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公开(公告)号：US5378772A
公开(公告)日：1995-01-03
申请号：US040067
申请日：1993-03-30
CPC分类号： C08G75/024 , C08G75/0245
摘要： Disclosed herein are a poly(arylene thioether) block copolymer alternately comprising (A) at least one poly(arylene thioetherketoneketone) block having predominant recurring units of the formula ##STR1## and (B) at least one poly(arylene thioether) block having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) block (B) to the total amount of the poly(arylene thioetherketoneketone) block (A) being within a range of 0.1-9 by weight, (B) the weight average molecular weight of the poly(arylene thioether) block (B) being at least 1,000, and (c) said block copolymer having a melt viscosity of 2-100,000 poises as measured at 380.degree. C. and a shear rate of 1,200/sec as well as a production process of the block copolymer.
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公开(公告)号：US5324814A
公开(公告)日：1994-06-28
申请号：US686972
申请日：1991-04-18
IPC分类号： C08G75/02 , C08G75/20 , C08G75/14 , C08F283/00
CPC分类号： C08G75/20 , C08G75/0227 , C08G75/024 , C08G75/0245 , C08G75/0295
摘要： Disclosed herein is a process for the production of an arylene thioether copolymer (C), wherein an alkali metal sulfide is caused to act on a poly(arylene thioether) (A) having predominant recurring units of the formula [I]: ##STR1## wherein R denotes an alkyl group having 1-6 carbon atoms, and 1 stands for 0 or an integer of 1-4, in a water-containing polar organic solvent so as to depolymerize the poly(arylene thioether) (A), thereby preparing a prepolymer (B) having an alkali thiolate group on at least one terminal thereof and the resultant prepolymer (B) is then subjected to a polymerization reaction with at least one dihalogen-substituted aromatic compound.
摘要翻译： 本文公开了一种制备亚芳基硫醚共聚物（C）的方法，其中使碱金属硫化物作用于具有主要的式[I]重复单元的聚（亚芳基硫醚）（A）：
在含水极性有机溶剂中，其中R表示具有1-6个碳原子的烷基，1表示0或1-4的整数，以使聚（亚芳基硫醚）（A）解聚， ，由此在至少一个末端制备具有碱硫醇盐基的预聚物（B），然后将所得预聚物（B）与至少一种二卤代芳香族化合物进行聚合反应。 -
公开(公告)号：US07252882B2
公开(公告)日：2007-08-07
申请号：US10289775
申请日：2002-11-07
申请人： Yoshikatsu Satake , Genzo Asai
发明人： Yoshikatsu Satake , Genzo Asai
IPC分类号： B32B5/16
CPC分类号： C08J9/20 , B01J13/14 , C08J9/16 , C08J2327/08 , C08J2333/00 , Y10T428/2987
摘要： The invention provides a thermally foamable microsphere whose shell is formed of a polymer that is obtained by the polymerization of a polymerizable monomer and a crosslinkable monomer at a proportion of greater than 1% by weight up to 5% by weight based on the polymerizable monomer and which has a maximum expansion ratio of at least 5. The invention also provides a process for the production of a thermally foamable microsphere having a maximum expansion ratio of at least 5 by the suspension polymerization of a polymerizable mixture containing a crosslinkable monomer at a proportion of greater than 1% by weight up to 5% by weight based on the polymerizable monomer.
摘要翻译： 本发明提供了一种热可发泡微球体，其外壳由聚合物形成，该聚合物通过聚合可聚合单体和可交联单体的比例基于可聚合单体大于1重量％至多5重量％ 其具有至少为5的最大膨胀比。本发明还提供了通过含有可交联单体的可聚合混合物的悬浮聚合制备热发泡性微球的方法，所述热发泡性微球的最大膨胀比为至少5 基于可聚合单体大于1重量％至多5重量％。
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公开(公告)号：US5744576A
公开(公告)日：1998-04-28
申请号：US888599
申请日：1997-07-07
CPC分类号： C08G75/0254
摘要： In a process for producing poly(phenylene sulfide), in which an alkali metal sulfide is reacted with a dihalo-aromatic compound in an organic amide solvent, the reaction is conducted through the following Steps 1 and 2, thereby efficiently providing granular, high-molecular weight poly(phenylene sulfide) having excellent whiteness in a short period of time and at a high yield. Step 1: a step comprising reacting the alkali metal sulfide with the dihalo-aromatic compound within a temperature range of 170.degree.-270.degree. C. in the organic amide solvent containing water in a proportion of 0.5-2.0 moles per mole of the alkali metal sulfide charged while raising the reaction temperature at an average heating rate of 0.1.degree.-1.degree. C./min in at least a temperature range of from 220.degree. C. to 240.degree. C., so as to give a conversion of the dihalo-aromatic compound of 70-98 mol %, thereby forming a: prepolymer of poly(phenylene sulfide); and Step 2: a step comprising adding water to the reaction system at a temperature of at least 235.degree. C. in such a manner that water is present in a proportion of 2.1-10 moles per mole of the alkali metal sulfide charged, and continuing the reaction for 0.5-10 hours within a temperature range of 245.degree.-290.degree. C., thereby converting the prepolymer to high-molecular weight poly(phenylene sulfide).
摘要翻译： 在有机酰胺溶剂中使碱金属硫化物与二卤芳香族化合物反应的聚苯硫醚的制造方法中，通过以下的工序1和2进行反应， 分子量的聚（苯硫醚）在短时间内具有优异的白度并以高产率。 步骤1：包括使碱金属硫化物与二卤代芳族化合物在170-270℃的温度范围内反应，所述有机酰胺溶剂含有0.5-2.0摩尔/摩尔碱金属的比例的水 硫化物在220℃至240℃的至少220℃的温度范围内以0.1-1℃/分钟的平均加热速率升高反应温度，从而使二卤代 - 芳族化合物为70-98mol％，从而形成：聚苯硫醚的预聚物; 和步骤2：包括在至少235℃的温度下向反应体系中加入水的步骤，使得水以每摩尔所加入的碱金属硫化物为2.1-10摩尔的比例存在，并且继续 在245〜-290℃的温度范围内反应0.5-10小时，由此将预聚物转化为高分子量聚苯硫醚。
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公开(公告)号：US5650459A
公开(公告)日：1997-07-22
申请号：US397015
申请日：1995-03-01
申请人： Yoshikatsu Satake , Toshihiko Ono
发明人： Yoshikatsu Satake , Toshihiko Ono
摘要： A poly(arylene sulfide) resin composition comprising in admixture a poly(arylene sulfide) resin and at least one nickel compound selected from the group consisting of (a) nickel carbonates, (b) nickel hydroxide, (c) organic carboxylates of nickel and (d) nickel oxide is provided. According to the resin composition of the invention, the metal corrosiveness of the poly(arylene sulfide) resin upon and after its molding or forming is sufficiently inhibited without deteriorating the excellent heat resistance, mechanical properties, processability and the like inherent in the resin.
摘要翻译： 一种聚（亚芳基硫醚）树脂组合物，其包含混合聚（亚芳基硫醚）树脂和至少一种选自（a）碳酸镍，（b）氢氧化镍，（c）镍的有机羧酸盐和 （d）提供氧化镍。 根据本发明的树脂组合物，可以充分抑制聚（亚芳基硫醚）树脂在其成型或成型时及其后的金属腐蚀性，而不会降低树脂固有的优异的耐热性，机械性能，加工性等。
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36.发明授权High-heat-resistant, crystalline block copolymers and production process thereof 失效高耐热结晶嵌段共聚物及其制备方法
公开(公告)号：US5378771A
公开(公告)日：1995-01-03
申请号：US40066
申请日：1993-03-30
CPC分类号： C08G75/024 , C08G75/0245
摘要： Disclosed herein are a poly(arylene thioether) block copolymer alternately comprising (A) at least one poly(arylene thioetherketoneketone) block having predominant recurring units of the formula ##STR1## and (B) at least one poly(arylene thioether) block having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) block (B) to the total amount of the poly(arylene thioetherketoneketone) block (A) being within a range of 0.1-9 by weight, (B) the weight average molecular weight of the poly(arylene thioether) block (B) being at least 1,000, and (c) said block copolymer having a melt viscosity of 2-100,000 poises as measured at 380.degree. C. and a shear rate of 1,200/sec as well as a production process of the block copolymer.
摘要翻译： 本文公开了一种聚（亚芳基硫醚）嵌段共聚物，其交替地包含（A）至少一种具有主题的式（IMA）的重复单元的聚（亚芳基硫醚酮酮）嵌段和（B）至少一种具有主体的聚（亚芳基硫醚）嵌段 （a）聚（亚芳基硫醚）嵌段（B）的总量与聚（亚芳基硫醚酮酮）嵌段（A）的总量的比例在0.1的范围内的重复单元， 9，（B）聚亚芳基硫醚嵌段（B）的重均分子量为至少1,000，和（c）所述嵌段共聚物在380℃下测得的熔融粘度为2-100,000泊 ，剪切速度为1200 /秒，以及嵌段共聚物的制造方法。
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37.发明授权
公开(公告)号：US5288815A
公开(公告)日：1994-02-22
申请号：US686978
申请日：1991-04-18
IPC分类号： C08G75/02 , C08F283/00 , C08G14/00
CPC分类号： C08G75/024 , C08G75/0245
摘要： Disclosed herein are a poly(arylene thioether-ketone) copolymer comprising (A) at least one poly(arylene thioether-ketone) segment having predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other and (B) at least one poly(arylene thioether) segment having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) segment (B) to the total amount of the poly(arylene thioether-ketone) segment (A) ranging from 0.05 to 5 by weight, (b) the number-average polymerization degree of the poly(arylene thioether) segment (B) being higher than 1 but lower than 10, and (c) said copolymer having a melt viscosity of 2-100,000 poises as measured at 350.degree. C. and a shear rate of 1,200/sec as well as a production process of the poly(arylene thioether-ketone) copolymer.
摘要翻译： 本文公开了一种聚（亚芳基硫醚 - 酮）共聚物，其包含（A）至少一种具有主要重复单元的式（*化学结构*）的聚（亚芳基硫醚 - 酮）链段，其中-CO-和-S-为 （B）至少一种具有主要的式（*化学结构*）重复单元的聚亚芳基硫醚链段（a）聚（亚芳基硫醚）链段的总量的比例 （B）相对于聚（亚芳基硫醚 - 酮）链段（A）的总量为0.05-5重量％，（b）聚（亚芳基硫醚）链段（B）的数均聚合度更高 1，但低于10，和（c）所述共聚物在350℃下测得的熔融粘度为2-100,000泊，剪切速率为1200 /秒，以及聚（亚芳基硫醚 - 酮）共聚物。
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公开(公告)号：US07931967B2
公开(公告)日：2011-04-26
申请号：US10480207
申请日：2002-06-10
申请人： Yasuhiro Tasaki , Genzo Asai , Yoshikatsu Satake
发明人： Yasuhiro Tasaki , Genzo Asai , Yoshikatsu Satake
CPC分类号： B01J13/18 , B01J13/14 , D21H17/59 , D21H21/54 , Y10T428/2984 , Y10T428/2985 , Y10T428/2991 , Y10T428/2995
摘要： The invention provides a thermally foamable microsphere having a structure with a foaming agent encapsulated in a shell formed of a polymer, wherein the shell contains an organosilicon compound, and a process for producing a thermally foamable microsphere having a structure with a foaming agent encapsulated in a shell formed of a polymer by suspension polymerization of a polymerizable mixture containing at least a foaming agent and a polymerizable monomer in an aqueous dispersion medium, wherein the polymerizable mixture is suspension polymerized in the presence of the organosilicon compound.
摘要翻译： 本发明提供一种具有包封在由聚合物形成的壳体中的发泡剂的结构的热发泡性微球体，其中壳体包含有机硅化合物，以及制备具有封装在其中的发泡剂结构的热发泡性微球体的方法 通过在含水分散介质中至少含有发泡剂和可聚合单体的可聚合混合物的悬浮聚合形成聚合物的壳体，其中可聚合混合物在有机硅化合物存在下悬浮聚合。
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39.发明授权Poly(arylene thioether-ketone-ketone) copolymer and production process thereof 失效聚（亚芳基硫醚 - 酮 - 酮）共聚物及其制备方法
公开(公告)号：US5378770A
公开(公告)日：1995-01-03
申请号：US35768
申请日：1993-03-23
CPC分类号： C08G75/024 , C08G75/0245
摘要： Disclosed herein is a poly(arylene thioether-ketone-ketone) copolymer comprising (A) at least one poly(arylene thioether-ketone-ketone) segment having predominant recurring units of the formula ##STR1## and (B) at least one poly(arylene thioether) segment having predominant recurring units of the formula ##STR2## (a) the ratio of the total amount of the poly(arylene thioether) segment (B) to the total amount of the poly(arylene thioether-ketone-ketone) segment (A) ranging from 0.1 to 9 by weight, (b) the weight-average molecular weight of the poly(arylene thioether) segment (B) being at least 200 but lower than 1000, and (c) said copolymer having a melt viscosity of 2-100,000 poises as measured at 380.degree. C. and a shear rate of 1,200/sec as well as a production process of the poly(arylene thioether-ketone-ketone) copolymer. The copolymer has high crystallinity and heat resistance, uniform composition, and excellent melt stability, processability, handling properties, solvent resistance and moisture absorption resistance.
摘要翻译： 本文公开了一种聚（亚芳基硫醚 - 酮 - 酮）共聚物，其包含（A）至少一种具有下式的主要重复单元的聚（亚芳基硫醚 - 酮 - 酮）链段和（B）至少一种聚 （a）聚（亚芳基硫醚）链段（B）的总量与聚（亚芳基硫醚 - 酮 - 酮）链段的总量的比率（a）具有下式的主要重复单元的亚芳基硫醚） （A）为0.1-9重量％，（b）聚亚芳基硫醚链段（B）的重均分子量至少为200但小于1000，和（c）所述共聚物具有熔体粘度 在380℃下测量的2-100,000泊，剪切速率为1200 /秒，以及聚（亚芳基硫醚 - 酮 - 酮）共聚物的制备方法。 共聚物具有高结晶度和耐热性，组成均匀性，以及优异的熔体稳定性，加工性，操作性，耐溶剂性和耐吸湿性。
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公开(公告)号：US4302558A
公开(公告)日：1981-11-24
申请号：US72846
申请日：1979-09-06
申请人： Masaki Ohya , Akio Kobayashi , Takeo Ogiwara , Yoshikatsu Satake
发明人： Masaki Ohya , Akio Kobayashi , Takeo Ogiwara , Yoshikatsu Satake
IPC分类号： C08F265/00 , C08F279/00 , C08L7/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/04 , C08F265/06 , C08F297/02
CPC分类号： C08L51/04
摘要： A graft copolymer is obtained by graft-polymerizing a vinyl or vinylidene monomer onto a rubber trunk polymer which comprises a polyalkylene oxide monomer comprising 4 to 500 alkylene oxide groups together with an ethylenic unsaturation, and a conjugated diene and/or an alkyl acrylate. This graft copolymer alone or in a mixture thereof with another thermoplastic resin, because of the presence of the polyalkylene oxide monomer unit incorporated in the rubber trunk polymer, provides a resin composition possessing excellent antistatic property, which, practically, is not lowered by washing.
摘要翻译： 通过将乙烯基或亚乙烯基单体接枝聚合到橡胶树脂聚合物上而获得接枝共聚物，橡胶树脂聚合物包含含有4-50个烯化氧基团和烯属不饱和基团的聚环氧烷单体和共轭二烯和/或丙烯酸烷基酯。 由于在橡胶树脂聚合物中引入的聚环氧烷单体单元的存在，单独或与其它热塑性树脂的混合物中的接枝共聚物提供了具有优异的抗静电性的树脂组合物，其实际上通过洗涤实际上不降低。
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