Abstract:
A salt-sensitive polymeric binder composition which includes a water soluble salt-sensitive polymer component, and a latex processing aid. The binder compositions of the invention exhibit good strength in salt solutions, yet are dispersible in the presence of water. The latex processing aid is effective to reduce the shear viscosity of the binder composition, enabling an aqueous solution of the binder to be sprayed onto an airlaid nonwoven web.
Abstract:
Wallcoverings which include a nonwoven synthetic substrate and a water-based ground coating which is applied thereto. The ground coating includes emulsion polymer pigment binders and a mineral pigment composition. The ground coating provides the nonwoven substrate with superior printing and durability properties, enabling the production of wallcoverings which may be printed with a decorative design. The wallcoverings are desirable for environmental, health, and safety reasons.
Abstract:
A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer of carboxylic acid monomer units and ethylenically unsaturated monomer units. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with base to make it water soluble. The binders provide a higher wet strength in concentrated salt solutions than in deionized water, and are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.
Abstract:
This invention relates to a process for using computerized molecular interaction modeling to predict the adhesive interactions between a substrate and a polymer. The molecular modeling method may be used to predict and select optimal adhesion promoting monomers for use in latex polymer coatings, providing the best wet adhesion to alkyd-coated substrates. The molecular modeling method could also predict substrate polymer pairs having the least affinity, and thus the most useful as a release liner. The method involves the steps of: a) identifying interacting chemical segments on both the surface and the polymer; b) generating models of the interacting segments, said models describing the spatial relationship of each atom in the segment and the connectivity between the atoms; c) merging the models of each surface segment with each polymer segment to describe each possible interacting surface/polymer pair; d) generating several hundred random configurations for each surface/polymer pair merged models, by choosing random values for the six spatial variables, that describe the relative orientations of two objects; e) optimizing the atomic coordinates of each surface/polymer segment interaction model by calculating the minimum of the molecular potential energy; f) computing the pair interaction energy for each merged model pair; g) averaging the pair interaction energies; and h) comparing the average pair interaction energies of each surface/polymer pair to choose the best pair for the intended application.
Abstract:
The invention is directed to carpet coating compositions which utilize an emulsion binder which is prepared by emulsion polymerization of ethylene, a vinyl ester monomer and a functional monomer and to carpet products prepared with the carpet coating compositions.
Abstract:
The present invention is directed to an abrasive substrate formed by the application of a polymer composition to the surface of the substrate. The polymer composition is applied to the substrate in a manner producing an uneven, structured coating on the substrate, resulting in a surface having abrasive properties. The invention is especially useful in producing abrasive non-woven materials useful as wet and dry wipes.
Abstract:
Latex paint compositions containing water, pigment and a latex wherein the latex is prepared by emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of 0.1 to 0.2 pphm of at least one hydrophobically modified starch having the structure ##STR1## In the above structure, St is a starch base material, R.sup.1 is a dimethylene or trimethylene group, R.sup.2 is selected from the group consisting of alkyl, alkenyl, aralkyl and aralkenyl groups having 2 to 20 carbon atoms, and Y is selected from the group consisting of hydrogen, alkali metal, alkaline earth metal and ammonium. The hydrophobically modified starch is the reaction product of starch and an anhydride moiety and provides the latex paint with improved rheological properties and allows for easier spreading and less dripping of paint.
Abstract:
The invention relates to an emulsion polymerization process for preparing a latex binder for use in paint. The process involves reacting a water-soluble or water-dispersible polymerizable surfactant having a terminal allyl amine moiety with at least one ethylenically unsaturated monomer and ionic monomer at a pH from about 2 to about 7. Significantly lower levels of the polymerizable surfactants are required to control the latex particle size and to stabilize the latex particles at high solids content as compared to the amount of conventional anionic surfactants used to stabilize a latex.
Abstract:
The invention relates to a pressure sensitive adhesive prepared from an aqueous emulsion polymer. The polymer is prepared by reacting at least one ethylenically unsaturated monomer and from about 0.1 to about 5 weight percent, based on the total weight of ethylenically unsaturated monomer, of a water-soluble or water-dispersible polymerizable surfactant having a terminal allyl amine moiety. The pressure sensitive adhesives may be used in all types of tapes, labels, decals, packaging, electrical insulation, and surgical bandaging.
Abstract:
Latex binders are disclosed which are used to prepare freeze-thaw-stable latex coating compositions which may be free of volatile freeze-thaw/open-time additives. The latex binders are prepared by combining a polymer which is the polymerization product of a polymerizable saccharide monomer, an acrylic monomer and, optionally, a monomer selected from styrenic monomers, ionic monomer and wet adhesion monomers. The latex coating compositions are freeze-thaw stable, even in the total absence of a volatile freeze-thaw additive, and exhibit improved open-time when compared to a latex coating composition which does not contain a volatile freeze-thaw additive. Methods for preparing the freeze-thaw-stable latex coating compositions are also disclosed.