SURFACE-MODIFIED COMPOSITE ZINC-BASED NEGATIVE ELECTRODE AND PREPARATION METHOD THEREOF, AND BATTERY

    公开(公告)号:US20240097103A1

    公开(公告)日:2024-03-21

    申请号:US18317572

    申请日:2023-05-15

    Abstract: A surface-modified composite zinc-based negative electrode, a preparation method thereof, and a battery are provided. The composite zinc-based negative electrode includes a zinc matrix material, a nano inorganic metal/alloy modified layer, and an organic polymer protective layer. The nano inorganic metal/alloy modified layer can increase hydrogen evolution overpotential of the composite zinc-based negative electrode, inhibit the generation of hydrogen on the negative electrode surface and occurrence of side reactions. The organic polymer protective layer can enhance the zinc ion concentration and deposition uniformity at the electrode interface, and improve the dendrite problem caused by uneven zinc deposition-dissolution during the charging and discharging process. The application of the modified composite zinc-based negative electrode in aqueous zinc-based batteries can improve their cycling stability under high current and high utilization conditions and show good rate performance and cycling life. The method has simple preparation process, low cost, and is suitable for large-scale production.

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