METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER, AQUEOUS DISPERSION LIQUID OF FLUORINE-CONTAINING POLYMER, AND POLYMER COMPOSITION

    公开(公告)号:US20230212331A1

    公开(公告)日:2023-07-06

    申请号:US18181687

    申请日:2023-03-10

    申请人: AGC Inc.

    IPC分类号: C08F14/26 C08F14/24 C08F14/22

    CPC分类号: C08F14/26 C08F14/24 C08F14/22

    摘要: To provide a method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which comprises polymerizing at least one fluorinated polymer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a specific polymer having at least one type of units selected from units based on a compound represented by the formula (1) and units based on a compound represented by the formula (2) to produce a fluorinated polymer (provided that when tetrafluoroethylene is polymerized, tetrafluoroethylene is polymerized so that the content of units based on tetrafluoroethylene in the fluorinated polymer becomes less than 99 mass % to all units in the fluorinated polymer):


    CXY═CR1—COO-(L-O)n—R2  formula (1):



    CXY═CR3—(O)m—CH2—Z—R4  formula (2):

    FLUOROPOLYMER PRODUCTION METHOD
    38.
    发明申请
    FLUOROPOLYMER PRODUCTION METHOD 有权
    氟聚合物生产方法

    公开(公告)号:US20160108159A1

    公开(公告)日:2016-04-21

    申请号:US14892844

    申请日:2014-04-30

    IPC分类号: C08F214/26 C08F214/28

    摘要: The present invention aims to provide a method of producing a fluoropolymer, especially a fluoropolymer essentially including a tetrafluoroethylene or chlorotrifluoroethylene unit, at a higher polymerization rate with improved efficiency, the method being capable of improving the moldability in extrusion molding and suppressing discoloration. The method of producing a fluoropolymer of the present invention includes producing a fluoropolymer by polymerizing tetrafluoroethylene or chlorotrifluoroethylene in the presence of a peroxydicarbonate. The peroxydicarbonate is represented by the formula: R—O—C(═O)—O—O—C(═O)—O—R wherein R's may be the same as or different from each other and individually represent a C4 alkyl group or alkoxy alkyl group.

    摘要翻译: 本发明的目的在于提供一种以更高的聚合速率生产含氟聚合物,特别是基本上包含四氟乙烯或氯三氟乙烯单元的含氟聚合物的方法,该方法能够提高挤出成型中的成型性和抑制变色。 本发明的含氟聚合物的制造方法包括在过氧化二碳酸酯的存在下聚合四氟乙烯或氯三氟乙烯来制造含氟聚合物。 过氧化二碳酸酯由下式表示:R-O-C(= O)-O-O-C(= O)-O-R,其中R可以彼此相同或不同,并且各自表示C4烷基 或烷氧基烷基。

    ULTRA-HIGH MOLECULAR WEIGHT POLY(VINYLIDENE FLUORIDE)
    39.
    发明申请
    ULTRA-HIGH MOLECULAR WEIGHT POLY(VINYLIDENE FLUORIDE) 审中-公开
    超高分子量聚(氟乙烯)

    公开(公告)号:US20140296438A1

    公开(公告)日:2014-10-02

    申请号:US14301567

    申请日:2014-06-11

    申请人: Arkema Inc.

    摘要: The invention relates to a polyvinylidene fluoride polymer having an ultra-high molecular weight, and unexpected physical properties. The ultra-high molecular weight polymer is clear, has a lower melting point, reduced crystallinity, excellent impact resistance, and a high elongation at the yield point. The ultra-high molecular weight polyvinylidene fluoride can be alone, or blended with other polymers, in final applications and articles.

    摘要翻译: 本发明涉及具有超高分子量和意想不到的物理性质的聚偏二氟乙烯聚合物。 超高分子量聚合物是透明的,具有较低的熔点,降低的结晶度,优异的耐冲击性和屈服点的高伸长率。 超高分子量聚偏二氟乙烯可以在最终应用和制品中单独使用或与其它聚合物共混。

    Method for producing fluorine-containing polymer
    40.
    发明授权
    Method for producing fluorine-containing polymer 有权
    含氟聚合物的制造方法

    公开(公告)号:US08735492B2

    公开(公告)日:2014-05-27

    申请号:US13392814

    申请日:2010-08-25

    IPC分类号: C08F2/24

    摘要: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2═CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.)

    摘要翻译: 本发明的目的是提供一种使用具有表面活性剂的特定非氟化合物生产大量具有小粒径的颗粒的含氟聚合物的方法。 含氟聚合物的制造方法包括在由式:CH 2 = CR 1 -R 2 -O-(AO)p -X(式1)表示的化合物(1)的存在下包含至少一种氟烯烃的单体的水分散聚合 R1是氢或烷基; R2是具有两个或更多个碳原子的亚烷基; AO是具有2至4个碳原子的直链或支链氧化烯基; p是正整数; X是H或SO 3 Y,其中Y是 NH 4或碱金属;并且AO可以相同或不同,如果存在多于一个AO,则可以形成两个或更多个嵌段)。