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    PROCESS FOR THE SYNTHESIS OF DMAPA
    42.
    发明申请
    PROCESS FOR THE SYNTHESIS OF DMAPA 有权
    合成DMAPA的方法

    公开(公告)号：US20100105952A1

    公开(公告)日：2010-04-29

    申请号：US12683015

    申请日：2010-01-06

    申请人： Martin Ernst ,  Steffen Oehlenschläger ,  Frank Kuhnke ,  Karl-Heinz Roß ,  Roland Deeg ,  Johann-Peter Melder

    发明人： Martin Ernst ,  Steffen Oehlenschläger ,  Frank Kuhnke ,  Karl-Heinz Roß ,  Roland Deeg ,  Johann-Peter Melder

    IPC分类号： C07C209/02 ,  B01J19/00

    CPC分类号： C07C209/48 ,  B01J2219/00006 ,  C07C253/30 ,  C07C211/11 ,  C07C255/24

    摘要： The present invention relates to a process for the industrial preparation of a diamine starting from a corresponding alkenyl nitrile comprising at least one C—C double bond, which comprises the steps (a) reaction of the alkenyl nitrile with a corresponding monoamine in a first reactor so that the monoamine adds exothermically onto the at least one double bond to form an aminoalkyl nitrile, with the monoamine and water being charged initially and the alkenyl nitrile being fed in; (b) evaporation of unreacted alkenyl nitrile and monoamine to increase the concentration of the aminoalkyl nitrile product in the bottoms of the first reactor; (c) transfer of the aminoalkyl nitrile bottom product from step (b) to a second reactor; (d) batchwise catalytic hydrogenation of the aminoalkyl nitrile transferred in step (c) to the diamine in the second reactor, with each batch being obtained by initially charging a catalyst suitable for the hydrogenation of nitriles to amines and also water, the desired diamine and a base, introducing hydrogen into the second reactor and feeding in the aminoalkyl nitrile transferred in step (c); and (e) isolation of the diamine and, if appropriate, repetition of the steps (a) to (e). The invention further relates to an apparatus for preparing these diamines and the use of the apparatuses. A preferred diamine is 3-dimethylaminopropylamine (DMAPA).

    摘要翻译： 本发明涉及从包含至少一个C-C双键的相应链烯基腈开始工业制备二胺的方法，其包括步骤（a）在第一反应器中烯基腈与相应的单胺反应 使得单胺在至少一个双键上放热添加以形成氨基烷基腈，最初加入单胺和水，并加入链烯基腈; （b）蒸发未反应的烯基腈和单胺以增加第一反应器底部氨基烷基腈产物的浓度; （c）将氨基烷基腈底部产物从步骤（b）转移至第二反应器; （d）将步骤（c）中转移的氨基烷基腈分批催化氢化为第二反应器中的二胺，每个批次通过首先将适合于将腈氢化成的催化剂加入到胺中而得到，并且还需要水，所需的二胺和 碱，将氢气引入第二反应器并进料步骤（c）中转移的氨基烷基腈; 和（e）分离二胺，如果合适，重复步骤（a）至（e）。 本发明还涉及一种用于制备这些二胺的装置和该装置的用途。 优选的二胺是3-二甲基氨基丙胺（DMAPA）。

    Method for the production of β-aminopropionic acid derivatives
    44.
    发明授权
    Method for the production of β-aminopropionic acid derivatives 有权
    生产氨基丙酸衍生物的方法

    公开(公告)号：US07674929B2

    公开(公告)日：2010-03-09

    申请号：US12066681

    申请日：2006-09-13

    申请人： Holger Evers ,  Johann-Peter Melder ,  Thomas Preiss ,  Harald Meissner

    发明人： Holger Evers ,  Johann-Peter Melder ,  Thomas Preiss ,  Harald Meissner

    IPC分类号： C07C255/00

    CPC分类号： C07C253/30 ,  C07B43/04 ,  C07C227/06 ,  C07C2601/14 ,  C07C255/24

    摘要： The invention relates to a process for preparing β-aminopropionic acid derivatives by reacting a primary or secondary amine with an acrylic acid derivative, wherein comprises (i) a first primary or secondary amine is provided as an amine of value and reacted with the acrylic acid derivative, to obtain a reaction mixture comprising a first β-aminopropionic acid derivative as a product of value and additionally unconverted acrylic acid derivative, (ii) the unconverted acrylic acid derivative present in the reaction mixture is reacted with a second secondary amine as a scavenger amine virtually fully to give a second β-aminopropionic acid derivative to obtain a reaction mixture comprising the first β-aminopropionic acid derivative as a product of value, the second β-aminopropionic acid derivative and unconverted secondary amine.

    摘要翻译： 本发明涉及一种通过使伯胺或仲胺与丙烯酸衍生物反应来制备β-氨基丙酸衍生物的方法，其中包括（i）第一伯胺或仲胺作为有价值的胺并与丙烯酸反应 酸衍生物，得到包含第一和次氨基丙酸衍生物作为值的产物和另外未转化的丙烯酸衍生物的反应混合物，（ii）将存在于反应混合物中的未转化的丙烯酸衍生物与第二仲胺反应， 一种清除剂胺实际上完全可以得到第二种 - 氨基丙酸衍生物，以获得包含第一种和第二种 - 氨基丙酸衍生物和未转化的仲胺的第一种 - 氨基丙酸衍生物的反应混合物。

    Process for Producing Ethyleneamines
    48.
    发明申请
    Process for Producing Ethyleneamines 有权
    生产乙烯胺的方法

    公开(公告)号：US20080255360A1

    公开(公告)日：2008-10-16

    申请号：US12088715

    申请日：2006-09-25

    申请人： Gunther van Cauwenberge ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach ,  Frank Kiesslich ,  Ekkehard Schwab ,  Bram Willem Hoffer

    发明人： Gunther van Cauwenberge ,  Johann-Peter Melder ,  Holger Evers ,  Till Gerlach ,  Frank Kiesslich ,  Ekkehard Schwab ,  Bram Willem Hoffer

    IPC分类号： C07C209/14 ,  C07D295/023 ,  C07D241/04

    CPC分类号： C07C209/16 ,  B01J21/04 ,  B01J23/755 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/18 ,  C07D295/02 ,  C07D295/13 ,  C07C211/10 ,  C07C211/14

    摘要： Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of

    摘要翻译： 方法包括：提供包含单乙醇胺的原料; 并在非均相过渡金属催化剂的存在下使原料与氨反应形成包含一种或多种亚乙基胺的反应产物; 其中所述催化剂包含催化活性组合物，其在用氢处理之前包括铝，铜，镍和钴的含氧化合物的混合物; 并且其中所述催化剂作为选自球体，挤出物，丸粒和其它几何形状的一种或多种成型催化剂颗粒存在，其中所述球体或挤出物的直径<3mm，所述颗粒具有<3mm的高度，而另一种 几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mm×s×2 / 由 定义的 3 MI> a = A / MSUB> V p 其中A < SUB>是催化剂颗粒的外表面积（mm 2），V p是催化剂颗粒的体积（mm 3） 3＆lt; 3＆gt; 3＆lt; 3＆gt;）。

      Process for the continuous synthesis of methylamines
      49.
      发明授权
      Process for the continuous synthesis of methylamines 有权
      连续合成甲胺的方法

      公开(公告)号：US07435855B2

      公开(公告)日：2008-10-14

      申请号：US11629801

      申请日：2005-06-16

      申请人： Marco Bosch ,  Jan Kurt Eberhardt ,  Roderich Röttger ,  Thomas Krug ,  Johann-Peter Melder

      发明人： Marco Bosch ,  Jan Kurt Eberhardt ,  Roderich Röttger ,  Thomas Krug ,  Johann-Peter Melder

      IPC分类号： C07C209/14

      CPC分类号： C07C209/16 ,  C07C211/04

      摘要： Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the steps (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.

      摘要翻译： 在多相催化剂存在下，通过甲醇和/或二甲醚与氨的反应连续合成甲胺的方法，其中使用的催化剂是成形体，其包含微孔材料和至少一种有机硅化合物作为粘合剂，并且可以是 通过包括步骤（I）制备包含微孔材料，粘合剂，粘贴剂和溶剂的混合物的方法制备的方法制备，（II）混合和混合物的致密化，（III）使致密混合物成形，得到 （IV）成型体的干燥和（V）干燥成型体的煅烧。

      Method for the Production of Beta-Aminopropionic Acid Derivatives
      50.
      发明申请
      Method for the Production of Beta-Aminopropionic Acid Derivatives 有权
      β-氨基丙酸衍生物的制备方法

      公开(公告)号：US20080249333A1

      公开(公告)日：2008-10-09

      申请号：US12066681

      申请日：2006-09-13

      申请人： Holger Evers ,  Johann-Peter Melder ,  Thomas Preiss ,  Harald Meissner

      发明人： Holger Evers ,  Johann-Peter Melder ,  Thomas Preiss ,  Harald Meissner

      IPC分类号： C07C229/02

      CPC分类号： C07C253/30 ,  C07B43/04 ,  C07C227/06 ,  C07C2601/14 ,  C07C255/24

      摘要： The invention relates to a process for preparing β-aminopropionic acid derivatives by reacting a primary or secondary amine with an acrylic acid derivative, wherein comprises (i) a first primary or secondary amine is provided as an amine of value and reacted with the acrylic acid derivative, to obtain a reaction mixture comprising a first β-aminopropionic acid derivative as a product of value and additionally unconverted acrylic acid derivative, (ii) the unconverted acrylic acid derivative present in the reaction mixture is reacted with a second secondary amine as a scavenger amine virtually fully to give a second β-aminopropionic acid derivative to obtain a reaction mixture comprising the first β-aminopropionic acid derivative as a product of value, the second β-aminopropionic acid derivative and unconverted secondary amine.

      摘要翻译： 本发明涉及通过使伯胺或仲胺与丙烯酸衍生物反应来制备β-氨基丙酸衍生物的方法，其中包括（i）第一伯胺或仲胺作为有价值的胺并与丙烯酸反应 衍生物，以获得包含作为有价值的产物的第一β-氨基丙酸衍生物和另外未转化的丙烯酸衍生物的反应混合物，（ii）反应混合物中存在的未转化的丙烯酸衍生物与作为清除剂的第二仲胺反应 胺实际上完全提供第二β-氨基丙酸衍生物以获得包含第一β-氨基丙酸衍生物作为有价值的产物，第二β-氨基丙酸衍生物和未转化的仲胺的反应混合物。