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    Gasoline upgrading process
    31.
    发明授权
    Gasoline upgrading process 失效
    汽油升级过程

    公开(公告)号：US5407559A

    公开(公告)日：1995-04-18

    申请号：US891248

    申请日：1992-06-01

    申请人： Thomas F. Degnan ,  Stuart S. Shih

    发明人： Thomas F. Degnan ,  Stuart S. Shih

    IPC分类号： C10G35/095 ,  C10G53/16 ,  C10G67/00 ,  C10G67/16 ,  C10G69/08 ,  C10G69/02

    CPC分类号： C10G35/095 ,  C10G53/16 ,  C10G67/00 ,  C10G67/16 ,  C10G69/08 ,  C10G2300/70

    摘要： A process is provided for producing low sulfur gasoline of relatively high octane number from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst comprising crystals having the structure of ZSM-12. The treatment over the acidic catalyst comprising ZSM-12 in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained.

    摘要翻译： 提供了一种通过加氢脱硫从催化裂解的含硫石脑油生产具有相对高辛烷值的低硫汽油的方法，然后在包含具有ZSM-12结构的晶体的酸性催化剂上进行处理。 在第二步骤中包含ZSM-12的酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失，并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。 在有利的情况下，使用延伸终点的原料如重质石脑油，高于约380°F（约193℃）为95％，可以获得相对于进料的产品辛烷值和产率的改善。

    Method for manufacturing synthetic mesoporous crystalline material
    33.
    发明授权
    Method for manufacturing synthetic mesoporous crystalline material 失效
    制造合成介孔结晶材料的方法

    公开(公告)号：US5156828A

    公开(公告)日：1992-10-20

    申请号：US732516

    申请日：1991-07-18

    申请人： Thomas F. Degnan ,  Ivy D. Johnson ,  Kathleen M. Keville

    发明人： Thomas F. Degnan ,  Ivy D. Johnson ,  Kathleen M. Keville

    IPC分类号： B01J29/04 ,  B01J29/70 ,  C01B37/00 ,  C01B37/02 ,  C01B39/00

    CPC分类号： C01B37/02 ,  B01J29/04 ,  B01J29/70 ,  C01B37/00 ,  C01B39/00 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42

    摘要： This invention relates to a method for synthesizing an ultra-large pore crystalline material and the use of such crystalline material as a sorbent and in catalytic conversion of organic and inorganic compounds. The synthesis method includes hydrothermally treating the as-synthesized crystalline material in the presence or absence of a binder. In a preferred embodiment, the crystalline material contains organic directing agent and is composited in an alumina binder. The crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units.

    摘要翻译： 本发明涉及一种用于合成超大孔结晶材料的方法以及这种结晶材料作为吸附剂的用途以及催化转化有机和无机化合物。 合成方法包括在存在或不存在粘合剂的情况下水解处理合成的结晶材料。 在优选的实施方案中，结晶材料含有有机导向剂并且在氧化铝粘合剂中复合。 结晶物质表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克/ 100克，六方形电子衍射图可用d100值大于约18 埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。

    Hydrocracking process
    35.
    发明授权
    Hydrocracking process 失效
    加氢裂化过程

    公开(公告)号：US4902392A

    公开(公告)日：1990-02-20

    申请号：US139545

    申请日：1987-12-30

    申请人： Brent A. Aufdembrink ,  Thomas F. Degnan ,  Richard F. Socha ,  Michael R. Stapleton

    发明人： Brent A. Aufdembrink ,  Thomas F. Degnan ,  Richard F. Socha ,  Michael R. Stapleton

    IPC分类号： C10G47/12 ,  C10G47/16

    CPC分类号： C10G47/12 ,  C10G47/16

    摘要： A catalytic hydrocracking process for use in refining various petroleum based feedstocks to lighter hydrocarbons. The hydrocracking process for treatment of petroleum fractions utilizes a catalyst comprising (a) a layered metal oxide of the titanometallate type intercalated with an interspathic polymeric chalcogenide, e.g., polymeric silica, (b) a transition hydrogenation metal selected from Group IVA, VIA, and VIIIA of the Periodic Table such as platinum and the like, and optionally, (c) a conventional cracking component, e.g., a large pore crystalline silicate component.

    摘要翻译： 用于将各种石油基原料精炼成轻质烃的催化加氢裂化方法。 用于处理石油馏分的加氢裂化方法使用催化剂，其包含（a）层状金属螯合物层状金属氧化物，其中嵌入有层状聚合硫族化物，例如聚合二氧化硅，（b）选自IVA族，VIA族和 周期表的VIIIA，例如铂等，和任选地，（c）常规的裂化组分，例如大孔结晶硅酸盐组分。

    Production of high viscosity index lubricants
    38.
    发明授权
    Production of high viscosity index lubricants 有权
    生产高粘度指数润滑剂

    公开(公告)号：US06231749B1

    公开(公告)日：2001-05-15

    申请号：US09439665

    申请日：1999-11-15

    申请人： Thomas F. Degnan ,  Robert T. Hanlon ,  Grant G. Karsner ,  Dominick N. Mazzone

    发明人： Thomas F. Degnan ,  Robert T. Hanlon ,  Grant G. Karsner ,  Dominick N. Mazzone

    IPC分类号： C10G7302

    CPC分类号： C10G65/12 ,  C10G2400/10

    摘要： Petroleum wax feeds are converted to high viscosity index lubricants by a two-step hydrocracking-hydroisomerization process in which the wax feed which exhibits branchingis initially subjected to hydrocracking under mild conditions with a conversion to non-lube range products of no more than about 30 weight percent of the feed. The hydrocracking is carried out at a hydrogen pressure of at least 1000 psig (7000 kPa) using an amorphous catalyst which preferentially removes the aromatic components present in the initial feed. The hydrocracked effluent is then subjected to hydroisomerization in a second step using a low acidity zeolite beta catalyst which effects a preferential isomerization on the paraffin components to less waxy, high VI isoparaffins. The second stage may be operated at high pressure by cascading the first stage product into the second stage or at a lower pressure, typically from 200 to 1000 psig. The second stage catalyst is preferably a noble metal containing zeolite beta catalyst which contains boron as a framework component of the zeolite to give a low alpha value, typically below 10 while maintaining an isomerizaiton selectiveity of no less than 48%. The second stage is carried out at relatively low temperature, typically from 600° to 650° F. with a 650° F.+ conversion in the range of 10 to 20 weight percent of the second stage feed but with high selectivity for isomerization of the paraffins. A final dewaxing step to target pour point may be used with relatively low loss, typically no more than 15 weight percent, during this dewaxing. The final products typically have VI values in excess of 140 and usually in the range of 143 to 147 and are characterized by exceptional stability.

    摘要翻译： 石油蜡进料通过两步加氢裂化 - 加氢异构化方法转化为高粘度指数润滑剂，其中显示支化的蜡进料在温和条件下最初进行加氢裂化，转化为不超过约30重量％的非润滑范围的产物 百分比的饲料。 使用优先除去初始进料中存在的芳香族成分的无定形催化剂，在至少1000psig（7000kPa）的氢气压力下进行加氢裂化。 然后使用低酸性沸石β催化剂在第二步骤中对加氢裂化的流出物进行加氢异构化，该催化剂对链烷烃组分进行优先异构化，以减少蜡状，高VI异链烷烃。 第二阶段可以通过将第一阶段产品级联到第二阶段或通常为200至1000psig的较低压力下在高压下操作。 第二级催化剂优选是含有沸石β催化剂的贵金属，其含有硼作为沸石的骨架组分，以产生低α值，通常低于10，同时维持不小于48％的异构选择性。 第二阶段在相对较低的温度下进行，通常为600°F至650°F，650°F +转化率在第二级进料的10至20％（重量）范围内，但对于 石蜡 在该脱蜡过程中，目标倾点的最终脱蜡步骤可以使用相当低的损失，通常不超过15重量％。 最终产品通常具有超过140的VI值，通常在143至147的范围内，并且具有出色的稳定性。

    Hydrogenation process
    39.
    发明授权
    Hydrogenation process 失效
    氢化过程

    公开(公告)号：US5573657A

    公开(公告)日：1996-11-12

    申请号：US309288

    申请日：1994-09-20

    申请人： Thomas F. Degnan ,  Richard C. Dougherty ,  George H. Hatzikos ,  Stuart S. Shih ,  Tsoung Y. Yan

    发明人： Thomas F. Degnan ,  Richard C. Dougherty ,  George H. Hatzikos ,  Stuart S. Shih ,  Tsoung Y. Yan

    IPC分类号： B01J29/04 ,  C10G45/00 ,  C10G45/54

    CPC分类号： B01J29/043 ,  B01J29/0325 ,  C10G45/00 ,  B01J2229/42 ,  C10G2400/10

    摘要： A hydrogenation process for reducing the unsaturation of lubricants uses a catalyst which is based on an ultra-large pore crystalline material. The crystalline material has pores of at least 13 .ANG. diameter arranged in a uniform manner and exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams (50 torr and 25.degree. C.). A preferred form of the catalyst has a hexagonal structure which exhibits a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG.. The hydrogenation catalysts based on these materials are capable of reducing the unsaturation in poly alpha olefin lubricants to a low level.

    摘要翻译： 用于降低润滑剂的不饱和度的氢化方法使用基于超大孔结晶材料的催化剂。 结晶材料具有均匀排列的至少13安培直径的孔，并且通过苯吸附能力大于约15克苯/ 100克（50托和25℃）表现出非常大的吸附能力。 催化剂的优选形式具有六角形结构，其显示六方电子衍射图，其可以以大于约18安培的d100值进行索引。 基于这些材料的氢化催化剂能够将聚α-烯烃润滑剂的不饱和度降低至低水平。