Process and apparatus for autothermic cracking of ethane to ethylene
    32.
    发明授权
    Process and apparatus for autothermic cracking of ethane to ethylene 失效
    将乙烷自热裂化为乙烯的方法和装置

    公开(公告)号:US4044068A

    公开(公告)日:1977-08-23

    申请号:US622347

    申请日:1975-10-14

    申请人: Bruce E. Kurtz

    发明人: Bruce E. Kurtz

    摘要: Process is provided for producing ethylene by the oxidative dehydrogenation ethane wherein a gas containing ethane is passed to a first elongated reaction zone, and a gas mixture containing oxygen and chlorine is passed into a second elongated gas zone positioned along said first gas zone, said first and second gas zones being separated by a porous member. The pressure of gases within the second gas zone is maintained in excess of the pressure in the first gas zone for diffusion of the chlorine and oxygen through the porous member into the first gas zone. The first gas zone is maintained under conditions sufficient to effect reaction therein of at least a portion of diffused oxygen and chlorine with ethane for production of ethylene. The reaction product containing the desired ethylene is discharged from the first gas zone.

    摘要翻译: 提供了通过氧化脱氢乙烷生产乙烯的方法,其中将含有乙烷的气体通入第一细长反应区,并且含有氧和氯的气体混合物进入沿着所述第一气体区定位的第二细长气体区,所述第一 并且第二气体区域被多孔构件分隔开。 第二气体区域内的气体压力保持超过第一气体区域中的压力,以使氯和氧气通过多孔构件扩散到第一气体区域中。 将第一气体区域保持在足以在其中进行至少一部分扩散的氧和氯与乙烷的反应的条件下生产乙烯。 含有所需乙烯的反应产物从第一气体区排出。

    Process for the recovery of iodine
    34.
    发明授权
    Process for the recovery of iodine 失效
    恢复碘的过程

    公开(公告)号:US3726937A

    公开(公告)日:1973-04-10

    申请号:US3726937D

    申请日:1970-11-18

    IPC分类号: C01B7/13 C07C5/44 C07C5/20

    CPC分类号: C07C5/44 C01B7/13 Y10S585/90

    摘要: A process for the recovery of iodine from the products of iodative dehydrogenation of hydrocarbons containing iodine and hydrogen iodide which consists in processing said products of dehydrogenation of hydrocarbons with an aqueous solution of sodium hydroxide, sodium carbonate or a mixture thereof until a weakly alkaline solution of iodine salts (pH 8 -10), containing iodide and iodate, is obtained. Said solution of iodine salts is electrolyzed to separately obtain the solutions of iodine and alkali, which contain undecomposed salts of iodine as well. The solution of alkali is recycled to the stage for alkali treatment of dehydrogenation products. Iodine is blown off from its solution by oxygen, an oxygen-containing gas or a mixture thereof with steam and recycled to the stage of dehydrogenation of hydrocarbons, and the solution of iodine salts free of iodine is recycled to the stage for alkali treatment of dehydrogenation products. The process is continuous. It enables complete recovery of iodine (up to 99.7 -99.9 percent), makes it possible to eliminate the formation of waste and crystalline iodine during the process as well as corrosive medium and dangerously explosive compounds.

    摘要翻译: 一种从含有碘和碘化氢的烃的碘脱氢产物中回收碘的方法,其中包括用氢氧化钠,碳酸钠或其混合物的水溶液处理所述烃的脱氢产物,直到其中的弱碱性溶液 得到含有碘化物和碘酸盐的碘盐(pH = 8-10)。 所述碘盐溶液经电解,分别得到碘和碱的溶液,其中还含有未分解的碘盐。 将碱的溶液再循环到脱氢产物的碱处理阶段。 碘由氧气,含氧气体或与蒸汽的混合物从其溶液中吹出,再循环到烃脱氢阶段,将碘盐不含碘溶液循环回到脱氢碱处理阶段 产品。