Abstract:
The invention provides a molded article containing a specific fluororesin and having excellent hydrophilicity. The molded article containing the fluororesin has a melt flow rate of 1.00 g/10 min or lower and a water contact angle of 90° or smaller. The fluororesin contains at least one copolymer selected from the group consisting of a copolymer containing a tetrafluoroethylene unit and a perfluoro(alkylvinylether) unit and a copolymer containing a tetrafluoroethylene unit and a hexafluoropropylene unit.
Abstract:
Provided is a tetrafluoroethylene/hexafluoropropylene copolymer which is less likely to form a lump, or is less likely to form a large lump even if a lump is formed, during the formation of an electric wire. The tetrafluoroethylene/hexafluoropropylene copolymer has a melt flow rate measured at 372° C. of 35.0 to 45.0 g/10 minutes and a swell of −8.0% to 5.0%, the sum of the numbers of —CF2H groups and unstable end groups being 120 or less per 1×106 carbon atoms.
Abstract:
A composition which can provide foamed moldings and foamed electric wires having a small average cell size and a high foam content and causing fewer sparks. The composition includes a fluororesin (A) and a compound (B) which is a sulfonic acid or a salt thereof. The sulfonic acid is represented by the following formula (1): F(CF2)nSO3H (1) wherein n is 4 or 5, or the following formula (2): F(CF2)nCH2CH2SO3H (2) wherein n is 4 or 5. Also disclosed is a foamed molding formed from the composition and a method for producing a foamed molding.
Abstract translation:可以提供具有小平均泡孔尺寸和高泡沫含量并且引起较少火花的泡沫模制品和泡沫电线的组合物。 该组合物包括氟树脂(A)和作为磺酸或其盐的化合物(B)。 磺酸由下式(1)表示:F(CF 2)n SO 3 H(1)其中n为4或5,或下式(2):F(CF 2)n CH 2 CH 2 SO 3 H(2)其中n为4或5 还公开了由该组合物形成的发泡模制品和一种用于生产发泡模制品的方法。
Abstract:
The invention provides a process for producing a modified molded article capable of providing a diaphragm that is less likely to generate particles. The process for producing a modified molded article includes: molding modified polytetrafluoroethylene containing a tetrafluoroethylene unit and a modifying monomer unit based on a modifying monomer copolymerizable with tetrafluoroethylene to provide a molded article; and irradiating the molded article with not lower than 30 kGy but lower than 70 kGy of radiation at 270° C. to 310° C. to provide a modified molded article.
Abstract:
An object of the present invention is to provide a method for recovering a fluorine-containing ether capable of recovering a fluorine-containing ether used for producing a fluoropolymer, in higher recovery yield and in a shorter time. The present invention relates to a method for recovering a fluorine-containing ether, including the steps of: producing a wet fluoropolymer by suspension polymerization, solution polymerization, or bulk polymerization in the presence of at least a specific fluorine-containing ether; vaporizing and discharging vaporizable substances including the fluorine-containing ether by heating the wet fluoropolymer in a container; and transferring the vaporizable substances in the vaporized state to a cooling means to cool the vaporizable substances.
Abstract:
The invention provides novel pellets having high fluidity in a hopper of an extruder and capable of forming a coating layer having good wire diameter stability and capacitance stability even when used for rapid molding of electric wire coating. The pellets contain a fluororesin. Each of the pellets, placed on a horizontal surface, has a substantially circular outline or a substantially elliptic outline and has a major axis D1 of 3.1 mm or shorter and a minor axis D2 of 3.1 mm or shorter when observed in the direction normal to the horizontal surface. Each pellet satisfies the following formula (1): (D1+D2)/2L=1.8 to 2.6, wherein D1 represents the major axis, D2 represents the minor axis, and L represents the height from the horizontal surface to the highest point of the pellet.
Abstract:
A method for recovering a hydrofluorocarbon, including: producing a wet fluoropolymer by suspension polymerization, solution polymerization, or bulk polymerization in the presence of a hydrofluorocarbon; vaporizing and discharging vaporizable substances including the hydrofluorocarbon by heating the wet fluoropolymer in a container; and transferring the discharged vaporizable substances to a cooling means to cool the substances.
Abstract:
The present invention aims to provide a method of producing a fluoropolymer, especially a fluoropolymer essentially including a tetrafluoroethylene or chlorotrifluoroethylene unit, at a higher polymerization rate with improved efficiency, the method being capable of improving the moldability in extrusion molding and suppressing discoloration. The method of producing a fluoropolymer of the present invention includes producing a fluoropolymer by polymerizing tetrafluoroethylene or chlorotrifluoroethylene in the presence of a peroxydicarbonate. The peroxydicarbonate is represented by the formula: R—O—C(═O)—O—O—C(═O)—O—R wherein R's may be the same as or different from each other and individually represent a C4 alkyl group or alkoxy alkyl group.
Abstract:
The present invention aims to provide a composition which can provide molded foams and foamed electric wires having a small average cell size and a high expansion ratio. The composition of the present invention includes a fluororesin; and boron nitride having an average particle size of 10.5 μm or greater, or boron nitride having a particle size distribution represented by (D84−D16)/D50 of 1.2 or lower.
Abstract:
The present invention provides a molded article for a biodiesel fuel having excellent durability against a biodiesel fuel. The invention is a molded article for a biodiesel fuel of which the surface to be contacted with a biodiesel fuel is made of a fluorine-containing ethylenic resin.