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公开(公告)号：US5763136A
公开(公告)日：1998-06-09
申请号：US736104
申请日：1996-10-24
CPC分类号： B41M5/38207 , B41M5/38221
摘要： A method of producing a radiation-induced colorant transfer image on a support, includes the steps of: providing an image-receiving element comprising a support having thereon an image-receiving layer; providing a colorant donor element having a colorant transfer layer on a colorant element support and wherein colorant can be transferred from a transfer surface of the colorant donor element to the image-receiving layer in response to selectively applied radiation; providing a rigid element being configured to provide a surface having peaks and valleys; pressing either the colorant element support surface or the image-receiving support surface against the rigid element so as to cause either the colorant transfer layer surface or the image-receiving surface, respectively, to conformally have peaks and valleys; causing the peaks of the colorant transfer layer or the image-receiving layer to engage either the image-receiving element or the colorant donor element, respectively; and applying radiation to the colorant element support to cause colorant to transfer in the space between the image-receiving element and the colorant transfer layer surface corresponding to the valleys in the colorant transfer surface or image-receiving surface.
摘要翻译： 在支撑体上产生辐射诱导的着色剂转印图像的方法包括以下步骤：提供图像接收元件，该图像接收元件包括其上具有图像接收层的支撑件; 提供着色剂供体元件，其在着色剂元件载体上具有着色剂转移层，并且其中可以响应于选择性施加的辐射将着色剂从着色剂供体元件的转移表面转移到图像接收层; 提供刚性元件，其被配置为提供具有峰和谷的表面; 将着色剂元件支撑表面或图像接收支撑表面压在刚性元件上，以分别使着色剂转印层表面或图像接收表面保形地具有峰谷; 使得着色剂转移层或图像接收层的峰分别与图像接收元件或着色剂供体元件接合; 以及向着色剂元件支撑件施加辐射以使得着色剂在图像接收元件和与着色剂转印表面或图像接收表面中的谷部相对应的着色剂转印层表面之间的空间中转印。
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公开(公告)号：US5506093A
公开(公告)日：1996-04-09
申请号：US380479
申请日：1995-01-30
CPC分类号： B41M5/32 , G03C1/67 , G03C5/16 , Y10S430/137 , Y10S430/145
摘要： This invention relates to an imaging element for reductive laser-imaging comprising a support having thereon an imaging layer comprising:a) a reducible Co(III) ammine complex,b) a source of phthalaldehyde, andc) a reducing agent,the imaging layer having an infrared-absorbing material associated therewith in the amount of about 0.001 to about 0.5 g/m.sup.2 of element.
摘要翻译： 本发明涉及一种用于还原激光成像的成像元件，包括其上具有成像层的支撑体，该成像层包括：a）可还原Co（III）氨络合物，b）邻苯二甲醛源，和c）还原剂，成像层 其具有与其相关联的红外线吸收材料的量为约0.001至约0.5g / m 2的量。
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43.发明授权Duplicating radiographic, medical or other black and white images using laser thermal digital halftone printing 失效使用激光热量数字半色调打印复制放射照相，医疗或其他黑白图像
公开(公告)号：US5477344A
公开(公告)日：1995-12-19
申请号：US154837
申请日：1993-11-19
CPC分类号： B41M5/48 , B41M5/24 , H04N1/00249 , H04N1/00265 , H04N1/23
摘要： Continuous tone black and white images are duplicated using laser thermal digital halftone printing. A continuous tone black and white image signal is provided by a source such as a medical imaging source. The image signal is screened with a digital halftone screen, such that each pixel of said image signal is represented by a predetermined matrix of micropixels, whereby to produce a digital halftone image signal corresponding to the continuous tone black and white image signal. A master is created by printing the digital halftone image onto a dye ablated medium by means of laser thermal recording. A duplicate of the master is produced by contact printing onto a duplicating medium.
摘要翻译： 连续色调黑白图像使用激光热量数字半色调打印进行复制。 连续色调黑白图像信号由诸如医学成像源的源提供。 利用数字半色调屏幕对图像信号进行屏蔽，使得所述图像信号的每个像素由预定的微孔矩阵表示，从而产生对应于连续色调黑白图像信号的数字半色调图像信号。 通过激光热记录将数字半色调图像打印到染料消融的介质上来创建主人。 通过联系印刷到复制介质上产生主机的副本。
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公开(公告)号：US5291218A
公开(公告)日：1994-03-01
申请号：US956712
申请日：1992-10-05
申请人： Charles D. DeBoer
发明人： Charles D. DeBoer
IPC分类号： B41M5/382 , B41M5/00 , B41M5/392 , B41M5/41 , B41M5/42 , B41M5/46 , B41M5/50 , B41M5/52 , B41M5/26
摘要： This invention relates to a thermal dye transfer assemblage comprising:a) a dye-donor element comprising a support having thereon a dye layer and an infrared absorbing material associated therewith, andb) a dye-receiving element comprising a support having thereon a dye image-receiving layer having a given image area, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is adjacent to the dye image-receiving layer,the improvement wherein spacer rails having a height of about 3 to about 50 .mu.m are located between the dye-donor element and the dye-receiving element, the spacer rails being located just outside the image area of the assemblage in such a location so as to separate the dye-donor from the dye-receiver across the entire image area; andthe dye-donor element support and the dye-receiving element support either being rigid and flat or being held rigid and flat in the assemblage so that there is no more than an insignificant sag at the area midway between said rails.
摘要翻译： 本发明涉及一种热染料转移组合物，其包括：a）染料供体元件，其包含其上具有染料层和与其相关联的红外吸收材料的载体，以及b）染料接收元件，其包含其上具有染料图像的载体 - 接收层具有给定的图像区域，染料接收元件与染料供体元件重叠关系，使得染料层与染料影像接收层相邻，其改进之处在于，具有高度约为 3至约50（my）m位于染料供体元件和染料接收元件之间，间隔导轨位于组合物的图像区域正好在该位置的正上方，以便将染料供体与 整个图像区域的染料接收器; 并且染料供体元件支撑件和染料接受元件支撑件是刚性的和平坦的，或者在组合件中保持刚性和平坦，使得在所述轨道之间的中间区域处不存在不大的下垂。
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公开(公告)号：US5234886A
公开(公告)日：1993-08-10
申请号：US722810
申请日：1991-06-28
CPC分类号： B41M5/42 , B41M5/38207 , B41M5/52 , Y10S428/913 , Y10S428/914 , Y10S430/146 , Y10T428/24777 , Y10T428/31507
摘要： A dye-receiving element for thermal dye transfer suitable for forming a slide for projection viewing comprising a polymeric central dye image-receiving section and an integral polymeric frame section extending around the periphery of the central dye image-receiving section, the frame section being from about 1/2 to about 3 mm thick and the central dye image-receiving section preferably being thinner than the frame section. Such integral receiver-frames do not require post-imaging framing and mounting assembly operations in order to be viewable in slide projectors, and are particularly advantageously used in laser thermal dye transfer systems.
摘要翻译： 一种用于热染料转移的染料接收元件，其适于形成用于投影观察的载玻片，包括聚合物中心染料影像接收部分和围绕中央染料影像接收部分周围延伸的整体聚合物框架部分，所述框架部分来自 约1/2至约3毫米厚，并且中心染料影像接收部优选地比框架部分薄。 这种整体的接收机框架不需要后成像框架和安装组装操作，以便在幻灯机中可以看到，并且特别有利地用于激光热染料转移系统中。
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公开(公告)号：US5227265A
公开(公告)日：1993-07-13
申请号：US673509
申请日：1990-11-30
申请人： Charles D. DeBoer , Dennis R. Kamp , William Mey
发明人： Charles D. DeBoer , Dennis R. Kamp , William Mey
CPC分类号： G03G17/10 , G03G15/342 , Y10S430/145
摘要： A migration imaging system using a laser-addressable thermoplastic imaging member. The imaging member comprises a supporting section and a thermoplastic imaging surface layer. A charged, uniform layer of marking particles is deposited on the imaging surface layer. An imagewise-modulated laser beam transforms selected volumes of the imaging surface layer in an imagewise pattern to a permeable state. Charged marking particles that superpose a transformed volume then migrate into the imaging surface layer so as to be retained. Unaddressed marking particles are cleaned away. The imaging member, or solely the imaging surface layer, may be transferred and bonded to a receiver such as a drum for use as an exposure mask, or to a receiver sheet to provide a hard copy reproduction. The processed imaging member is usable as a master in a xeroprinting system.
摘要翻译： 一种使用激光寻址热塑性成像构件的迁移成像系统。 成像构件包括支撑部分和热塑性成像表面层。 带电均匀的标记颗粒层沉积在成像表面层上。 成像调制激光束以成像图案将选定体积的成像表面层转换为可渗透状态。 装载变换体积的带电标记颗粒然后迁移到成像表面层中以便被保留。 未处理的标记颗粒被清除。 成像构件或单独的成像表面层可以被转印并结合到诸如鼓的接收器以用作曝光掩模，或者接收到接收片以提供硬拷贝再现。 经处理的成像构件可在遥控打印系统中用作主机。
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47.发明授权
公开(公告)号：US4973572A
公开(公告)日：1990-11-27
申请号：US463095
申请日：1990-01-10
申请人： Charles D. DeBoer
发明人： Charles D. DeBoer
CPC分类号： B41M5/465 , B41M5/385 , B41M5/3854 , B41M5/392 , Y10S428/913 , Y10S428/914 , Y10S430/146 , Y10T428/31786
摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer comprising a polymeric binder and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a cyanine dye having a solution absorption maximum in methanol of between about 700 nm and 900 nm and having the following formula: ##STR1## wherein: R.sup.1 and R.sup.2 each independently represents a substituted or unsubstituted alkyl group;R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 each independently represents hydrogen or a substituted or unsubstituted alkyl group;or any two of said R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 groups may be joined together, directly or through one or more methyne or methylene groups to complete a substituted or unsubstituted carbocyclic or heterocyclic ring of 5 to 9 members;Z.sup.1 and Z.sup.2 each independently represents hydrogen or the atoms necessary to complete a unsubstituted or substituted benzene or naphthalene ring;Y.sup.1 represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulphur atom, a selenium atom, a nitrogen atom with an R.sup.1 or a substituted or unsubstituted aryl group attached, or direct bond between the B-ring vinylene carbon and the carbon at the R.sup.4 position;Y.sup.2 represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulphur atom, a selenium atom, a nitrogen atom with an R.sup.1 or a substituted or unsubstituted aryl group attached, or a direct bond between the B-ring vinylene carbon and the carbon at the R.sup.7 position;J represents hydrogen; a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a halogen atom; or a nitrogen atom substituted with an alkyl or aryl group, or the atoms necessary to complete a 5- or 6-membered heterocyclic ring;n and m each independently represents 0, 1 or 2; andX is a monovalent anion.
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公开(公告)号：US4965242A
公开(公告)日：1990-10-23
申请号：US449623
申请日：1989-12-11
CPC分类号： B41M5/38257 , B41M5/265 , B41M7/0027 , G02F1/133516 , Y10S359/90 , Y10S428/913 , Y10S428/914 , Y10S430/146 , Y10T428/1041
摘要： A process of preparing a color filter array element for use in making a color liquid crystal display device comprising:(a) overlaying a dye-receiving element with a dye-donor element, the dye-receiving element comprising a dimensionally-stable temporary support having thereon, in order, a polymeric alignment layer, a transparent conducting layer and a dye-receiving layer;(b) imagewise heating the dye-donor element to transfer a dye image in a repeating mosaic pattern to the dye-receiving layer;(c) removing the dye-donor element from contact with the dye-receiving element;(d) laminating a transparent permanent support to the dye-receiving layer containing the dye image in a repeating mosaic pattern; and(e) removing the temporary support to expose one surface of the polymeric alignment layer, thereby forming the color filter array element.
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49.发明授权Infrared absorbing bis(aminoaryl)polymethine dyes for dye-donor element used in laser-induced thermal dye transfer 失效用于激光诱导热染料转移的染料供体元件的红外线吸收双（氨基芳基）聚甲炔染料
公开(公告)号：US4950639A
公开(公告)日：1990-08-21
申请号：US366968
申请日：1989-06-16
申请人： Charles D. DeBoer , Steven Evans
发明人： Charles D. DeBoer , Steven Evans
CPC分类号： B41M5/465 , B41M5/392 , Y10S428/913 , Y10S428/914 , Y10S430/146 , Y10T428/31786
摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(aminoaryl)polymethine dye. In a preferred embodiment, the bis(aminoaryl)polymethine dye has the following formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together or with an adjacent aromatic ring to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;R.sup.4, R.sup.5, R.sup.6 and R.sup.7 each independently represents hydrogen, a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms;or R.sup.4 and R.sup.5 or R.sup.6 and R.sup.7 may be joined together to form a 5- to 7-membered heterocyclic ring;or R.sup.4, R.sup.5, R.sup.6 or R.sup.7 may be joined to the carbon atom of the adjacent aromatic ring at a position ortho to the position of attachment of the anilino nitrogen to form, along with the nitrogen to which they are attached, a 5-or 6-membered heterocyclic ring;n is 1 to 5;X is a monovalent anion;Z.sup.1 and Z.sup.2 each independently represents R.sup.1 or the atoms necessary to complete a 5- to 7-membered fused carbocyclic or heterocyclic ring; and m and p are each 4.
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50.发明授权Infrared absorbing oxyindolizine dyes for dye-donor element used in laser-induced thermal dye transfer 失效用于激光诱导热染料转移的染料供体元件的红外吸收氧基吲嗪染料
公开(公告)号：US4948778A
公开(公告)日：1990-08-14
申请号：US369494
申请日：1989-06-20
申请人： Charles D. DeBoer
发明人： Charles D. DeBoer
CPC分类号： B41M5/465 , B41M5/392 , Y10S428/913 , Y10S428/914 , Y10S430/146 , Y10T428/31786
摘要： A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an oxyindolizine dye. In a preferred embodiment, the oxyindolizine dye has the following formula: ##STR1## wherein R.sup.1 and R.sup.2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms;R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group;or any two of said R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 groups may be combined with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y represents oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus;A and Z each independently represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring, with the proviso that Z may be a ring only when Y is nitrogen or phosphorus;n is 0 to 2, with the proviso that n is 1 or 2 when Y is oxygen, sulfur, selenium or tellurium; andX is a monovalent anion.
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