公开(公告)号：US10744482B2

公开(公告)日：2020-08-18

申请号：US16434472

申请日：2019-06-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10703767B2

公开(公告)日：2020-07-07

申请号：US16280504

申请日：2019-02-20

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Dong-Xu Xue ,  Amy J. Cairns ,  Youssef Belmabkhout

IPC: C07F5/00 ,  B01J31/16 ,  C07C51/41 ,  B01J20/22

Abstract: Embodiments of the present disclosure describe compositions comprising a molecular building block (MBB) having the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion. Embodiments of the present disclosure further describe methods of making a metal-organic framework (MOF) composition comprising contacting one or more molecular building blocks (MBBs) with one or more bidentate ligands, wherein the MBBs have the formula [RE6(μ3-OH)8(O2C—)6N4C—)6] or [RE6(μ3-OH)8(O2C—)12], wherein RE is a rare earth metal ion.

公开(公告)号：US10322402B2

公开(公告)日：2019-06-18

申请号：US15532839

申请日：2015-12-04

Applicant: King Abdullah University of Science and Technology

Inventor： Dalal Alezi ,  Youssef Belmabkhout ,  Mohamed Eddaoudi

IPC: B01D53/02 ,  B01D53/14 ,  B01D53/46 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22 ,  C10L3/06 ,  C10L3/10 ,  B01D53/047 ,  F17C11/00

Abstract: Embodiments provide a method of storing a compound using a metal organic framework (MOF). The method includes contacting one or more MOFs with a fluid and sorbing one or more compounds, such as O2 and CH4. O2 and CH4 can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF, wherein M can include aluminum, iron, gallium, indium, vanadium, chromium, titanium, or scandium.

公开(公告)号：US10001448B2

公开(公告)日：2018-06-19

申请号：US14375665

申请日：2013-01-30

Applicant: King Abdullah University of Science and Technology

Inventor： Ryan Luebke ,  Mohamed Eddaoudi ,  Hesham Omran ,  Youssef Belmabkhout ,  Osama Shekhah ,  Khaled N. Salama

IPC: G01N27/02 ,  G01N33/00 ,  G01N27/04 ,  G01N27/12

CPC classification number: G01N27/02 ,  G01N27/041 ,  G01N27/12 ,  G01N33/0027 ,  G01N33/0031 ,  Y10T29/49117

Abstract: A gas sensor using a metal organic framework material can be fully integrated with related circuitry on a single substrate. In an on-chip application, the gas sensor can result in an area-efficient fully integrated gas sensor solution. In one aspect, a gas sensor can include a first gas sensing region including a first pair of electrodes, and a first gas sensitive material proximate to the first pair of electrodes, wherein the first gas sensitive material includes a first metal organic framework material.

公开(公告)号：US09663627B2

公开(公告)日：2017-05-30

申请号：US14549108

申请日：2014-11-20

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

Inventor： Mohamed Eddaoudi ,  Vincent Guillerm ,  Lukasz Weselinski ,  Mohamed H. Alkordi ,  Mohamed Infas Haja Mohideen ,  Youssef Belmabkhout

IPC: C08J9/36

CPC classification number: C08J9/36 ,  B01D53/02 ,  B01D2253/202 ,  B01D2253/204 ,  B01D2256/10 ,  B01D2256/12 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2257/504 ,  B01J20/226 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/3085 ,  B01J20/3206 ,  B01J20/3257 ,  C08J2201/036 ,  C10L3/104 ,  Y02C10/08 ,  Y02P20/152

Abstract: Amine groups can be introduced in porous materials by a direct (one pot) or post-synthetic modification (PSM) process on aldehyde groups, and the resulting porous materials have increased gas affinity.

公开(公告)号：US20150020577A1

公开(公告)日：2015-01-22

申请号：US14375665

申请日：2013-01-30

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

Inventor： Ryan Luebke ,  Mohamed Eddaoudi ,  Hesham Omran ,  Youssef Belmabkhout ,  Osama Shekhah ,  Khaled N. Salama

IPC: G01N27/02 ,  G01N33/00

CPC classification number: G01N27/02 ,  G01N27/041 ,  G01N27/12 ,  G01N33/0027 ,  G01N33/0031 ,  Y10T29/49117

Abstract: A gas sensor using a metal organic framework material can be fully integrated with related circuitry on a single substrate. In an on-chip application, the gas sensor can result in an area-efficient fully integrated gas sensor solution. In one aspect, a gas sensor can include a first gas sensing region including a first pair of electrodes, and a first gas sensitive material proximate to the first pair of electrodes, wherein the first gas sensitive material includes a first metal organic framework material.

Abstract translation: 使用金属有机骨架材料的气体传感器可以与单个基板上的相关电路完全集成。 在片上应用中，气体传感器可以产生全面集成的气体传感器解决方案。 在一个方面，气体传感器可以包括包括第一对电极的第一气体感测区域和靠近第一对电极的第一气体敏感材料，其中第一气体敏感材料包括第一金属有机骨架材料。