公开(公告)号：US4960456A

公开(公告)日：1990-10-02

申请号：US354329

申请日：1989-05-19

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents a substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cyclo-alkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

公开(公告)号：US4734126A

公开(公告)日：1988-03-29

申请号：US683891

申请日：1984-12-20

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00 ,  A61K31/41

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

摘要翻译： 化合物，其中A表示氮原子或CH基团，B表示氧，硫或CH2基团，其中R表示取代的烷基，且表示取代的烷基， B代表硫的情况也代表未取代的烷基，任选取代的环烷基或任选取代的苯基，Z代表卤素原子或烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基，任选取代的苯基， 苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其酸加成盐和金属盐络合物是新的，如上所述制备，可用作杀真菌剂和植物生长调节剂。

公开(公告)号：US4729783A

公开(公告)日：1988-03-08

申请号：US715574

申请日：1985-03-22

申请人： Erik Regel ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

发明人： Erik Regel ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

IPC分类号： A01N43/653 ,  C07C45/63 ,  C07C49/16 ,  C07D249/08 ,  C07D521/00 ,  A61K31/41

CPC分类号： C07D231/12 ,  A01N43/653 ,  C07C45/63 ,  C07C49/16 ,  C07D233/56 ,  C07D249/08

摘要： Halogenated triazolylvinyl keto derivatives and carbinol derivatives of the general formula ##STR1## in which A represents a keto group or a CH(OH) grouping,X represents a hydrogen or halogen atom,Y represents a halogen atom,R represents a halogen atom, an alkyl, halogenoalkyl, halogenoalkoxy, alkoxy, alkylthio, halogenoalkylthio, alkylamino, dialkylamino, nitro, cyano, hydroxyl or alkylcarbonyloxy radical, an optionally substituted phenyl radical, an optionally substituted phenoxy radical or an optionally substituted benzyloxy radical andn is 0, 1, 2 or 3,and physiologically acceptable acid addition salts and metal salt complexes thereof are outstandingly effective as plant growth regulators and as fungicides. The inventive compounds can be prepared by reacting a triazolylketone with an aldehyde.

摘要翻译： 卤代三唑基乙烯基酮衍生物和通式为其中A表示酮基或CH（OH）基的通式为（I）的甲醇衍生物，X表示氢或卤素原子，Y表示卤素原子，R表示卤素 烷氧基，烷硫基，卤代烷硫基，烷基氨基，二烷基氨基，硝基，氰基，羟基或烷基羰基氧基，任意取代的苯基，任意取代的苯氧基或任意取代的苄氧基，n为0， 1,2或3，其生理上可接受的酸加成盐和金属盐络合物作为植物生长调节剂和杀真菌剂是非常有效的。 本发明化合物可以通过使三唑基酮与醛反应来制备。

公开(公告)号：US4728356A

公开(公告)日：1988-03-01

申请号：US754788

申请日：1985-07-12

申请人： Hans-Ludwig Elbe ,  Wolf Reiser ,  Erik Regel ,  Karl H. Buchel ,  Paul Reinecke ,  Wilhelm Brandes ,  Klaus Lurssen ,  Paul-Ernst Frohberger

发明人： Hans-Ludwig Elbe ,  Wolf Reiser ,  Erik Regel ,  Karl H. Buchel ,  Paul Reinecke ,  Wilhelm Brandes ,  Klaus Lurssen ,  Paul-Ernst Frohberger

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.3 represents optionally substituted phenyl,X represents the CO or CH(OH) group andY represents a nitrogen atom or the CH group,or an addition product thereof with an acid or metal salt.The products are active in combating fungi and in regulating the growth of plants.

摘要翻译： 其中R 1表示任选取代的具有3至5个碳原子的环烷基，取代的环己基或基团，其中R 3表示任选取代的苯基，烯基，炔基，氰基或基团 - Z-R4，其中R4代表烷基，卤代烷基，任选取代的苯基或任选取代的苯基烷基，Z代表O，S，SO或SO 2，n代表0至2的数，R 2代表烷基，烯基，炔基， 取代的苯基或苯基烷基，或者在每种情况下都是任选取代的环烷基，环烷基烷基，环烯基，环烯基烷基，双环烷基或双环烯基，但R 2不同时代表任选取代的苯基，其中R 1表示任选取代的具有3至5个碳原子的环烷基或取代的环己基 或R 3表示任选取代的苯基，X表示CO或CH（OH）基团，Y表示氮气 m或CH基团，或其与酸或金属盐的加成产物。 该产品在防治真菌和调节植物生长方面发挥积极作用。

公开(公告)号：US4711657A

公开(公告)日：1987-12-08

申请号：US684973

申请日：1984-12-21

申请人： Wolfgang Kramer ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

发明人： Wolfgang Kramer ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Klaus Lurssen

IPC分类号： A01N43/653 ,  A01P3/00 ,  C07D249/08 ,  C07D521/00 ,  C07D249/10

CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： New substituted triazolylmethyl tert.-butyl ketones of the formula ##STR1## in which R represents alkyl, alkenyl, alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl or optionally substituted aralkyl,X represents hydrogen or halogen andY represents halogen,and the acid addition salts and metal salt complexes thereof, a process for the preparation of said novel compounds, their use as plant protection agents and as intermediate products for the synthesis of other plant protection agents.

摘要翻译： 新颖的具有式“IMAGE”的取代的三唑基甲基叔丁基酮，其中R代表烷基，烯基，炔基，任选取代的环烷基，任选取代的环烷基烷基或任选取代的芳烷基，X代表氢或卤素，Y代表卤素， 其盐和金属盐络合物，制备所述新化合物的方法，它们作为植物保护剂的用途以及用于合成其它植物保护剂的中间产物。

公开(公告)号：US4500537A

公开(公告)日：1985-02-19

申请号：US494216

申请日：1983-05-13

申请人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

发明人： Hans-Ludwig Elbe ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

IPC分类号： A01N43/653 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64 ,  A01N55/02 ,  C07F1/08

CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： A triazolyl-vinyl ketone or carbinol of the formula ##STR1## in which A represents the keto group or a CH(OH) grouping,R.sup.1 represents alkyl or halogenoalkyl andR.sup.2 represents a primary or tertiary alkyl radical, halogenoalkyl, alkoxyalkyl, alkylmercaptoalkyl, dialkylaminoalkyl, hydroxyalkyl, an optionally substituted alkenyl, alkynyl or alkenynyl radical, phenylalkyl which is optionally substituted in the alkyl part and/or in the phenyl part, an optionally substituted indenyl or fluorenyl radical, or an optionally substituted diphenylmethyl or triphenylmethyl radical,or an addition product thereof with a physiologically acceptable acid or a metal salt, which possesses fungicidal activity.

摘要翻译： 其中A表示酮基或CH（OH）基团的三唑基 - 乙烯基酮或甲醇，其中A表示酮基或CH（OH）基，R 1表示烷基或卤代烷基，R 2表示伯或叔烷基，卤代烷基，烷氧基烷基，烷基巯基烷基，二烷基氨基烷基 ，羟基烷基，任选取代的烯基，炔基或烯基炔基，在烷基部分和/或苯基部分任选取代的苯基烷基，任选取代的茚基或芴基，或任选取代的二苯基甲基或三苯基甲基，或加成 其具有生理上可接受的酸或金属盐，其具有杀真菌活性。

公开(公告)号：US4229459A

公开(公告)日：1980-10-21

申请号：US900401

申请日：1978-04-26

申请人： Wolfgang Kramer ,  Karl H. Buchel ,  Wilhelm Brandes ,  Paul-Ernst Frohberger ,  Volker Paul

发明人： Wolfgang Kramer ,  Karl H. Buchel ,  Wilhelm Brandes ,  Paul-Ernst Frohberger ,  Volker Paul

IPC分类号： A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  A01P3/00 ,  C07D233/54 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00 ,  A01N9/22

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： Azolyl ether derivatives of the formula ##STR1## in which A is CH or a nitrogen atom,R is alkyl, alkenyl, alkynyl, phenyl, benzyl or substituted phenyl or benzyl,X is halogen, alkyl, alkoxy, alkylthio, alkylsulphonyl, halogenoalkyl, alkoxycarbonyl, nitro, cyano, phenyl, phenoxy, phenylthio, or substituted phenyl, phenoxy of phenylthio,Y is alkyl, phenyl, or substituted alkyl or phenyl andn is 0, 1, 2, 3, 4 or 5,which possess fungicidal properties.

摘要翻译： 其中A为CH或氮原子，R为烷基，烯基，炔基，苯基，苄基或取代的苯基或苄基，式为“IMAGE”的唑基醚衍生物，X为卤素，烷基，烷氧基，烷硫基，烷基磺酰基，卤代烷基， 烷氧基羰基，硝基，氰基，苯基，苯氧基，苯硫基或取代的苯基，苯硫基的苯氧基，Y是烷基，苯基或取代的烷基或苯基，n是0,1,2,3,4或5，具有杀真菌性 。

公开(公告)号：US4140782A

公开(公告)日：1979-02-20

申请号：US806889

申请日：1977-06-15

申请人： Helmut Timmler ,  Wilfried Draber ,  Karl H. Buchel ,  Wolfgang Kramer ,  Wilhelm Brandes ,  Paul-Ernst Frohberger ,  Bernhard Homeyer

发明人： Helmut Timmler ,  Wilfried Draber ,  Karl H. Buchel ,  Wolfgang Kramer ,  Wilhelm Brandes ,  Paul-Ernst Frohberger ,  Bernhard Homeyer

IPC分类号： A01N43/653 ,  A01P3/00 ,  C07D249/08 ,  C07D521/00 ,  A01N9/00 ,  A01N9/22

CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： Diphenyl-triazolyl-methanes of the formula ##STR1## in which R is alkyl, alkylcarbonyl or optionally substituted phenylcarbonyl,X and Y each independently is halogen, alkyl, halogenoalkyl, alkoxy, alkylthio, optionally substituted phenyl or phenoxy, nitro or cyano, andM and n each independently is an integer from 0 to 5, and their physiologically tolerated salts are used to combat fungi and nematodes.

摘要翻译： 式（I）的二苯基 - 三唑基 - 甲烷，其中R是烷基，烷基羰基或任选取代的苯基羰基，X和Y各自独立地是卤素，烷基，卤代烷基，烷氧基，烷硫基，任选取代的苯基或苯氧基，硝基 或氰基，M和N每个独立地为0至5的整数，并且它们的生物学上可容忍的盐用于混合真菌和杀虫剂。

公开(公告)号：US4789672A

公开(公告)日：1988-12-06

申请号：US732194

申请日：1985-05-08

申请人： Graham Holmwood ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

发明人： Graham Holmwood ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

IPC分类号： A01N20060101 ,  A01N43/20 ,  A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  C07D20060101 ,  C07D233/60 ,  C07D249/08 ,  C07D301/00 ,  C07D301/02 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/20 ,  C07D303/22 ,  C07D521/00

CPC分类号： A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22

摘要： New 1-hydroxyethyl-azole derivatives of the general formula ##STR1## in which R represents an alkyl radical, an optionally substituted cycloalkyl radical or an optionally substituted phenyl radical,X represents a nitrogen atom or a CH group,Y represents a grouping --OCH.sub.2 --, --CH.sub.2 CH.sub.2 -- or --CH.dbd.CH--,Z represents a halogen atom, an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio radical, an optionally substituted phenyl radical, an optionally substituted phenoxy radical, an optionally substituted phenylalkyl radical or an optionally substituted phenylalkoxy radical andm is 0, 1, 2 or 3,a process for their preparation and their use as plant growth regulators and fungicides.

摘要翻译： 其中R表示烷基，任选取代的环烷基或任选取代的苯基的新的1-羟乙基 - 唑衍生物，其中R表示氮原子或CH基团，Y表示 分别为-OCH 2 - ， - CH 2 CH 2 - 或-CH = CH-，Z表示卤素原子，烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基或卤代烷硫基，任选取代的苯基，任选取代的苯氧基， 任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其制备方法及其用作植物生长调节剂和杀真菌剂。

公开(公告)号：US4427673A

公开(公告)日：1984-01-24

申请号：US291003

申请日：1981-08-07

申请人： Wolfgang Kramer ,  Karl H. Buchel ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

发明人： Wolfgang Kramer ,  Karl H. Buchel ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D233/61 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： Fungicidally active novel azolylalkyl derivatives of the formula ##STR1## in which R.sup.1 is an alkyl or aryl group,R.sup.2 is a hydrogen atom or an alkyl or aryl group,R.sup.3 is cyano or --CO--OR.sup.4,R.sup.4 is alkyl or aralkyl group,A is a keto group or a CH(OH) group,X is a nitrogen atom or the CH group, andm and n are identical and represent 0 to 1,or a physiologically acceptable addition product thereof with an acid or a metal salt.

摘要翻译： R1为烷基或芳基，R2为氢原子或烷基或芳基的R3为氰基或-CO-OR4，R4为烷基或芳烷基的式 是酮基或CH（OH）基，X是氮原子或CH基，m和n相同并且表示0至1，或其与酸或金属盐的生理上可接受的加成产物。