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127 条记录 (耗时 0.027 秒)

    Nanoparticulate phosphorus-containing flame retardant system
    41.
    发明申请
    Nanoparticulate phosphorus-containing flame retardant system 审中-公开
    纳米微粒含磷阻燃体系

    公开(公告)号：US20060287418A1

    公开(公告)日：2006-12-21

    申请号：US11182459

    申请日：2005-07-15

    申请人： Harald Bauer ,  Werner Krause ,  Martin Sicken ,  Norbert Weferling

    发明人： Harald Bauer ,  Werner Krause ,  Martin Sicken ,  Norbert Weferling

    IPC分类号： C08K5/52

    CPC分类号： C08K5/5313 ,  C07F9/30 ,  C07F9/305 ,  C08K5/0091

    摘要： The invention relates to a nanoparticulate phosphorus-containing flame retardant system, which comprises a phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4; and to a process for the preparation of these flame retardant systems, and to their use.

    摘要翻译： 本发明涉及一种纳米颗粒含磷阻燃体系，其包含式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物，其中R 1， O 2和R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4; 以及制备这些阻燃体系的方法及其应用。

    Granular flame-retardant composition
    42.
    发明授权
    Granular flame-retardant composition 有权
    颗粒阻燃组合物

    公开(公告)号：US07148276B2

    公开(公告)日：2006-12-12

    申请号：US10656398

    申请日：2003-09-05

    申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    IPC分类号： C08K5/53

    CPC分类号： C08K5/5313

    摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1–C6-alkyl, linear or branched, and/or aryl; R3 is C1–C10-alkylene, linear or branched, C6–C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.

    摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐， 黑夜和/或混战。

    Method to improve the efficacy of therapeutic radiolabeled drugs
    43.
    发明申请
    Method to improve the efficacy of therapeutic radiolabeled drugs 审中-公开
    提高治疗放射性标记药物疗效的方法

    公开(公告)号：US20060127308A1

    公开(公告)日：2006-06-15

    申请号：US11009518

    申请日：2004-12-13

    申请人： Werner Krause

    发明人： Werner Krause

    IPC分类号： A61K51/00 ,  C07F5/00

    CPC分类号： A61K51/1093

    摘要： Disclosed are radiolabeled drugs and methods to improve their efficacy by using a radiosensitizer such that the radiosensitizer is either part of the radiolabeled drug by directly attaching the radiosensitizer to the radiolabeled drug or by producing a mixture of the radiolabeled drug and an analogue of the drug with the radiosensitizer attached to the drug instead of the radiolabel.

    摘要翻译： 公开了通过使用放射增敏剂来提高其功效的放射性标记药物和方法，使得放射增敏剂是放射性标记药物的一部分，通过将放射增敏剂直接附着到放射性标记的药物或通过产生放射性标记的药物和药物的类似物的混合物与 放射敏剂附着于药物而不是放射性标记物。

    Phosphorus-containing flame retardant agglomerates
    44.
    发明申请
    Phosphorus-containing flame retardant agglomerates 有权
    含磷阻燃剂

    公开(公告)号：US20050143503A1

    公开(公告)日：2005-06-30

    申请号：US10959515

    申请日：2004-10-06

    申请人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    发明人： Harald Bauer ,  Sebastian Hoerold ,  Werner Krause ,  Martin Sicken

    IPC分类号： C09K21/12 ,  B01J2/28 ,  C08K5/00 ,  C08K5/5313 ,  C08K9/04 ,  C08L101/00 ,  C09K21/02 ,  C09K21/10 ,  C08K5/49

    CPC分类号： C08K5/0066 ,  C08J3/223 ,  C08J2367/02 ,  C08J2377/02 ,  C08J2377/06 ,  C08K5/5313

    摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.

    摘要翻译： 本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基， 直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，b）为0.01至20重量％的助剂。 本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。

    Process for extracting heavy metal ions from aqueous solutions
    47.
    发明授权
    Process for extracting heavy metal ions from aqueous solutions 失效
    从水溶液中提取重金属离子的方法

    公开(公告)号：US4503016A

    公开(公告)日：1985-03-05

    申请号：US582138

    申请日：1984-02-23

    申请人： G/u/ nther Schimmel ,  Werner Krause ,  Reinhard Gradl

    发明人： G/u/ nther Schimmel ,  Werner Krause ,  Reinhard Gradl

    IPC分类号： C02F1/26 ,  C01B25/238 ,  C02F1/62 ,  C22B3/38 ,  C01G3/00 ,  C01G9/00 ,  C01G11/00 ,  C01G28/00

    CPC分类号： C22B3/007 ,  C01B25/238 ,  Y02P10/234 ,  Y10S423/14

    摘要： The disclosure relates to a process for liquid/liquid-extraction of heavy metal ions from acid aqueous solutions with the aid of water-insoluble dithiophosphoric acid diesters as extracting agents. More particularly, use is made of phosphoric acid solutions with a P.sub.2 O.sub.5 -content of from 3 to 80 weight %, the solutions being free from emulsion-forming organic contaminants or having previously been freed therefrom in known manner. The resulting aqueous phase is separated from the phase containing the dithiophosphoric acid diester.

    摘要翻译： 本公开涉及借助于不溶于水的二硫代磷酸二酯作为提取剂从酸性水溶液中液/液萃取重金属离子的方法。 更具体地，使用P2O5含量为3至80重量％的磷酸溶液，该溶液不含乳液形成有机污染物，或者已知以已知的方式从其中释放出来。 将得到的水相与含有二硫代磷酸二酯的相分离。

    Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof
    50.
    发明授权
    Method for the production of monofunctionalized dialkylphosphinic acids, esters and salts, and use thereof 有权
    用于制备单官能二烷基次膦酸，酯和盐的方法及其用途

    公开(公告)号：US09279085B2

    公开(公告)日：2016-03-08

    申请号：US13140555

    申请日：2009-10-06

    申请人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

    发明人： Michael Hill ,  Harald Bauer ,  Werner Krause ,  Martin Sicken

    IPC分类号： C07F9/02 ,  C07F9/22 ,  C07F9/28 ,  C08K5/53 ,  C09K21/12 ,  C07F9/30 ,  C07F9/32 ,  C08K5/5313

    CPC分类号： C09K21/12 ,  C07F9/301 ,  C07F9/3211 ,  C08K5/5313

    摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.

    摘要翻译： 本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或 酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数 至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。 还公开了所述二烷基膦酸，酯和盐的用途。