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公开(公告)号：US08063153B2
公开(公告)日：2011-11-22
申请号：US10579954
申请日：2005-10-20
申请人： Yuan-Yong Yan , David F. Lawson
发明人： Yuan-Yong Yan , David F. Lawson
IPC分类号： C08C19/25
CPC分类号： B60C1/0016 , C08C19/30 , C08C19/44 , C08L19/006
摘要： A functionalized polymer includes an elastomer, a terminal functional group including at least one heteroatom, and a unit intermediate the elastomer and the functional group; the intermediate unit includes a terminal moiety which, in its anionic form, is less basic than a secondary amino radical ion. Methods of making the functionalized polymer and of using it with particulate filler to make, e.g., a tire tread composition also are disclosed.
摘要翻译： 官能化聚合物包括弹性体，包含至少一个杂原子的末端官能团和弹性体和官能团中间的单元; 中间单元包括末端部分，其末端部分以其阴离子形式比次级氨基离子碱性低。 制备官能化聚合物并使用其与颗粒填料制备例如轮胎胎面组合物的方法也被公开。
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42.发明申请Method for Generating Free Radical Capable Polymers Using Tin or Silicon Halide Compounds 失效使用锡或硅化合物生成自由基聚合物的方法公开(公告)号：US20080161495A1
公开(公告)日：2008-07-03
申请号：US11618059
申请日：2006-12-29
申请人： James E. Hall , David F. Lawson
发明人： James E. Hall , David F. Lawson
IPC分类号： C08F8/00
CPC分类号： C08F8/42
摘要： Provided is a method comprising reacting the anionic living end of a polymer with a compound selected from the group consisting of tin halides and silicon halides to produced a polymer with a homolytically cleavable group containing a Sn—C bond or a Si—C bond. An engineered plastic may then be produced by adding the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond to a solvent comprising at least one vinyl monomer; (b) optionally adding at least one additional inert solvent; (c) optionally adding additives selected from the group consisting of extender oils, modifiers, and antioxidants; and (d) initiating polymerization of the at least one vinyl monomer by the use of an initiator and/or heat, wherein a free radical is produced from the polymer containing a homolytically cleavable group containing a Sn—C bond or a Si—C bond.
摘要翻译： 提供了一种方法，其包括使聚合物的阴离子活性端与选自卤化锡和卤化硅的化合物反应，以制备具有含Sn-C键或Si-C键的均聚裂解基团的聚合物。 然后可以通过将含有含有Sn-C键或Si-C键的均聚裂解基团的聚合物加入到包含至少一种乙烯基单体的溶剂中来制备工程塑料; （b）任选地加入至少一种另外的惰性溶剂; （c）任选地添加选自由增量油，改性剂和抗氧化剂组成的组的添加剂; 和（d）通过使用引发剂和/或加热引发至少一种乙烯基单体的聚合，其中由含有Sn-C键或Si-C键的均聚裂解基团的聚合物产生自由基 。
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公开(公告)号：US06274680B1
公开(公告)日：2001-08-14
申请号：US09224328
申请日：1998-12-31
IPC分类号： C08F834
CPC分类号： C08C19/44
摘要： A method of preparing a functionalized polymer comprising the steps of initiating the formation and propagation of an anionically-polymerized living polymer, and terminating the propagation of the living polymer by reacting the polymer with a terminating agent selected from the group of agents defined by the formulas (III), (IV), and (V) where C is a carbon atom, S is a sulfur atom, X is a halogen atom, R2 and R4 are independently selected from hydrogen and carbon-based moieties, and where the phenyl groups are selected from unsubstituted and substituted phenyl groups.
摘要翻译： 一种制备官能化聚合物的方法，包括以下步骤：引发阴离子聚合的活性聚合物的形成和扩散，并通过使聚合物与选自由式 （III），（IV）和（V）其中C是碳原子，S是硫原子，X是卤素原子，R2和R4独立地选自氢和碳基部分，并且其中苯基 选自未取代的和取代的苯基。
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44.发明授权Process to scavenge amines in polymeric compounds by treatment with triazine derivatives and compositions therefrom 失效通过用三嗪衍生物及其组合物处理来清除高分子化合物中的胺的方法公开(公告)号：US06235819B1
公开(公告)日：2001-05-22
申请号：US09002056
申请日：1997-12-31
IPC分类号： C08K534
CPC分类号： C08K5/3492
摘要： A method for scavenging amines within polymeric compositions of matter comprising the step of adding to a polymeric composition of matter at least one triazine compound, wherein said triazine compound is defined according to the formula: where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.
摘要翻译： 一种用于清除物质的聚合物组合物中的胺的方法，其包括向物质的聚合物组合物中加入至少一种三嗪化合物的步骤，其中所述三嗪化合物根据下式定义：其中X选自氢，卤化物 ，具有1至约20个碳原子的胺和有机基团，Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可通过反应置换 与仲胺，Z选自烷氧基衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。
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45.发明授权Soft compounds derived from polypropylene grafted disubstituted ethylene- maleimide copolymers 失效衍生自聚丙烯接枝二乙烯 - 马来酰亚胺共聚物的软化合物公开(公告)号：US06204354B1
公开(公告)日：2001-03-20
申请号：US09073759
申请日：1998-05-06
IPC分类号： C08G7300
CPC分类号： C08G81/021 , C08F8/32 , C08F255/00 , C08F265/10 , C08L51/003 , C08L2666/02
摘要： The instant invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(disubstituted ethylene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(disubstituted ethylene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(disubstituted ethylene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The instant invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.
摘要翻译： 本发明教导了一种能够形成高阻尼软聚合物凝胶的方法。 该方法包括：在足够形成聚亚烷基接枝的聚（二取代的乙烯 - 共 - 马来酰亚胺）聚合物产物的基本干燥条件下使聚（二取代的乙烯 - 共 - 马来酰亚胺）聚合物与马来化的聚亚烷基和烷基二胺反应; 并且将分散有聚亚烷基接枝的聚（二取代的乙烯 - 共 - 马来酰亚胺）聚合物产物与足以形成凝胶的增量油分散。 本发明还考虑了由聚合物凝胶组合物制成的聚合物凝胶组合物，聚合物组合物和制品。
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公开(公告)号：US6133354A
公开(公告)日：2000-10-17
申请号：US193595
申请日：1998-11-17
CPC分类号： C08F8/32 , C08L23/08 , C08L23/22 , C08L53/00 , C08L23/0892
摘要： The present invention teaches a method for enabling the formation of a high damping composition. The method includes mixing a centipede polymer, i.e., a poly(disubstituted ethylene-co-maleimide) polymer, and plasticizers or extenders within a non-vulcanized thermoplastic elastomer to form a relatively high damping gel composition.
摘要翻译： 本发明教导了一种能够形成高阻尼组合物的方法。 该方法包括将蜈蚣聚合物，即聚（二取代的乙烯 - 共 - 马来酰亚胺）聚合物和在非硫化的热塑性弹性体内的增塑剂或增量剂混合以形成相对较高的阻尼凝胶组合物。
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47.发明授权Process to scavenge amines in polymeric compounds by treatment with triazine derivatives, and compositions therefrom 失效通过用三嗪衍生物处理在高分子化合物中清除胺及其组合物的方法
公开(公告)号：US6063873A
公开(公告)日：2000-05-16
申请号：US2054
申请日：1997-12-31
IPC分类号： B60C1/00 , C07D251/34 , C07D251/50 , C08K5/29 , C08K5/3492 , C08L21/00 , C08C19/22
CPC分类号： C08K5/34922 , Y10T152/10495
摘要： A rubber tread stock comprising a vulcanizable composition of matter, and a triazine, wherein said triazine is defined by the formula ##STR1## where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.
摘要翻译： 一种橡胶胎面料，其包含可硫化的物质组合物和三嗪，其中所述三嗪由下式定义：其中X选自氢，卤化物，胺和具有1至约20个碳原子的有机基团， Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可以通过与仲胺的反应置换，并且Z选自烷氧基 衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。
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48.发明授权Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds 失效二烯聚合物和共聚物结合部分偶联和由烃基甲硅烷化合物形成的末端
公开(公告)号：US06008295A
公开(公告)日：1999-12-28
申请号：US891570
申请日：1997-07-11
IPC分类号： B60C1/00 , C08C19/44 , C08F8/00 , C08F297/04 , C08K3/36 , C08L9/00 , C08L15/00 , C08L19/00 , C08F8/42
CPC分类号： C08L7/00 , B60C1/0016 , C08C19/44 , C08L15/00 , C08L19/006 , C08L9/00 , C08L9/06
摘要： Diene polymers or copolymers having improved balance between raw polymer viscosity and mixed compound viscosity, useful in tire tread compositions having highly balanced wet traction, rolling resistance, and traction in ice and snow, and fracture properties in the cured and white carbon reinforced states are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from hydrocarboxysilane compounds. The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using hydrocarboxysilane compounds. The resultant diene polymers or copolymers have improved balance between raw polymer viscosity and mixed compound viscosity when compounded with silica and/or carbon black and cured compositions are useful in tire tread having highly balanced wet traction, rolling resistance, and traction in ice and snow. The polymers can be utilized to form elastomer compositions for tire treads having balanced properties of reduced rolling resistance and wet traction and handling or balanced properties of wet traction and handling and traction in snow and ice.
摘要翻译： 本发明提供了在具有高均衡湿牵引力，滚动阻力和冰雪牵引力的轮胎胎面组合物中有用的原始聚合物粘度和混合化合物粘度之间的改进平衡的二烯聚合物或共聚物，以及固化和白色碳增强状态下的断裂性能 。 这些二烯聚合物或共聚物包含在主聚合物或共聚物链中含有碳 - 锡键的二烯聚合物或共聚物链的混合物，以及含有衍生自烃基甲硅烷化合物的末端的二烯聚合物或共聚物链。 二烯聚合物或共聚物通过首先将一部分活性二烯聚合物或通过阴离子聚合获得的共聚物链与多卤化物偶联剂偶联，然后使用烃基甲硅烷化合物终止剩余的活性二烯聚合物或共聚物链来制备。 所得到的二烯聚合物或共聚物在与二氧化硅和/或炭黑混合时与原料聚合物粘度和混合化合物粘度之间具有改善的平衡，并且固化的组合物可用于具有高度平衡的湿牵引力，滚动阻力和在冰雪中的牵引力的轮胎胎面。 聚合物可用于形成用于轮胎胎面的弹性体组合物，其具有降低的滚动阻力和湿牵引力和处理性能的平衡性能或湿牵引和处理以及雪和冰中牵引的平衡性能。
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49.发明授权
公开(公告)号：US5883183A
公开(公告)日：1999-03-16
申请号：US467363
申请日：1995-06-06
申请人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
发明人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
IPC分类号： C08F4/48 , B60C1/00 , C08F4/00 , C08F4/08 , C08F4/42 , C08F36/04 , C08F236/10 , C08K3/04 , C08L21/00 , C08F8/42
CPC分类号： C08F36/04 , B60C1/00 , B60C1/0016 , Y10T152/10495
摘要： The present invention is directed toward anionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂胺进行阴离子聚合。 所述锂胺具有通式（A）Li（SOL）y，其中SOL是增溶组分，A是烷基，二烷基，环烷基或二环烷基胺基或环状胺，y是0或约0.5至 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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50.发明授权
公开(公告)号：US5393721A
公开(公告)日：1995-02-28
申请号：US962373
申请日：1992-10-16
申请人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
发明人： Takashi Kitamura , David F. Lawson , Koichi Morita , Yoichi Ozawa
CPC分类号： C08F36/04 , B60C1/0016
摘要： The present invention is directed toward artionic polymerization employing lithio amines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio amines have the general formula (A)Li(SOL)y, where SOL is a solubilizing component, A is an alkyl, dialkyl, cycloalkyl or dicycloalkyl amine radical or a cyclic amine, and y is 0 or is from about 0.5 to about 3. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂胺进行挥发聚合。 所述锂胺具有通式（A）Li（SOL）y，其中SOL是增溶组分，A是烷基，二烷基，环烷基或二环烷基胺基或环状胺，y是0或约0.5至 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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