公开(公告)号：US20060043859A1

公开(公告)日：2006-03-02

申请号：US10535310

申请日：2003-11-13

申请人： Kenichi Fukuoka ,  Masahide Matsuura ,  Hiroshi Yamamoto ,  Chishio Hosokawa

发明人： Kenichi Fukuoka ,  Masahide Matsuura ,  Hiroshi Yamamoto ,  Chishio Hosokawa

IPC分类号： H01J1/88

CPC分类号： H01L51/0052 ,  H01L51/005 ,  H01L51/0054 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/5092 ,  Y10S428/917 ,  Y10T428/24942

摘要： An organic electroluminescence element comprising: an anode; a first emitting layer comprising at least a first host material and a first dopant; a second emitting layer comprising at least a second host material and a second dopant; and a cathode in the order mentioned: wherein the energy gap Egh1 of the first host material, the energy gap Egd1 of the first dopant, the energy gap Egh2 of the second host material, and the energy gap Egd2 of the second dopant satisfy the following formulas; and the luminescent intensity I1 at the maximum luminescent wavelength of an emission spectrum derived from the first emitting layer, and the luminescent intensity I2 at the maximum luminescent wavelength of an emission spectrum derived from the second emitting layer satisfy the following formula: Egh1>Egd1 Egh2>Egd2 Egd1>Egd2 I1>3.5×I2.

摘要翻译： 一种有机电致发光元件，包括：阳极; 包括至少第一主体材料和第一掺杂剂的第一发光层; 第二发光层，包括至少第二主体材料和第二掺杂剂; 和阴极，其中第一主体材料的能隙E 1h 1，第一掺杂剂的能隙E gd 1，能隙E 第二主体材料的第二能隙和第二掺杂剂的能隙E gd 2满足下式： 并且从第一发光层得到的发光光谱的最大发光波长的发光强度I 1和来自第二发光层的发光光谱的最大发光波长的发光强度I 2满足下式： in-line-formula description =“In-line Formulas”end =“lead”？> E 1> E 1 <？in-line-formula description = “In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> E gd 2 <？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> E-in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> I 1> 3.5xI 2. <？in-line-formula description =“In-line Formulas”end =“tail”？>

公开(公告)号：US20050064233A1

公开(公告)日：2005-03-24

申请号：US10617397

申请日：2003-07-11

申请人： Masahide Matsuura ,  Masakazu Funahashi ,  Kenichi Fukuoka ,  Chishio Hosokawa

发明人： Masahide Matsuura ,  Masakazu Funahashi ,  Kenichi Fukuoka ,  Chishio Hosokawa

IPC分类号： C07C13/567 ,  C07C13/72 ,  C07C15/38 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14

CPC分类号： H01L51/0058 ,  B82Y30/00 ,  C07C13/567 ,  C07C13/72 ,  C07C15/28 ,  C07C15/30 ,  C07C15/38 ,  C07C15/52 ,  C07C2603/46 ,  C07C2603/50 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1018 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0072 ,  H01L51/0096 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5052 ,  H01L51/5206 ,  H01L51/5221 ,  H01L51/56 ,  H05B33/14 ,  Y10S428/917 ,  Y10S977/755

摘要： An organic electroluminescence device having a layer of an organic light emitting medium which comprises (A) a specific arylamine compound and (B) at least one compound selected from specific anthracene derivatives, spirofluorene derivatives, compounds having condensed rings and metal complex compounds and is disposed between a pair of electrodes and an organic light emitting medium comprising the above components (A) and (B) are provided. The organic electroluminescence device exhibits a high purity of color, has excellent heat resistance and a long life and efficiently emits bluish to yellowish light. The organic light emitting medium can be advantageously used for the organic electroluminescence device.

摘要翻译： 一种具有有机发光介质层的有机电致发光器件，其包含（A）特定的芳基胺化合物和（B）至少一种选自特定蒽衍生物，螺芴衍生物，具有稠环的化合物和金属络合物的化合物， 在一对电极和包含上述组分（A）和（B）的有机发光介质之间。 有机电致发光器件具有高纯度的颜色，具有优异的耐热性和长寿命，并有效地发出蓝绿色至浅黄色的光。 有机发光介质可以有利地用于有机电致发光器件。

公开(公告)号：US06509109B1

公开(公告)日：2003-01-21

申请号：US09281953

申请日：1999-03-31

申请人： Hiroaki Nakamura ,  Chishio Hosokawa ,  Kenichi Fukuoka ,  Hiroshi Tokailin

发明人： Hiroaki Nakamura ,  Chishio Hosokawa ,  Kenichi Fukuoka ,  Hiroshi Tokailin

IPC分类号： H05B3300

CPC分类号： H01L51/5092 ,  H01L51/002 ,  H01L51/0052 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： An organic EL device is improved to produce an increased luminance and have a prolonged lifetime. In an organic EL device comprising a cathode layer 16, an electron injection region 14, a light emission region 12 and an anode layer 10 as laminated in that order, the electron injection region 14 contains an aromatic compound composed of carbon and hydrogen or an aromatic compound composed of carbon, hydrogen and oxygen, along with a reducing dopant, and the electron affinity of the electron injection region is controlled to fall between 1.8 and 3.6 eV; or the electron injection region 14 contains an electron-transporting compound and a reducing dopant having a work function of at most 2.9 eV, and the electron affinity of the electron injection region is controlled to fall between 1.8 and 3.6 eV.

摘要翻译： 有机EL器件被改进以产生增加的亮度并且具有延长的寿命。 在包括依次层叠的阴极层16，电子注入区域14，发光区域12和阳极层10的有机EL器件中，电子注入区域14含有由碳和氢或芳族化合物构成的芳族化合物 由碳，氢和氧组成的化合物以及还原性掺杂剂，电子注入区的电子亲和力控制在1.8和3.6eV之间; 或电子注入区域14含有电子传输性化合物和功函数为2.9eV以下的还原性掺杂剂，电子注入区域的电子亲和力控制在1.8〜3.6eV之间。

公开(公告)号：US08841003B2

公开(公告)日：2014-09-23

申请号：US11178456

申请日：2005-07-12

申请人： Takashi Arakane ,  Kenichi Fukuoka ,  Chishio Hosokawa

发明人： Takashi Arakane ,  Kenichi Fukuoka ,  Chishio Hosokawa

IPC分类号： H01L51/54 ,  H01L51/00 ,  C09K11/06 ,  H05B33/14 ,  H05B33/22 ,  H01L51/50

CPC分类号： H05B33/22 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0077 ,  H01L51/5012 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

摘要： In an organic electroluminescent element comprising an anode layer, an organic luminescent layer, an inorganic compound layer (or reductive dopant layer) and a cathode layer; the organic luminescent layer comprises an aromatic amine compound of a formula (1), and/or an aromatic amine compound of a formula (2) wherein A, B, and Ar1 to Ar6 are independently a C6-60 aromatic group which does not contain a styryl group nor an alkenyl group, at least one of A, Ar1, Ar2, or B, Ar3 to Ar6 contains at least three condensed aromatic rings, and p, q and r of a condensation number are an integer of 1 to 6. The element has significantly long half-life and high luminance even at low driving voltages.

摘要翻译： 在包含阳极层，有机发光层，无机化合物层（或还原掺杂剂层）和阴极层的有机电致发光元件中， 有机发光层包括式（1）的芳族胺化合物和/或其中A，B和Ar 1至Ar 6独立地为不包含C 6 -C 6芳族基团的式（2）的芳族胺化合物 苯乙烯基或烯基，A，Ar 1，Ar 2或B，Ar 3〜Ar 6中的至少一个含有至少3个稠合芳环，缩合数p，q和r为1〜6的整数。 该元件即使在低驱动电压下也具有明显长的半衰期和高亮度。

公开(公告)号：US08294142B2

公开(公告)日：2012-10-23

申请号：US12667939

申请日：2008-07-04

申请人： Kazuki Nishimura ,  Toshihiro Iwakuma ,  Masahiro Kawamura ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Masakazu Funahashi

发明人： Kazuki Nishimura ,  Toshihiro Iwakuma ,  Masahiro Kawamura ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Masakazu Funahashi

IPC分类号： H01L29/08 ,  H01J1/62

CPC分类号： H01L51/5016 ,  B82Y10/00 ,  C09B1/00 ,  C09B23/148 ,  C09B57/00 ,  C09B57/008 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1044 ,  C09K2211/1051 ,  C09K2211/1059 ,  C09K2211/107 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/0045 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0071 ,  H01L51/5004 ,  H01L51/5036 ,  H01L2251/552 ,  H05B33/14

摘要： An organic EL device includes: an anode; a cathode and an organic thin-film layer provided between the anode and the cathode. The organic thin-film layer includes: a fluorescent-emitting layer containing a fluorescent host and a fluorescent dopant; and a phosphorescent-emitting layer containing a first phosphorescent host and a first phosphorescent dopant. The first phosphorescent dopant emits light by receiving exited triplet energy transferred from the fluorescent host. The fluorescent host has a substituted or unsubstituted polycyclic fused aromatic skeleton and has an exited triplet energy gap of 2.10 eV to 3.00 eV.

摘要翻译： 有机EL器件包括：阳极; 设置在阳极和阴极之间的阴极和有机薄膜层。 有机薄膜层包括：荧光发射层，含有荧光主体和荧光掺杂剂; 以及包含第一磷光发光体和第一磷光掺杂剂的磷光发光层。 第一个磷光掺杂剂通过接收从荧光主体转移的离子三重态能量而发光。 荧光主体具有取代或未取代的多环稠合芳族骨架，并且具有2.10eV至3.00eV的退出三线态能隙。

公开(公告)号：US08221907B2

公开(公告)日：2012-07-17

申请号：US12666226

申请日：2008-07-02

申请人： Masahiro Kawamura ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Masakazu Funahashi ,  Tetsuya Inoue ,  Yukitoshi Jinde ,  Yuichiro Kawamura ,  Mitsunori Ito ,  Yoriyuki Takashima ,  Toshinari Ogiwara

发明人： Masahiro Kawamura ,  Kazuki Nishimura ,  Toshihiro Iwakuma ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Masakazu Funahashi ,  Tetsuya Inoue ,  Yukitoshi Jinde ,  Yuichiro Kawamura ,  Mitsunori Ito ,  Yoriyuki Takashima ,  Toshinari Ogiwara

IPC分类号： H01L51/54 ,  C07C13/48

CPC分类号： H01L51/0054 ,  C07C13/567 ,  C07C13/72 ,  C07C15/38 ,  C07C2601/08 ,  C07C2601/14 ,  C07C2603/18 ,  C07C2603/26 ,  C07C2603/42 ,  C07C2603/48 ,  C07C2603/50 ,  C07C2603/94 ,  C07F7/0805 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0058 ,  H01L51/5016 ,  H01L51/5048 ,  Y10S428/917

摘要： A chrysene derivative shown by the following formula: wherein R1 to R10 and R21 to R25 are independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 ring carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 8 to 30 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 20 ring carbon atoms, provided that at least one of R21 to R25 is a substituted or unsubstituted fused aromatic ring group having 10 to 20 ring carbon atoms or a substituted or unsubstituted fluorenyl group.

摘要翻译： 由下式表示的衍生物衍生物：其中R1至R10和R21至R25独立地为氢原子，取代或未取代的碳原子数1〜10的烷基，取代或未取代的环碳原子数为3〜10的环烷基， 取代或未取代的碳原子数为3〜20的烷基甲硅烷基，取代或未取代的碳原子数为8〜30的芳基甲硅烷基或取代或未取代的环碳原子数为6〜20的芳基，只要R21〜R25中的至少一个为 是取代或未取代的环碳原子数为10〜20的稠环芳基或取代或未取代的芴基。

公开(公告)号：US08154195B2

公开(公告)日：2012-04-10

申请号：US12122316

申请日：2008-05-16

申请人： Kazuki Nishimura ,  Toshihiro Iwakuma ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Masahiro Kawamura ,  Mitsunori Ito ,  Yoriyuki Takashima ,  Toshinari Ogiwara

发明人： Kazuki Nishimura ,  Toshihiro Iwakuma ,  Kenichi Fukuoka ,  Chishio Hosokawa ,  Masahiro Kawamura ,  Mitsunori Ito ,  Yoriyuki Takashima ,  Toshinari Ogiwara

IPC分类号： H01L51/54 ,  C09K11/06 ,  H05B33/14

CPC分类号： H01L51/0052 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5048 ,  H01L51/5092 ,  H01L2251/308 ,  H05B33/20 ,  Y10S428/917

摘要： An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. In the organic electroluminescence device, the organic thin-film layer includes at least one emitting layer, and the at least one emitting layer contains: at least one phosphorescent material; and a host material represented by the following formula (1). Ra—Ar1—Ar2—Rb  (1) In the formula, Ar1, Ar2, Ra and Rb each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted condensed aromatic hydrocarbon group selected from a group consisting of a naphthalene ring, a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, a picene ring and a benzo[b]fluoranthene ring.

摘要翻译： 有机电致发光器件包括：阴极; 阳极; 以及设置在阴极和阳极之间的单层或多层有机薄膜层。 在有机电致发光器件中，有机薄膜层包括至少一个发光层，并且所述至少一个发光层包含：至少一种磷光材料; 和由下式（1）表示的主体材料。 Ra-Ar1-Ar2-Rb（1）式中，Ar1，Ar2，Ra和Rb表示取代或未取代的苯环或取代或未取代的稠合芳香族烃基，选自萘环， 环，荧蒽环，三亚苯环，菲环，苯并菲环，二苯并菲环，苯并亚苯环，苯并环，咔唑环和苯并[b]荧蒽环。

公开(公告)号：US08106582B2

公开(公告)日：2012-01-31

申请号：US10591688

申请日：2005-02-18

申请人： Keiko Yamamichi ,  Kenichi Fukuoka ,  Kimihiro Yuasa ,  Chishio Hosokawa ,  Hitoshi Kuma

发明人： Keiko Yamamichi ,  Kenichi Fukuoka ,  Kimihiro Yuasa ,  Chishio Hosokawa ,  Hitoshi Kuma

IPC分类号： H01L51/52 ,  H01J9/24

CPC分类号： H01L51/5036 ,  H01L27/3206 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/5265 ,  H01L2251/308 ,  H01L2251/5315 ,  H01L2251/558

摘要： An organic electroluminescent display (1) including: a substrate (11); and a first organic electroluminescent device part (10) and a second organic electroluminescent device part (20) placed side by side on a surface of the substrate; the first organic electroluminescent device part (10) including at least a light reflective conductive layer (12), an organic luminescent medium layer (13), and a transparent electrode layer (15) in this order and including a light reflective layer (14) inside or outside of the organic luminescent medium layer (13) or the transparent electrode layer (15); the second organic electroluminescent device part (20) including at least a light reflective conductive layer (12), a first inorganic compound layer (21), an organic luminescent medium layer (13), and a transparent electrode layer (15) in this order and including a light reflective layer (14) inside or outside of the organic luminescent medium layer (13) or the transparent electrode layer (15); and an emission spectrum of light from the first organic electroluminescent device part (10) differing from an emission spectrum of light from the second organic electroluminescent device part (20).

摘要翻译： 一种有机电致发光显示器（1），包括：基板（11）; 以及并排放置在所述基板的表面上的第一有机电致发光器件部件（10）和第二有机电致发光器件部件（20） 第一有机电致发光器件部分（10），其至少包括光反射导电层（12），有机发光介质层（13）和透明电极层（15），并且包括光反射层（14） 在有机发光介质层（13）或透明电极层（15）的内部或外部; 第二有机电致发光器件部分（20）至少包括光反射导电层（12），第一无机化合物层（21），有机发光介质层（13）和透明电极层（15） 并且在有机发光介质层（13）或透明电极层（15）的内部或外部包括光反射层（14）。 以及来自第一有机电致发光器件部分（10）的光的发射光谱与来自第二有机电致发光器件部分（20）的光的发射光谱不同。

公开(公告)号：US08106391B2

公开(公告)日：2012-01-31

申请号：US12670490

申请日：2008-09-26

申请人： Jun Endo ,  Kenichi Fukuoka ,  Toshihiro Iwakuma ,  Chishio Hosokawa ,  Tadahiko Yoshinaga ,  Emiko Kambe ,  Yasunori Kijima

发明人： Jun Endo ,  Kenichi Fukuoka ,  Toshihiro Iwakuma ,  Chishio Hosokawa ,  Tadahiko Yoshinaga ,  Emiko Kambe ,  Yasunori Kijima

IPC分类号： H01L51/00 ,  H01L51/30

CPC分类号： H01L51/006 ,  C09B57/00 ,  C09B57/008 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5048

摘要： An organic EL device includes: an anode, a cathode and an organic thin-film layer interposed between the anode and the cathode, in which the organic thin-film layer includes: an emitting layer containing a host material and a phosphorescent material; and a hole transporting layer provided adjacent to the anode relative to the emitting layer. The hole transporting layer includes a first hole transporting layer and a second hole transporting layer that are sequentially layered on the anode, in which the first hole transporting layer contains an amino compound substituted by an aromatic substituent represented by a formula (1) below and the second hole transporting layer contains at least one of compounds represented by formulae (2) to (5) below.

摘要翻译： 有机EL器件包括：阳极，阴极和介于阳极和阴极之间的有机薄膜层，其中有机薄膜层包括：含有主体材料和磷光材料的发射层; 以及相对于发光层与阳极相邻设置的空穴传输层。 空穴传输层包括依次层叠在阳极上的第一空穴传输层和第二空穴传输层，其中第一空穴传输层含有被下述式（1）表示的芳香族取代基取代的氨基化合物和 第二空穴传输层含有下述式（2）〜（5）表示的化合物中的至少一种。

公开(公告)号：US08021574B2

公开(公告)日：2011-09-20

申请号：US12102484

申请日：2008-04-14

申请人： Masahiro Kawamura ,  Kazuki Nishimura ,  Yoriyuki Takashima ,  Mitsunori Ito ,  Toshihiro Iwakuma ,  Toshinari Ogiwara ,  Chishio Hosokawa ,  Kenichi Fukuoka

发明人： Masahiro Kawamura ,  Kazuki Nishimura ,  Yoriyuki Takashima ,  Mitsunori Ito ,  Toshihiro Iwakuma ,  Toshinari Ogiwara ,  Chishio Hosokawa ,  Kenichi Fukuoka

IPC分类号： C09K11/00 ,  C07C15/00 ,  C07C15/20

CPC分类号： C09K11/565 ,  C07C13/567 ,  C07C15/24 ,  C07C15/30 ,  C07D235/08 ,  C09K11/06 ,  C09K2211/1011 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0085 ,  H01L51/5012 ,  H01L2251/308 ,  H05B33/14 ,  H05B33/20

摘要： A naphthalene derivative represented by the following formula (1) is provided. In the formula, Ar1 to Ar4 each represent an aromatic hydrocarbon cyclic group having 6 to 18 carbon atoms forming a ring. The aromatic hydrocarbon cyclic group has none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. n, m and l each represent an integer in a range of 1 to 5. p represents an integer in a range of 0 to 5. When n, m, l and p each are 2 or more, a plurality of Ar1 to Ar4 may be mutually the same or different.

摘要翻译： 提供由下式（1）表示的萘衍生物。 式中，Ar 1〜Ar 4表示碳原子数为6〜18的芳香族烃环，形成环。 芳烃环状基团没有蒽骨架，芘骨架，乙炔骨架和并四苯骨架。 n，m和l各自表示1〜5的整数.p表示0〜5的整数.n，m，l和p分别为2以上时，多个Ar 1〜Ar 4可以 相互相同或不同。