Organic electroluminescent materials and devices
    33.
    发明授权
    Organic electroluminescent materials and devices 有权
    有机电致发光材料和器件

    公开(公告)号:US09590195B2

    公开(公告)日:2017-03-07

    申请号:US14194311

    申请日:2014-02-28

    Abstract: A compound including a Ligand L of Formula I: as well as, a first device and a formulation containing the same, are disclosed. In the compound including the Ligand L of Formula I: X is selected from the group consisting of S, Se, SiRR′ and GeRR′; R1, R2, R, and R′ are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; any adjacent substitutions or substituents of R1, R2, R, and R′ are optionally linked together to form a ring; the Ligand L is coordinated to a metal M having an atomic number of 40 or greater; and the Ligand L is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.

    Abstract translation: 公开了包含式I的配体L的化合物以及第一装置和含有其的制剂。 在包含式I的配体L的化合物中,X选自S,Se,SiRR'和GeRR'; R1,R2,R和R'各自独立地选自氢,氘,卤素,烷基,环烷基,杂烷基,芳基烷基,烷氧基,芳氧基,氨基,甲硅烷基,烯基,环烯基,杂烯基,炔基,芳基, 杂芳基,酰基,羰基,羧酸,酯,腈,异腈,硫烷基,亚磺酰基,磺酰基,膦基及其组合; R1,R2,R和R'的任何相邻的取代基或取代基任选地连接在一起形成环; 配体L与原子序数为40或更大的金属M配位,并且配体L任选地与其它配体连接以包含三齿,四齿,五齿或六齿配体。

    Organic electroluminescent materials and devices

    公开(公告)号:US11560398B2

    公开(公告)日:2023-01-24

    申请号:US16859226

    申请日:2020-04-27

    Abstract: Provided is a process for preparation of a compound of Formula 1 where, ring Y and ring Z are each independently a 5-membered or 6-membered carbocyclic or heterocyclic ring; Z1 and Z2 are each independently C or N; each RY and RZ independently represents mono to the maximum possible number of substitutions, or no substitution; x=1, 2, or 3; y=0, 1, or 2; and x+y=3. Disclosed is a chemical synthesis process that involves contacting a compound of Formula 2 with a compound of Formula 3 in an organic solvent to yield a compound of Formula 1

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