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公开(公告)号：US4308054A
公开(公告)日：1981-12-29
申请号：US200352
申请日：1980-10-24
申请人： Yo Isogai , Soshiro Takahashi , Koichi Shudo , Toshihiko Okamoto
发明人： Yo Isogai , Soshiro Takahashi , Koichi Shudo , Toshihiko Okamoto
IPC分类号： A01N47/36 , C07D213/75 , A01N47/30
CPC分类号： C07D213/75 , A01N47/36
摘要： N-(2,6-disubstituted 4-pyridyl)-N'-phenylurea compounds are plant growth regulators having potent cytokinin activity. N-(2,6-dichloro-4-pyridyl)-N'-phenylurea is useful for regulating plant growth.
摘要翻译： N-（2,6-二取代的4-吡啶基）-N'-苯脲化合物是具有强的细胞分裂素活性的植物生长调节剂。 N-（2,6-二氯-4-吡啶基）-N'-苯基脲可用于调节植物生长。
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公开(公告)号：US4193788A
公开(公告)日：1980-03-18
申请号：US947468
申请日：1978-10-02
申请人： Koichi Shudo , Toshihiko Okamoto , Yo Isogai , Soshiro Takahashi
发明人： Koichi Shudo , Toshihiko Okamoto , Yo Isogai , Soshiro Takahashi
IPC分类号： A01N47/36 , C07D213/75 , A01N9/22 , C07D213/46 , C07D213/52 , C07D401/12
CPC分类号： C07D213/75 , A01N47/36
摘要： N-(2-Chloro-4-pyridyl)ureas represented by the formula (I): ##STR1## wherein R.sub.1 represents hydrogen or alkyl, R.sub.2 represents an aromatic group, especially phenyl, which may be substituted by alkyl, alkoxyl, hydroxyl or halogen, and X is oxygen or sulfur, and acid addition salts thereof, useful as plant growth regulators, are disclosed. Method of making and using same and agricultural compositions thereof are also disclosed.
摘要翻译： 由式（I）表示的N-（2-氯-4-吡啶基）脲：其中R 1表示氢或烷基，R 2表示芳基，特别是可被烷基取代的苯基，烷氧基 ，羟基或卤素，X是氧或硫，及其酸加成盐，可用作植物生长调节剂。 还公开了制备和使用它们的方法及其农业组合物。
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43.发明授权Curable composition and methods for improving recovery properties and creep properties 有权用于改善回收性能和蠕变性能的可固化组合物和方法公开(公告)号：US07910682B2
公开(公告)日：2011-03-22
申请号：US10533309
申请日：2003-10-22
CPC分类号： C08G65/336 , C08L101/10 , C09K3/1018
摘要： Disclosed are a curable composition characterized by using a curable composition including an organic polymer (A1) having one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds in which the one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds are silicon-containing functional groups each having three or more hydrolyzable groups on one or more silicon atoms thereof; and a method for controlling the recovery properties, durability and creep resistance of the cured article. Herewith, the present invention provides a curable composition capable of giving a cured article excellent in recovery properties, durability and creep resistance, and a method for controlling the recovery properties, durability and creep resistance of the cured article.
摘要翻译： 公开了一种可固化组合物，其特征在于使用包含具有一个或多个能够通过形成硅氧烷键交联的含硅官能团的有机聚合物（A1）的固化性组合物，其中所述一个或多个能够交叉的含硅官能团 通过形成硅氧烷键的连接是在其一个或多个硅原子上具有三个或更多个可水解基团的含硅官能团; 以及用于控制固化制品的回收性能，耐久性和抗蠕变性的方法。 因此，本发明提供了能够提供回收性，耐久性和抗蠕变性优异的固化物的固化性组合物，以及控制固化物的回收性，耐久性和抗蠕变性的方法。
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公开(公告)号：US07625990B2
公开(公告)日：2009-12-01
申请号：US11579630
申请日：2005-04-25
IPC分类号： C08G77/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： A curable composition having good curability and adhesion comprising: (A) an reactive silicon group-containing organic polymer, (B) a titanium chelate represented by the general formula (1) or (2) and (C) a high molecular weight plasticizer having a number average molecular weight of 1,000 to 15,000. General formula (1): wherein each of n R1s is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2s is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1s and (4-n) A2s is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2 or 3. General formula (2): wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 20 carbon atoms.
摘要翻译： 具有良好固化性和粘合性的可固化组合物包含：（A）含反应性硅基的有机聚合物，（B）由通式（1）或（2）表示的钛螯合物和（C）具有高分子量增塑剂 数均分子量为1,000〜15,000。 通式（1）：其中，n个R 1各自独立地为取代或未取代的碳原子数1〜20的烃基，（4-n）R 2各自独立地为氢原子或取代或未取代的碳原子数1〜20的烃基 （4-n）A1和（4-n）A2中的每一个独立地为-R 3或-OR 3，其中R 3为取代或未取代的具有1至20个碳原子的烃基，n为1,2或3.通式 （2）：其中R2，A1和A2与上述定义相同，R4为取代或未取代的碳原子数1〜20的二价烃基。
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公开(公告)号：US20090186993A1
公开(公告)日：2009-07-23
申请号：US12279466
申请日：2007-02-09
申请人： Noriko Noro , Toshihiko Okamoto , Ayako Yano , Yoshikazu Morii
发明人： Noriko Noro , Toshihiko Okamoto , Ayako Yano , Yoshikazu Morii
IPC分类号： C08G77/38
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/0016 , C08K5/31 , C08L71/02 , C08L101/10 , C08L2666/22 , C09D201/10 , C09J133/14
摘要： The present invention has its object to provide a curable composition which comprises a reactive silyl group-containing organic polymer, does not contain, as a silanol condensation catalyst, any organotin type curing catalyst currently of concern because of the toxic feature thereof, is excellent in surface curability and depth curability and, further, can provide cured products excellent in adhesiveness; the above object can be achieved by a curable composition which comprises: an organic polymer (A) containing a silicon-containing group capable of crosslinking under siloxane bond formation; and a guanidine compound (B-1), as a silanol condensation catalyst (B), represented by the general formula (1): R1N═C(NR12)2 (1) (wherein one of the five R1s is an aryl group and the other four R1s each independently is a hydrogen atom or a hydrocarbon group in which the carbon atom at position 1 is saturated).
摘要翻译： 本发明的目的是提供一种可固化组合物，其包含含有反应性甲硅烷基的有机聚合物，由于其毒性特征，目前令人关注的任何有机锡型固化催化剂不含硅烷醇缩合催化剂，因此其优异 表面固化性和深度固化性，并且还可以提供粘合性优异的固化物; 上述目的可以通过一种可固化组合物来实现，该组合物包括：含硅氧烷键形成交联的含硅基团的有机聚合物（A） 和由通式（1）表示的硅烷醇缩合催化剂（B）的胍化合物（B-1）：＆lt;＆lt;直列式说明=“In-Line Formulas”end =“lead” R1N-C（NR12）2（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中五个R1之一是芳基，另外四个R1各自独立地 是氢原子或其中第1位的碳原子饱和的烃基）。
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公开(公告)号：US20090182091A1
公开(公告)日：2009-07-16
申请号：US12279623
申请日：2007-02-09
申请人： Noriko Noro , Ayako Yano , Toshihiko Okamoto
发明人： Noriko Noro , Ayako Yano , Toshihiko Okamoto
IPC分类号： C08L83/04
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/0016 , C08K5/31 , C08L71/02 , C08L101/10 , C08L2666/22 , C09D201/10 , C09J133/14
摘要： The present invention has its object to provide a curable composition which comprises a guanidine compound as a non-organotin type catalyst, is less discolored, has good surface curability, depth curability, strength rise and adhesiveness, and can retain the curability even after storage; the above object can be achieved by a curable composition which comprises: (A) an organic polymer containing a silyl group capable of crosslinking under siloxane bond formation, the silyl group being a group represented by the general formula (1): —SiX3 (1) (wherein X represents a hydroxyl group or a hydrolyzable group and the three X groups may be mutually the same or different), (B) a guanidine compound (B-1) as a silanol condensation catalyst, and (C) a plasticizer, wherein the content of the component (B-1) is not lower than 0.1 part by weight but lower than 8 parts by weight per 100 parts by weight of the component (A), and a non-phthalate ester plasticizer accounts for 80 to 100% by weight of the (C) component plasticizer.
摘要翻译： 本发明的目的是提供一种可固化组合物，其包含作为非有机锡型催化剂的胍化合物，变色少，表面固化性，深度固化性，强度上升和粘合性，并且即使在保存后也能保持固化性; 上述目的可以通过一种可固化组合物来实现，该组合物包括：（A）含硅氧烷键形成能够交联的甲硅烷基的有机聚合物，所述甲硅烷基是由通式（1）表示的基团：-SiX 3（1 ）（其中X表示羟基或可水解基团，并且三个X基团可以相同或不同），（B）作为硅烷醇缩合催化剂的胍化合物（B-1）和（C）增塑剂， 其中组分（B-1）的含量不小于每100重量份组分（A）0.1重量份但低于8重量份，非邻苯二甲酸酯增塑剂占80至100重量份 （C）成分增塑剂的重量％。
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公开(公告)号：US20080194773A1
公开(公告)日：2008-08-14
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08F20/06 , C08F283/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好粘附性的可固化组合物。 [解决问题的方法]固化性组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆的一种或多种 催化剂，其特征在于，当通过加入和混合1.5份辛酸锡，0.25重量份月桂胺和0.6重量份纯水测定时，50％张力下的应力在0.01MPa至0.20MPa的范围内 至100重量份的组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中以不混合气泡，将混合物在23℃下老化1小时，进一步在70℃ ℃下冲洗20小时，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min） 。
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公开(公告)号：US20080021140A1
公开(公告)日：2008-01-24
申请号：US11547027
申请日：2005-03-18
IPC分类号： C08L101/10 , C08K5/09 , C08L71/02 , C08K5/47
CPC分类号： C08G65/336 , C08K5/09 , C08K5/44 , C08L71/02 , C08L101/10 , C08L2205/02 , C08L2666/02 , C08L2666/14
摘要： The present invention has its object to provide a curable composition having good curability and capable of keeping a curability and mechanical strength even after storage by using a substantially metal-free curing catalyst. The present invention provides a curable composition which comprises (A) an organic polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and (C) a polymer plasticizer.
摘要翻译： 本发明的目的是提供一种具有良好固化性的固化性组合物，即使在使用基本上无金属的固化催化剂进行保存后也能够保持固化性和机械强度。 本发明提供一种可固化组合物，其包含（A）具有通过形成硅氧烷键而能够交联的含硅基团的有机聚合物，（B）与羰基相邻的碳原子为季碳的羧酸 ，（C）聚合物增塑剂。
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公开(公告)号：US20070287780A1
公开(公告)日：2007-12-13
申请号：US11579635
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having satisfactory curability and adhesion by use of a non-tin curing catalyst, and minimizing lowering of mechanical properties of a cured article obtained after storing. [Means to Solve] A one-component type curable composition comprising (A) a polyoxyalkylene polymer (a1) having a silicon-containing group being capable of crosslinking by forming siloxane bonds and/or a (meth)acrylate polymer (a2) having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) a chelate type methyl titanate (b1) and/or a chelate type ethyl titanate (b2), and (C) a compound having, in its molecule, a hydrolyzable silicon group and a nitrogen-substituted group.
摘要翻译： [问题]提供了通过使用非锡固化催化剂具有令人满意的固化性和粘合性的可固化组合物，并且使储存后获得的固化物的机械性能降至最低。 [解决方法]一种单组分型可固化组合物，其包含（A）具有能够通过形成硅氧烷键而交联的含硅基团的聚氧化烯聚合物（a1）和/或具有（甲基）丙烯酸酯聚合物 含硅基团能够通过形成硅氧烷键交联，（B）螯合型甲基钛酸酯（b1）和/或螯合型钛酸乙酯（b2），和（C）在其分子中具有可水解的 硅基和氮取代基。
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公开(公告)号：US20060199933A1
公开(公告)日：2006-09-07
申请号：US10568616
申请日：2004-08-12
IPC分类号： C08G77/60
CPC分类号： C08K5/09 , C08G18/244 , C08L101/10 , C08L75/04
摘要： The present invention provides a curable composition including: an organic polymer (A) which has on average 1.1 to 50 groups per one molecule thereof each represented by the general formula (1) and has one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds: —NR1—C(═O)— (1) wherein R1 is a hydrogen atom, or a substituted or unsubstituted monovalent organic group; and a metal carboxylate and/or a carboxylic acid (B), the curable composition giving a cured article excellent in curability and also excellent in heat resistance although a non-organotin catalyst is used.
摘要翻译： 本发明提供一种可固化组合物，其包含：有机聚合物（A），其每一分子平均具有1.1至50个基团，各自由通式（1）表示，并且具有一个或多个能够交联的含硅官能团， 通过形成硅氧烷键进行连接：<？in-line-formula description =“In-line formula”end =“lead”→NR 1 -C（-O） - （1） 其中R 1是氢原子，或取代或未取代的一价有机基团;在式中， 和金属羧酸盐和/或羧酸（B），虽然使用非有机锡催化剂，但固化性组合物赋予固化性优异且耐热性优异的固化物。
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