a level higher than +3, thus advantageously exerting improved overall electrochemical properties including electric capacity, in particular, superior high-rate charge/discharge characteristics.

    摘要翻译: 本发明提供一种正极活性物质,其为具有α-NaFeO 2层状结晶结构的锂过渡金属氧化物,其中,过渡金属为Ni和Mn的混合物,除锂以外的过渡金属的平均氧化数为+3以上, 锂过渡金属氧化物满足方程m(Ni)≥m(Mn)(其中m(Ni)和m(Mn)分别表示锰和镍的摩尔数)。 锂过渡金属氧化物通过将过渡金属的氧化数控制到高于+ 3的水平,具有均匀且稳定的层状结构,因此有利地实现包括电容在内的改进的整体电化学性质,特别是优异的高速率充电/放电特性 。