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公开(公告)号：US20070060780A1
公开(公告)日：2007-03-15
申请号：US11472155
申请日：2006-06-21
CPC分类号： B01J29/80 , B01J27/1804 , B01J29/084 , B01J29/40 , B01J29/7007 , B01J37/0045 , B01J2229/42 , C10G2400/22
摘要： The invention comprises a catalyst composition comprising a pentasil type of zeolite, one or more solid acidic promoters, an additional material selected from the group consisting of an anionic clay, smectite clay, and thermally or chemically modified clay, and optionally a filler and/or binder, methods for making the catalyst composition and a process for using the catalyst in the manufacture of olefins.
摘要翻译： 本发明包括催化剂组合物，其包含pentasil型沸石，一种或多种固体酸性促进剂，选自阴离子粘土，蒙脱石粘土和热或化学改性的粘土的另外的材料，以及任选的填料和/或 粘合剂，制备催化剂组合物的方法和使用该催化剂制备烯烃的方法。
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42.发明授权Process for the preparation of doped pentasil-type zeolite using doped seeds 有权使用掺杂种子制备掺杂的pentasil型沸石的方法公开(公告)号：US06964934B2
公开(公告)日：2005-11-15
申请号：US10647854
申请日：2003-08-25
申请人： Mike Brady , Erik Jeroen Laheij , Paul O'Connor , Dennis Stamires
发明人： Mike Brady , Erik Jeroen Laheij , Paul O'Connor , Dennis Stamires
CPC分类号： B01J29/405 , B01J2229/62 , C01B39/36 , C01B39/38 , C01B39/40
摘要： The present invention relates to a process for the preparation of doped pentasil-type zeolite, which process comprises the steps of: a) preparing an aqueous precursor mixture from a silicon source, an aluminium source, and doped non-zeolitic seeds; and b) thermally treating the precursor mixture to form a doped pentasil-type zeolite. The term “non-zeolitic seeds” includes seeds made from materials selected from the group consisting of (i) X-ray amorphous materials, (ii) milled crystalline materials, such as milled zeolites, that have a relative crystallinity of not more than 75%, and (iii) crystalline materials other than zeolites, such as clays (e,g, bentonite and kaolin) and (low) crystalline aluminas.
摘要翻译： 本发明涉及一种制备掺杂的pentasil型沸石的方法，该方法包括以下步骤：a）从硅源，铝源和掺杂的非沸石种子制备水性前体混合物; 和b）热处理前体混合物以形成掺杂的pentasil型沸石。 术语“非沸石种子”包括由选自以下的材料制成的种子：（i）X射线无定形材料，（ii）研磨的结晶材料，例如研磨的沸石，其相对结晶度不大于75 ％，和（iii）沸石以外的结晶材料，例如粘土（e，g，膨润土和高岭土）和（低）结晶氧化铝。
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43.发明授权Method for performing a Fischer-Tropsch process using an iron-containing layered material 失效使用含铁层状材料进行费 - 托工艺的方法公开(公告)号：US06933324B2
公开(公告)日：2005-08-23
申请号：US10637787
申请日：2003-08-08
IPC分类号： B01J23/00 , B01J23/745 , B01J23/78 , C10G2/00 , C07C27/00
CPC分类号： B01J23/007 , B01J23/745 , B01J23/78 , C10G2/332
摘要： A method for performing a Fischer-Tropsch process using as a catalyst (precursor) an iron-containing layered material selected from the group consisting of layered materials in which iron is present in the layered structure as divalent and/or trivalent metal (group 1), iron-doped layered materials (group 2), calcined iron-doped layered materials (group 3), and calcined layered materials in which iron is present in the layered structure as divalent metal (group 4). The term “layered material” includes anionic clays, layered hydroxy salts, cationic clays, and cationic layered materials.
摘要翻译： 作为催化剂（前体）进行费 - 托法的方法，所述含铁层状材料选自层状材料，其中铁作为二价和/或三价金属存在于层状结构中（组1） ，铁掺杂层状材料（组2），煅烧铁掺杂层状材料（组3）和煅烧层状材料，其中铁作为二价金属存在于层状结构中（组4）。 术语“层状材料”包括阴离子粘土，层状羟基盐，阳离子粘土和阳离子层状材料。
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44.发明授权公开(公告)号：US06589902B1
公开(公告)日：2003-07-08
申请号：US09636695
申请日：2000-08-11
申请人： Dennis Stamires , Paul O'Connor
发明人： Dennis Stamires , Paul O'Connor
IPC分类号： B01J2110
摘要： The present invention is directed to a process for the preparation of crystalline anionic clay-containing bodies from sources comprising an aluminum source and a magnesium source comprising the steps of: a) preparing a precursor mixture, b) shaping the precursor mixture to obtain shaped- bodies, c) optionally thermally treating the shaped bodies, and d) aging to obtain crystalline anionic clay-containing bodies. The quintessence of the present invention is that the bodies are shaped prior to the forming of the crystalline anionic clay in said bodies. This results in very attrition resistant bodies, without the need to add a binder material.
摘要翻译： 本发明涉及从包含铝源和镁源的源制备含结晶阴离子粘土的物质的方法，包括以下步骤：a）制备前体混合物，b）使前体混合物成形， 主体，c）任选地热处理成形体，并且d）老化以获得结晶阴离子含粘土的物质。本发明的精髓在于，在所述体内形成结晶阴离子粘土之前，将物体成型。 这导致非常耐磨损的体，而不需要添加粘合剂材料。
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公开(公告)号：US08552233B2
公开(公告)日：2013-10-08
申请号：US13140053
申请日：2009-12-16
申请人： Dennis Stamires , Paul O'Connor
发明人： Dennis Stamires , Paul O'Connor
IPC分类号： C07C1/00
CPC分类号： C10L9/10 , C10G2300/1011 , C10L1/026 , Y02P30/20
摘要： A composition of matter is described herein that can be subjected to pyrolysis and converted into a bio-oil. The composition comprises an intimate mixture of a particulate solid biomass material and a carbonaceous material. The carbonaceous material acts as a reducing agent during the pyrolysis reaction. The composition of matter produces bio-oil in a greater yield than prior art processes. The bio-oil is of improved quality, as evidenced by its low TAN value.
摘要翻译： 本文描述了可以经受热解并转化为生物油的物质组合物。 组合物包含颗粒状固体生物质材料和含碳材料的紧密混合物。 碳质材料在热解反应期间用作还原剂。 物质的组成比现有技术的方法产生更大的产量的生物油。 生物油质量提高，其TAN值低。
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公开(公告)号：US08323458B2
公开(公告)日：2012-12-04
申请号：US12373745
申请日：2007-07-13
申请人： Paul O'Connor , Dennis Stamires
发明人： Paul O'Connor , Dennis Stamires
IPC分类号： B01J19/12
摘要： A process is disclosed for making a biomass susceptible to depolymerization or liquefaction under mild conditions. The process comprises introducing into the biomass a material susceptible to the absorption of electro-magnetic radiation to form a radiation absorbent biomass. The radiation absorbent biomass is subjected to electro-magnetic radiation to form an activated biomass.
摘要翻译： 公开了一种用于使生物质在温和条件下易于解聚或液化的方法。 该方法包括将易受吸收电磁辐射影响的材料引入生物质以形成辐射吸收生物质。 对辐射吸收生物质进行电磁辐射以形成活化的生物质。
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公开(公告)号：US08288600B2
公开(公告)日：2012-10-16
申请号：US12917988
申请日：2010-11-02
申请人： Robert Bartek , Michael Brady , Dennis Stamires , Steve Yanik , Paul O'Connor , Jacobus Cornelius Rasser
发明人： Robert Bartek , Michael Brady , Dennis Stamires , Steve Yanik , Paul O'Connor , Jacobus Cornelius Rasser
IPC分类号： C10L1/00
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. to 400° C. to form particulated biomass having a mean average particle size between 1 μm and 1000 μm. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes from 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit, and then at least a portion of the particulated biomass of the suspension is converted into fuel.
摘要翻译： 本文公开了一种从生物质生产燃料的方法。 该方法包括在80℃至400℃的温度下焙烧生物质材料，以形成平均粒度为1μm至1000μm的颗粒状生物质。 将颗粒状生物质与液体烃混合以形成悬浮液，其中悬浮液包括1重量％至40重量％的颗粒生物质。 将悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置中的单元中，然后将至少一部分颗粒生物质 的悬浮液转化为燃料。
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48.发明申请PROCESS FOR THE CONVERSION OF BIOMASS TO LIQUID FUELS AND SPECIALTY CHEMICALS 有权生物质转化为液体燃料和特种化学品的方法公开(公告)号：US20120190062A1
公开(公告)日：2012-07-26
申请号：US13195493
申请日：2011-08-01
申请人： Paul O'Connor , Dennis Stamires , Sjoerd Daamen
发明人： Paul O'Connor , Dennis Stamires , Sjoerd Daamen
CPC分类号： C10G1/02 , C10G1/006 , C10G2300/1014 , C10G2300/4006 , C10G2300/4081 , Y02P30/20
摘要： A process is disclosed for converting biomass to fuels and/or valuable chemicals. The process comprises the steps of a) activating biomass to make it more susceptible to conversion; c) partially converting the biomass to a solubilized material; and d) subjecting the unconverted biomass to a second conversion step. The process optionally comprises a step b) of adding a solvent to the activated biomass. In a preferred embodiment the solubilized biomass obtained in step c) is removed before the unconverted biomass is subjected to step d).
摘要翻译： 公开了将生物质转化为燃料和/或有价值化学品的方法。 该方法包括以下步骤：a）活化生物质使其更易于转化; c）部分地将生物质转化为溶解的材料; 和d）对未转化的生物质进行第二转化步骤。 该方法任选地包括向活化的生物质中加入溶剂的步骤b）。 在优选的实施方案中，在未转化的生物质经受步骤d）之前，将步骤c）中获得的溶解的生物质除去。
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公开(公告)号：US08168840B2
公开(公告)日：2012-05-01
申请号：US12921343
申请日：2009-06-25
申请人： Michael Brady , Paul O'Connor , Dennis Stamires
发明人： Michael Brady , Paul O'Connor , Dennis Stamires
IPC分类号： C10G1/00
CPC分类号： C10L1/04 , C08L97/00 , C10G1/00 , C10G1/083 , C10G2300/1014 , C10G2300/44 , C10G2300/80 , C12P2201/00 , C13K1/02 , D21C1/04 , D21C1/06 , D21C11/0007 , Y02E50/16 , Y02P30/20
摘要： A process is described for pretreating lignocellulosic biomass. The process comprises swelling the lignocellulosic biomass with an aqueous liquid. The pretreated lignocellulosic biomass may be used as a feedstock for the enzymatic conversion to ethanol, or in a thermal conversion. process to produce bio-oil. The pretreatment results in a greater yield and, in the case of a thermal conversion process, a better quality of the bio-oil. The pretreatment process may be used to adjust the composition and amount of inorganic material present in the lignocellulosic biomass material.
摘要翻译： 描述了一种用于预处理木质纤维素生物质的方法。 该方法包括用含水液体使木质纤维素生物质膨胀。 预处理的木质纤维素生物质可以用作酶转化成乙醇或热转化的原料。 生产生物油的过程。 预处理导致更高的产量，并且在热转化过程的情况下，生物油的质量更好。 预处理方法可用于调节木质纤维素生物质材料中存在的无机材料的组成和量。
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公开(公告)号：US20110258913A1
公开(公告)日：2011-10-27
申请号：US13140053
申请日：2009-12-16
申请人： Dennis Stamires , Paul O'connor
发明人： Dennis Stamires , Paul O'connor
CPC分类号： C10L9/10 , C10G2300/1011 , C10L1/026 , Y02P30/20
摘要： A composition of matter is disclosed comprising an intimate mixture of a particulate solid biomass material and a carbonaceous material. The composition is suitable for conversion to a bio-oil in a pyrolysis reaction. The carbonaceous material acts as a reducing agent during the pyrolysis reaction. The composition of matter produces bio-oil in a greater yield than prior art processes. The bio-oil is of improved quality, as evidenced by its low TAN value.
摘要翻译： 公开了一种物质组合物，其包括颗粒状固体生物质材料和含碳材料的紧密混合物。 该组合物适于在热解反应中转化为生物油。 碳质材料在热解反应期间用作还原剂。 物质的组成比现有技术的方法产生更大的产量的生物油。 生物油质量提高，其TAN值低。
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