公开(公告)号：US5621057A

公开(公告)日：1997-04-15

申请号：US455489

申请日：1995-05-31

申请人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  David Huettner ,  Walter Magee

发明人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  David Huettner ,  Walter Magee

IPC分类号： C08F283/12 ,  C08F290/00 ,  C08L83/04 ,  C08L83/07 ,  C09D4/00 ,  C08F26/00

CPC分类号： C08F283/124

摘要： Alkenyl ether-siloxane compositions comprising(A) an oligomeric or polymeric organosilicon compound having on average more than one alkenyloxy group of the formulaR.sup.2 --CH.dbd.CH--O-- (VI)(B) a monomeric maleic and/or fumaric acid compound of the formula ##STR1## in which R.sup.2 is a hydrogen atom or the methyl radical,R.sup.3 is identical or different and is a hydrogen atom, a hydrocarbon radical having 1 to 16 carbon atoms, which can be interrupted by oxygen, sulfur or oxygen- or silicon-containing units, a substituted hydrocarbon radical having 1 to 6 carbon atoms, a silyl radical or a siloxanyl radical,R.sup.4 is identical or different and is a hydrogen atom, chlorine, bromine, fluorine or an optionally substituted alkyl radical andZ is an oxygen atom or a radical --NR.sup.5 --, where R.sup.5 has one of the meanings given for R.sup.3,optionally(C) initiators which form free radicals and optionally(D) inhibitors for regulating the pot life.

摘要翻译： 烯基醚 - 硅氧烷组合物，其包含（A）具有平均多于一个式R 2 -CH = CH-O-（VI）的烯氧基的低聚或聚合有机硅化合物（B）（B）单体马来酸和/或富马酸化合物 该式为氢原子或甲基，R3相同或不同，为氢原子，可被氧，硫或含氧或含硅单元中断的碳原子数为1〜16的烃基， 具有1至6个碳原子的取代烃基，甲硅烷基或硅氧烷基，R4相同或不同，为氢原子，氯，溴，氟或任选取代的烷基，Z为氧原子或基团 - NR5-，其中R5具有R3给出的含义之一，任选的（C）引发剂，其形成自由基和任选的（D）抑制剂以调节适用期。

公开(公告)号：US5468890A

公开(公告)日：1995-11-21

申请号：US244920

申请日：1994-06-08

申请人： Christian Herzig ,  Silke Scheiding

发明人： Christian Herzig ,  Silke Scheiding

IPC分类号： C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C07F5/02 ,  C07F9/00

CPC分类号： C07F7/0818

摘要： The invention concerns iodonium salts of the general formula A-I.sup.+ --B X.sup.-, in which A is a group of the general formula ##STR1## in which C is a monovalent aromatic hydrocarbon group with 6 to 14 carbon atoms or a monovalent aromatic hydrocarbon group containing at least one oxygen and/or sulphur atom and with 5 to 14 atoms in the aromatic ring, D, E and F are each substituents of C, D being a group of the formula --(O).sub.x --(R).sub.y --SiR1/3, E being a group of the formula --OR.sup.2, F being a group of the formula --R.sup.3, a being 1, 2, or 3, b being 0, 1 or 2, c being 0, 1 or 2, x being 0 or 1 and y being 0 or 1, and R, R.sup.1, R.sup.2 and R.sup.3 are as defined in claim 1; B is a group of the formula ##STR2## in which E and F, which are as defined above, may each be bound to the 2, 3, 4, 5 or 6 position in the benzene ring, d is 0, 1 or 2, e is 0, 1 or 2 and X.sup.- is a tosylate anion or a weakly nucleophilic or non-nucleophilic anion Y.sup.- selected from the group comprising CF.sub.3 CO.sub.2.sup.-, BF.sub.4.sup.-, PF.sub.4.sup.-, AsF.sub.6.sup.-, SbF.sub.6.sup.-, ClO.sub.4.sup.-, HSO.sub.4.sup.- and CF.sub.3 SO.sub.3.sup.-.

摘要翻译： PCT No.PCT / EP92 / 02932 Sec。 371日期：1994年6月8日 102（e）日期1994年6月8日PCT提交1992年12月17日PCT公布。 公开号WO93 / 13110PC。 日本时间1993年7月8日。本发明涉及通式为A-1 + -B X-的碘鎓盐，其中A为通式（IMAGE）（1）的基团，其中C为单价芳族烃基， 6至14个碳原子或含有至少一个氧原子和/或硫原子并且芳环中具有5至14个原子的单价芳族烃基，D，E和F各自为C的取代基，D为式 - （O）x - （R）y -SiR1 / 3，E是式-OR2的基团，F是式-R3的基团，a是1,2或3，b是0,1或 2，c为0,1或2，x为0或1，y为0或1，R，R1，R2和R3如权利要求1所定义; B是式（2）中的基团，其中如上所定义的E和F各自可以与苯环中的2,3,4,5或6位相连，d为0， 1或2，e为0,1或2，X为甲苯磺酸根阴离子或弱亲核或非亲核阴离子Y-，选自CF 3 CO 2 - ，BF 4 - ，PF 4 - ，AsF 6 - ，SbF 6 - ，ClO 4 - ，HSO4-和CF3SO3-。

公开(公告)号：US5162452A

公开(公告)日：1992-11-10

申请号：US530388

申请日：1990-05-30

申请人： Christian Herzig ,  Bernward Deubzer ,  Josef Esterbauer

发明人： Christian Herzig ,  Bernward Deubzer ,  Josef Esterbauer

IPC分类号： C08K5/10 ,  C08K5/17 ,  C08L83/04 ,  C08L83/08 ,  C08L101/00 ,  C08L101/06 ,  C09D183/04 ,  C09D183/08

CPC分类号： C09D183/08 ,  C08L83/08

摘要： The Thermocurable compositions which contain(A) at least one mercaptoalkyl-containing compound which contains at least two SiC-bonded radicals per molecule of the general formulaHS--R.sup.2 -- (I) where R.sup.2 represents a divalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, selected from the group consisting mercaptoalkyl-containing organopolysiloxanes and cocondensates of mercaptoalkyl-containing organosilicon compounds containing groups capable of condensation, and hydroxyl-containing organic compounds,(B) at least one vinyl-containing compound which is compatible with constituent (A) and contains at least two groups per molecule of the general formulaR.sup.4 CH.dbd.CR.sup.3 C(O)O-- (II) where R.sup.3 represents a hydrogen atom or a methyl radical, and R.sup.4 represents a hydrogen atom or an alkyl radical having from 1 to 3 carbon atom(s) per radical, and(C) a mixture of a strong organic base selected from the group consisting of quaternary ammonium hydroxides, quaternary ammonium alkoxides, tertiary, secondary and primary amines, and a weak protonic acid.

摘要翻译： 含有（A）至少一种含巯基烷基的化合物的热固性组合物，其每分子具有通式HS-R2-（I）中至少两个SiC键合的基团，其中R2表示具有1至8个碳原子的二价烃基 每个基团的原子选自含巯基烷基的有机聚硅氧烷和含有缩合基团的含巯基烷基的有机硅化合物的缩聚物和含羟基的有机化合物，（B）至少一种含乙烯基的化合物，其相容 与组分（A）组成，每分子含有至少两个通式为R 4 CH = CR 3 C（O）O-（II）的基团，其中R 3表示氢原子或甲基，R 4表示氢原子或具有 每个基团具有1至3个碳原子，和（C）选自下列的强有机碱的混合物：季铵氢氧化物，季铵醇盐，te 仲胺和伯胺，以及弱质子酸。

公开(公告)号：US5151473A

公开(公告)日：1992-09-29

申请号：US609680

申请日：1990-11-06

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C08G77/38 ,  C08G77/392

CPC分类号： C08G77/38 ,  C08G77/392

摘要： The invention relates to novel organopolysiloxanes which contain sulfosuccinate groups and consist of average units of the general formula ##EQU1## in which R is the same or different monovalent hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical or monovalent halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, Z is a radical of the formula ##STR1## in which Y represents a radical of the formula ##STR2## R.sup.1 is a hydrogen atom or an alkyl radical having from 1 to 4 carbon atom(s) per radical, M.sup.+ represents a hydrogen ion and/or an alkali metal ion or an ammonium ion, a is 0 or 1, with an average of from 0.03 to 1.0, b is 0, 1, 2 or 3, with an average of from 1.0 to 2.5, and the sum of a+b is no greater than 3, with the proviso that the compound contains at least one radical Z per molecule.

摘要翻译： 本发明涉及含有磺基琥珀酸盐基团并由通式（I）的平均单元组成的新的有机聚硅氧烷，其中R是每个基团具有1至18个碳原子的相同或不同的一价烃基或单价 每个基团具有1至18个碳原子的卤代烃基，Z是下式的基团，其中Y表示下式的基团R 1是氢原子或具有1个 至4个碳原子，M +表示氢离子和/或碱金属离子或铵离子，a为0或1，平均为0.03至1.0，b为0,1,2或 3，平均为1.0〜2.5，a + b的总和为3以下，条件是该化合物每分子含有至少一个基团Z。

公开(公告)号：US5134203A

公开(公告)日：1992-07-28

申请号：US691912

申请日：1991-04-26

申请人： Friedrich Hockemeyer ,  Christian Herzig

发明人： Friedrich Hockemeyer ,  Christian Herzig

IPC分类号： C08L83/05 ,  C08L83/06 ,  C08L83/07 ,  C08L83/08 ,  C09D183/04 ,  C09D183/06 ,  C09D183/07 ,  C09D183/08 ,  C09J7/02 ,  C09J183/00 ,  C09J183/07 ,  D21H19/32 ,  D21H27/00 ,  D21H27/06

CPC分类号： D21H27/001 ,  C08L83/06 ,  C08L83/08 ,  C09D183/06 ,  C09D183/08 ,  D21H19/32 ,  D21H27/06

摘要： Crosslinkable compositions containing(1) An organopolysiloxane having alkenyloxy functional groups and containing Si-bonded radicals Y of the formula--(CH.sub.2).sub.2 --R.sup.1 --(A--R.sup.2).sub.z --O--R.sup.3 --CH.dbd.CH.sub.2, in whichA represents --O--, --S--or ##STR1## group, R.sup.1 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical of a cycloalkylene radical having from 5 to 7 carbon atoms per radical,R.sup.2 represents a straight-chain or branched alkylene radical having from 2 to 4 carbon atoms per radical, which can be substituted by a hydroxyl group, methoxy group, ethoxy group or trimethylsiloxy group,R.sup.3 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical, and z is 0, 1 or 2,(2) an organopolysiloxane containing Si-bonded hydrogen atoms, and(3) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.

摘要翻译： 含有（1）具有烯氧基官能团并含有式 - （CH 2）2 -R 1 - （A-R 2）z O-R 3 -CH = CH 2的Si键合基团Y的有机聚硅氧烷的交联组合物，其中A表示-O- ，-S-或基团，R 1表示每个基团具有5至7个碳原子的环亚烷基基团具有1至7个碳原子的直链或支链亚烷基，R 2表示直链或 每个基团具有2至4个碳原子的支链亚烷基，其可被羟基，甲氧基，乙氧基或三甲基甲硅烷氧基取代，R 3表示每个基团具有1至7个碳原子的直链或支链亚烷基 ，z为0,1或2，（2）含有Si键合的氢原子的有机聚硅氧烷，（3）促进将Si键合的氢加成脂肪族双键的催化剂。

公开(公告)号：US5118772A

公开(公告)日：1992-06-02

申请号：US718688

申请日：1991-06-21

申请人： Christian Herzig ,  Doris Gilch

发明人： Christian Herzig ,  Doris Gilch

IPC分类号： C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C08G77/20 ,  C08G77/22 ,  C08G77/38

CPC分类号： C07F7/182 ,  C07F7/0852 ,  C07F7/12 ,  C07F7/1892 ,  C08G77/38

摘要： Novel, alkenyloxy-functional organosilicon compounds are described which contain at least one Si-bonded Y radical per molecule having the formula--(CH.sub.2).sub.2 --R.sup.2 --(A--R.sup.3).sub.z --O--CH.dbd.CH--CH.sub.2 --R.sup.4 (I),in whichA represents --O--, --S-- or ##STR1## R.sup.2 represents a linear or branched alkylene radical having from 1 to 7 carbon atom(s) per radical or a cycloalkylene radical having from 5 to 7 carbon atoms per radical, R.sup.3 represents a linear or branched alkylene radical having from 2 to 4 carbon atoms per radical, which may be substituted by a hydroxyl group, methoxy group, ethoxy group or trimethylsiloxy group, R.sup.4 represents a hydrogen atom or an alkyl radical having from 1 to 4 carbon atoms(s) per radical, and z is 0, 1 or 2.The alkenyloxy-functional organosilicon compounds are preferably silanes or organopolysiloxanes.The alkenyloxy-functional organopolysiloxanes can be crosslinked, for example, with ultraviolet light. These organopolysiloxanes can also be used for preparing coatings.

公开(公告)号：US5113006A

公开(公告)日：1992-05-12

申请号：US594791

申请日：1990-10-09

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08G77/20 ,  C08G77/38 ,  C08L83/06 ,  C08L83/07 ,  C09D183/04 ,  C09D183/07

CPC分类号： C08G77/38 ,  C07F7/0852 ,  C07F7/1836 ,  C08G77/20 ,  C08L83/06

摘要： Novel organosilicon compounds containing alkenyl groups and comprising units of the average formula ##STR1## in which R and R.sup.1 are hydrocarbon containing groups, and A is a radical of the formula ##STR2## in which R.sup.2, R.sup.3 and R.sup.4 are hydrocarbon containing groups; x is 0 or 1; y is 0 or 1, with the proviso that the sum x+y is 1 or 2; a is 0 or 1, with an average of 0.003 to 1.0; b is 0, 1, 2 or 3, with an average of 0.0 to 3.0; c is 0, 1, 2 or 3; with an average of 0.0 to 3.0; and the sum a+b+c.ltoreq.4, with an average of 1.5 to 4.0, with the proviso that each molecule contains at least one A radical and a method for preparation of the novel compounds are disclosed.

摘要翻译： 含有烯基的新型有机硅化合物，其包含平均结构式（I）的单元，其中R和R 1为含烃基团，A为下式的基团，其中R 2，R 3和R 4为含烃基 团体 x为0或1; y为0或1，条件是和x + y为1或2; a为0或1，平均为0.003〜1.0; b为0,1,2或3，平均为0.0〜3.0; c为0,1,2或3; 平均为0.0〜3.0; 并且总和a + b + c = 4，平均为1.5至4.0，条件是每个分子含有至少一个A基团和制备新化合物的方法。

公开(公告)号：US5041594A

公开(公告)日：1991-08-20

申请号：US555218

申请日：1990-07-20

申请人： Christian Herzig

发明人： Christian Herzig

IPC分类号： C07F7/08 ,  C08G77/06 ,  C08G77/10 ,  C08G77/20 ,  C08G77/22 ,  C08G77/38

CPC分类号： C08G77/38 ,  C08G77/20

摘要： Organo(poly)siloxanes having Si-linked, conjugated dienyl groups are prepared by adding a secondary or tertiary acetylenic alcohol (1) to an organo(poly)siloxane (2) having at least one Si-linked hydrogen atom in the presence of a catalyst (3) which promotes the addition of Si-linked hydrogen to an aliphatic multiple bond, and then eliminating water by an intramolecular reaction in the presence of an acid catalyst (4) from the alkenol groups of the organo(poly)siloxane thus obtained.

摘要翻译： 具有Si连接的共轭二烯基的有机（聚）硅氧烷通过在具有至少一个Si连接的氢原子的有机（多）硅氧烷（2）中，在 催化剂（3），其促进将Si连接的氢加成脂族多重键，然后在由这样得到的有机（聚）硅氧烷的烯醇基团的酸催化剂（4）存在下通过分子内反应除去水 。

公开(公告)号：US4795823A

公开(公告)日：1989-01-03

申请号：US20902

申请日：1987-03-02

申请人： Werner Schmitt ,  Peter Jochum ,  Wolf-Dietrich Zahler ,  Heijo Hubner ,  Manfred Holupirek ,  Oswald Gasser ,  Christian Herzig

发明人： Werner Schmitt ,  Peter Jochum ,  Wolf-Dietrich Zahler ,  Heijo Hubner ,  Manfred Holupirek ,  Oswald Gasser ,  Christian Herzig

IPC分类号： C07C69/708 ,  A61K6/08 ,  A61K6/083 ,  C08F20/10 ,  C08F20/26 ,  C08F20/28 ,  C08F220/28 ,  C07C69/66

CPC分类号： A61K6/083 ,  Y10S522/908

摘要： (Methy)acrylic acid esters of the general formula(Mo).sub.n --[--A--O--CO--CH.sub.2 --O--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CO--O--].sub.x --A--(OM).sub.nare described whereinA is an alcohol radical having at least 4 chain atoms between two junction sites.M is CH.sub.2 .dbd.C(R.sup.1)--CO wherein R.sup.1 stands for hydrogen or methyl,n is 1 or 2, andx is 0.3 to 3.These esters are suited for the preparation of dental compositions.

摘要翻译： （Mo）n - [ - AO-CO-CH2-O-CH2-CH2-O-CH2-CO-O-] xA（OM）n的（甲基）丙烯酸酯，其中A是 在两个连接位点之间具有至少4个链原子的醇基。 M为CH 2 = C（R 1）-CO，其中R 1代表氢或甲基，n为1或2，x为0.3至3.这些酯适于制备牙科用组合物。

公开(公告)号：US08084566B2

公开(公告)日：2011-12-27

申请号：US13129159

申请日：2009-11-16

申请人： Holger Rautschek ,  Elisabeth Brehm ,  Christian Herzig

发明人： Holger Rautschek ,  Elisabeth Brehm ,  Christian Herzig

IPC分类号： C08G77/46 ,  C08G77/04 ,  C08G18/06 ,  C11D3/20

CPC分类号： B01D19/0404 ,  B01D19/0409 ,  C08G77/445 ,  C08G77/448 ,  C08G77/458 ,  C08G77/46 ,  C08L83/08 ,  C08L83/12 ,  C11D3/0026 ,  C11D3/373 ,  C11D3/3742 ,  C08L83/00

摘要： Mixtures of silicone resin with an organopolysiloxane copolymer prepared by hydrosilylating a substantially linear polymer containing an isocyanate reactive group with an Si—H containing organopolysiloxane, and reacting this intermediate with a diisocyanate, are useful as long lasting defoamers which are compatible with numerous media.

摘要翻译： 有机硅树脂与通过将含有异氰酸酯反应性基团的基本上线性的聚合物与含Si-H的有机聚硅氧烷氢化并使其与二异氰酸酯反应制备的有机聚硅氧烷共聚物的混合物可用作与多种介质相容的长效消泡剂。