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51 条记录 (耗时 0.025 秒)

    Process for preparing tertiary alkylphosphorodichloridites
    43.
    发明授权
    Process for preparing tertiary alkylphosphorodichloridites 失效
    制备叔烷基磷酸二氯化物的方法

    公开(公告)号：US4120917A

    公开(公告)日：1978-10-17

    申请号：US782271

    申请日：1977-03-28

    申请人： Kirk D. Schmitt

    发明人： Kirk D. Schmitt

    IPC分类号： C07F9/145 ,  C07F9/146

    CPC分类号： C07F9/146 ,  C07F9/145

    摘要： Tertiary alkyl phosphorodichloridites, characterized by the formula: ##STR1## where R.sup.1, R.sup.2 and R.sup.3 may be alkyl having from about 1 to about 4 carbon atoms, aryl having from about 6 to about 8 carbon atoms, or aralkyl having from about 7 to about 10 carbon atoms, however, at least one of R.sup.1, R.sup.2 and R.sup.3 must be alkyl, as new compounds, and synthesis thereof by reacting, at temperatures of 0.degree. C or less, a tertiary alcohol, a tertiary amine scavenger, and phosphorus trichloride, the PCl.sub.3 being employed in amounts in excess of the stoichiometric amount needed to react with the alcohol are provided. Both chlorines of the tertiary alkylphosphorodichloridites so produced may be relaced by RX.sup.- groups from alcohols (ROH), thiols (RSH), or amines (RR.sup.6 NH) in order that trisubstituted phosphite compounds of the formula: ##STR2## are produced. Disubstituted phosphorus acids of the formula: ##STR3## may be produced by heating the trisubstituted phosphite compounds. The RX.sup.- groups are retained as the substituents of the phosphorus acid compounds. Such phosphorus acids are extremely useful in lubricating media as antiwear agents, in insecticides and as additives in rubber.

    摘要翻译： 特征为下式的化合物：其中R 1，R 2和R 3可以是具有约1至约4个碳原子的烷基，具有约6至约8个碳原子的芳基或具有约7至约8个碳原子的芳烷基 10个碳原子，然而，R 1，R 2和R 3中的至少一个必须是烷基，作为新化合物，以及通过在0℃或更低的温度下，叔醇，叔胺清除剂和三氯化磷 提供的PCl3的用量超过与醇反应所需的化学计量量。 所产生的叔烷基二磷酸二氯的两个氯可以由醇（ROH），硫醇（RSH）或胺（RR6NH））的RX-基团所依赖，以便产生下式的三取代的亚磷酸酯化合物：。 可以通过加热三取代的亚磷酸酯化合物来制备下式的二取代的磷酸：。 RX-基保留为磷酸化合物的取代基。 这种磷酸在作为抗磨剂，杀虫剂和橡胶中的添加剂的润滑介质中非常有用。

    Synthesis of crystalline ZSM-18
    44.
    发明授权
    Synthesis of crystalline ZSM-18 失效
    结晶ZSM-18的合成

    公开(公告)号：US5350570A

    公开(公告)日：1994-09-27

    申请号：US128170

    申请日：1993-09-29

    申请人： Kirk D. Schmitt

    发明人： Kirk D. Schmitt

    IPC分类号： B01J29/70 ,  C01B39/48 ,  C01B33/34

    CPC分类号： C01B39/48 ,  B01J29/70

    摘要： This invention relates to a new form of crystalline material identified as having the structure of ZSM-18, to a new and useful method for synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g., hydrocarbon compound, conversion.

    摘要翻译： 本发明涉及一种被认为具有ZSM-18结构的新形式的结晶材料，用于合成所述结晶材料的新的和有用的方法，以及使用根据本文制备的所述结晶材料作为有机化合物的催化剂，例如 ，烃化合物，转化。

    Use of polyalkoxy sulfonate surfactants for inhibition of scale formation
    46.
    发明授权
    Use of polyalkoxy sulfonate surfactants for inhibition of scale formation 失效
    使用聚烷氧基磺酸盐表面活性剂抑制水垢的形成

    公开(公告)号：US4590996A

    公开(公告)日：1986-05-27

    申请号：US681391

    申请日：1984-12-13

    申请人： Dennis H. Hoskin ,  L. Deane Rollmann ,  Gerald L. Shoemaker ,  Kirk D. Schmitt

    发明人： Dennis H. Hoskin ,  L. Deane Rollmann ,  Gerald L. Shoemaker ,  Kirk D. Schmitt

    IPC分类号： B01F17/00 ,  C09K8/528 ,  E21B43/12

    CPC分类号： C09K8/528 ,  B01F17/0057

    摘要： The accumulation of inorganic mineral scale such as barium sulfate in oil field formations and/or production equipment is inhibited by adding to formation fluid or produced fluid a scale formation inhibitory amount of a polyalkoxy sulfonate of the general formula(RO[R'O].sub.x (CH.sub.2).sub.y SO.sub.3).sub.z Mwherein R is a hydrophobe, R'O is a C.sub.2 H.sub.4 O or a C.sub.3 H.sub.6 O group or some combination thereof, M is a monovalent or divalet cation, x is 2 to 10, y is 0 to about 4 and z is 1 or 2.

    摘要翻译： 在油田地层和/或生产设备中的无机矿物垢如硫酸钡的积累通过向地层流体或产生的流体中添加抑制量的通式（RO [R'O] x）的聚烷氧基磺酸盐 （CH 2）y SO 3）z M其中R是疏水基，R'O是C 2 H 4 O或C 3 H 6 O基团或其一些组合，M是一价或二价阳离子，x为2至10，y为0至约4，z为 1或2。

    Infrared absorption determination of sulfonate surfactants utilizing deuterated sulfonates
    48.
    发明授权
    Infrared absorption determination of sulfonate surfactants utilizing deuterated sulfonates 失效
    使用氘代磺酸盐的磺酸盐表面活性剂的红外吸收测定

    公开(公告)号：US4370146A

    公开(公告)日：1983-01-25

    申请号：US331056

    申请日：1981-12-16

    申请人： Kirk D. Schmitt

    发明人： Kirk D. Schmitt

    IPC分类号： C09K8/584 ,  E21B49/00 ,  G01N21/35 ,  E21B47/00 ,  E21B49/08

    CPC分类号： C09K8/584 ,  E21B49/00 ,  G01N21/3577 ,  Y10T436/182

    摘要： A method for determining the concentration of a brine tolerant sulfonate surfactant in a complex mixture containing, in addition to said brine tolerant sulfonate surfactant, lignosulfonates, crude oil, salts, and water and, optionally, petroleum sulfonates and alcohols, that comprises incorporating into the brine tolerant sulfonate surfactant molecule a small amount of deuterium prior to addition to the complex mixture and determining the concentration of the brine tolerant sulfonate surfactant by measuring its infrared absorption at 2150 cm.sup.-1.

    摘要翻译： 一种用于测定复合混合物中盐水耐受性磺酸盐表面活性剂浓度的方法，该混合物除了所述耐盐磺酸盐表面活性剂，木素磺酸盐，原油，盐和水以及任选的石油磺酸盐和醇之外，还包括掺入到 耐盐磺酸盐表面活性剂分配少量的氘，然后加入到复合混合物中，并通过测量盐水耐受性磺酸盐表面活性剂的浓度，测量其在2150cm-1的红外吸收。