ABS polymer compositions having a uniform matt surface
    41.
    发明授权
    ABS polymer compositions having a uniform matt surface 失效
    ABS聚合物组合物具有均匀的无光泽表面

    公开(公告)号:US5605963A

    公开(公告)日:1997-02-25

    申请号:US383832

    申请日:1995-02-06

    CPC分类号: C08L55/02

    摘要: ABS polymer compositions consisting ofA) 5 to 80 parts by weight of at least one ABS polymer prepared by mass polymerization or solution polymerization, having rubber particles with an average particle diameter of from 800 to 15,000 nm and a rubber content of from 1 to 20% by weight,B) 1 to 50 parts by weight of at least one ABS polymer prepared by emulsion polymerization, having an average particle diameter of from 50 to 500 nm and a rubber content of from 20 to 80% by weight,C) 0 to 70 parts by weight of at least one thermoplastic vinyl resin prepared by radical polymerization of at least two monomer components selected from styrene, .alpha.-methylstyrene, methyl methacrylate, acrylonitrile, N-phenylmaleimide andD) 0.5 to 10 parts by weight of at least one polybutadiene prepared by emulsion polymerization, having an average particle diameter d.sub.50 in the latex form of from 80 to 500 nm and a gel content of from 10 to 95% by weight.

    摘要翻译: ABS聚合物组合物,由A)5-80重量份的至少一种通过大量聚合或溶液聚合制备的ABS聚合物,具有平均粒径为800至15,000nm的橡胶颗粒和橡胶含量为1至20 B)1〜50重量份的通过乳液聚合制备的至少一种ABS聚合物,平均粒径为50〜500nm,橡胶含量为20〜80重量%,C)0 至70重量份的至少一种通过自由基聚合至少两种选自苯乙烯,α-甲基苯乙烯,甲基丙烯酸甲酯,丙烯腈,N-苯基马来酰亚胺和D)的单体组分制备的热塑性乙烯基树脂,D)至少0.5至10重量份 一种通过乳液聚合制备的聚丁二烯,其胶乳形式的平均粒径d50为80-500nm,凝胶含量为10-95重量%。

    Uncrosslinked copolymers containing reactive double bonds of fluorine
monomers and unconjugated dienes and a process for their production
    47.
    发明授权
    Uncrosslinked copolymers containing reactive double bonds of fluorine monomers and unconjugated dienes and a process for their production 失效
    包含荧光单体和不连续二氧化碳的反应双重债券的非交换性共聚物及其生产过程

    公开(公告)号:US5214115A

    公开(公告)日:1993-05-25

    申请号:US874931

    申请日:1992-04-28

    CPC分类号: C08F214/186

    摘要: An uncrosslinked copolymer of comonomers (a), (b) and (c) and containing reactive double bonds, the comonomers based on the total mols of (a), (b) and (c) comprising(a) 45 to 99.9 mol-% of at least one ethylene containing 1 to 4 fluorine atoms,(b) 0 to 54.9 mol-% of at least one comonomer selected from the group consisting of(b1) a linear or branched C.sub.3-8 alkene containing at least one fluorine atom,(b2) an alkyl vinyl ether containing at least one fluorine atom,(b3) an open-chain or cyclic C.sub.3-6 ketone containing fluorinated .alpha.,.alpha.'-positions and(b4) non-fluorinated C.sub.2-4 alkene, C.sub.3-6 alkyl vinyl ether or C.sub.4-6 vinyl ester, and(c) 0.1 to 5 mol-% of at least one unconjugated diene. They are produced by radical polymerization. Because of the absence of bromine and/or iodine, during subsequent peroxidic cross-linking no toxic alkyl bromide and/or iodide is released.

    摘要翻译: 共聚单体(a),(b)和(c)的未交联共聚物并含有反应性双键,基于(a),(b)和(c)的总摩尔数的共聚单体包含(a)45至99.9mol- 至少一种含有1至4个氟原子的乙烯的%,(b)0至54.9mol%的至少一种选自(b1)含有至少一个氟原子的直链或支链C 3-8烯烃的共聚单体 ,(b2)含有至少一个氟原子的烷基乙烯基醚,(b3)含氟化α,α'-位和(b4)非氟化C 2-4烯烃的开链或环状C 3-6酮, 6烷基乙烯基醚或C 4-6乙烯基酯,和(c)0.1至5mol%的至少一种非共轭二烯。 它们是通过自由基聚合制成的。 由于不存在溴和/或碘,在随后的过氧化物交联过程中,没有毒性的烷基溴和/或碘化物被释放。

    Polymer mixture
    50.
    发明授权
    Polymer mixture 失效
    聚合物混合物

    公开(公告)号:US5104935A

    公开(公告)日:1992-04-14

    申请号:US447300

    申请日:1989-12-06

    摘要: Polymer mixtures ofa. 10 to 60 parts by weight of a graft polymer,b. 10 to 50 parts by weight of a partially cross-linked, rubber like copolymer of from 5 to 40% by weight of acrylonitrile, styrene, alkyl methacrylate or mixtures thereof and from 95 to 60% by weight of alkyl acrylate having a gel content of from 20 to 99% by weight,c. 5 to 40 parts by weight of an uncross-linked polymer of styrenes, .alpha.-methyl styrenes, acrylonitrile, methacrylonitrile, esters of acrylic acid or methacrylic acid, vinyl C.sub.1 to C.sub.4 carboxylic acids or mixtures of these monomers having Staudinger Indices (.eta.) (determined in dimethyl formamide at 23.degree. C.) of from 0.3 to 1.5 dl/g andd. 1 to 45 parts by weight of a polymer of a cyclic aliphatic ester or of an aliphatic cyclic ester and an aliphatic cyclic carbonate.

    摘要翻译: 聚合物混合物 10〜60重量份的接枝聚合物,b。 10至50重量份的5-40重量%的丙烯腈,苯乙烯,甲基丙烯酸烷基酯或其混合物的部分交联的橡胶状共聚物和95至60重量%的具有凝胶含量的丙烯酸烷基酯 20至99重量%,c。 5至40重量份苯乙烯,α-甲基苯乙烯,丙烯腈,甲基丙烯腈,丙烯酸或甲基丙烯酸的酯,乙烯基C1至C4羧酸或具有Staudinger指数(eta)的这些单体的混合物的未交联聚合物 在23℃的二甲基甲酰胺中测定)为0.3〜1.5dl / g,d。 1至45重量份的环状脂族酯或脂族环酯和脂族环状碳酸酯的聚合物。