Herbicidal agents based on N-azolylmethylacetanilides and
cyclohexane-1,3-dione derivatives
    41.
    发明授权
    Herbicidal agents based on N-azolylmethylacetanilides and cyclohexane-1,3-dione derivatives 失效
    基于N-吡唑基甲基乙酰苯胺和环己烷-1,3-二酮衍生物的除草剂

    公开(公告)号:US4340418A

    公开(公告)日:1982-07-20

    申请号:US149965

    申请日:1980-05-15

    摘要: Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R, R.sup.1, R.sup.2, A and X have the meanings given in the disclosure, and a substituted cyclohexane-1,3-dione derivative of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, X and n have the meanings given in the disclosure, or a metal salt or ammonium salt of this cyclohexane-1,3-dione derivative.The ratio of N-azolylmethylhaloacetanilide of the formula I to cyclohexane-1,3-dione derivative of the formula II is from 1:0.125 to 1:10 parts by weight. The agents are suitable for combating unwanted grassy plants.

    摘要翻译: 含有下式的其中R,R 1,R 2,A和X具有本公开中给出的含义的式I的N-吡唑基甲基卤代乙酰替苯胺的除草剂和式II的取代的环己烷-1,3-二酮衍生物 其中R1,R2,R3,R4,X和n具有本公开内容中给出的含义,或该环己烷-1,3-二酮衍生物的金属盐或铵盐。 式I的N-吡唑基甲基卤代乙酰苯胺与式II的环己烷-1,3-二酮衍生物的比例为1:0.125至1:10重量份。 这些试剂适用于对付不想要的草本植物。

    Carboxylic acid derivatives
    43.
    发明授权
    Carboxylic acid derivatives 失效
    羧酸衍生物

    公开(公告)号:US5085685A

    公开(公告)日:1992-02-04

    申请号:US566536

    申请日:1990-08-13

    摘要: Carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy and/or C.sub.1 -C.sub.4 -alkylthio;R.sup.3 is hydrogen, hydroxyl, cyano, nitro, formyl, halogen, unsubstituted or substituted amino, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.6 -alkynyloxy;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is unsubstituted or substituted five-membered hetaryl or isoxazolinyl or --CR.sup.6 .dbd.NOR.sup.7 ;R.sup.6 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;R.sup.7 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;A is oxygen or sulfur;X is nitrogen or methine .dbd.CR.sup.8 --;R.sup.8 is one of the radicals R.sup.3, or R.sup.8 and R.sup.3 together form unsubstituted or substituted 1,3-butadiene-1,4-yl or aza-1,3-butadiene-1,4-yl, andY and Z are each nitrogen or methine .dbd.CH--, their preparation and agents containing them.

    摘要翻译: 其中R 1和R 2各自为C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷氧基和/或C 1 -C 4 - 烷硫基的通式I的羧酸衍生物; R3是氢,羟基,氰基,硝基,甲酰基,卤素,未取代或取代的氨基,C1-C4-烷基,C1-C4-烷氧基,C3-C6-烯基,C3-C6-烯氧基,C3-C6-炔基或C3 -C 6 - 炔氧基; R4是氢或C1-C4-烷基; R5是未取代的或取代的五元杂芳基或异恶唑啉基或-CR 6 = NOR 7; R6是氢或未取代或取代的C1-C4-烷基,C3-C8-环烷基或苯基; R 7为未取代或取代的C 1 -C 4 - 烷基,C 3 -C 6 - 烯基,C 3 -C 8 - 环烷基或苯基; A是氧或硫; X是氮或次甲基= CR8-; R8是基团R3之一,或R8和R3一起形成未取代或取代的1,3-丁二烯-1,4-基或氮杂-1,3-丁二烯-1,4-基,Y和Z各自为氮 或次甲基= CH-,它们的制备物和含有它们的试剂。

    Herbicidal agents based on acetanilides

    公开(公告)号:US4373945A

    公开(公告)日:1983-02-15

    申请号:US209961

    申请日:1980-11-24

    摘要: Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole which is attached via a ring nitrogen atom and is unsubstituted or mono- or poly-substituted by halogen, phenyl, alkyl, alkoxy, alkylthio or perfluoroalkyl, each of a maximum of 4 carbon atoms, cyano, carboxy, carbalkoxy of a maximum of 4 carbon atoms in the alkoxy, or alkanoyl of a maximum of 4 carbon atoms, A also denoting a salt of an azole containing 2 or 3 nitrogen atoms, and a haloacetanilide of the formula ##STR2## where R denotes linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting linear or branched alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-yl or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to haloacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.

    Herbicidal agents based on acetanilides
    47.
    发明授权
    Herbicidal agents based on acetanilides 失效
    基于乙酰苯胺的除草剂

    公开(公告)号:US4277278A

    公开(公告)日:1981-07-07

    申请号:US56146

    申请日:1979-07-09

    摘要: Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole and a haloacetanilide of the formula ##STR2## where R denotes alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-y1 or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 each denotes hydrogen or alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to halcacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.

    摘要翻译: 含有式“IMAGE”I的N-吡唑基甲基卤代乙酰替苯胺的除草剂,其中R表示氢或最多5个碳原子的烷基或烷氧基,R1表示氢,卤素或最多5个碳原子的烷基或烷氧基,R2 表示氢,卤素或最多5个碳原子的烷基或烷氧基,R与R2一起形成最多6个碳原子的亚烷基链,其在o位上连接并且未被取代或被直链烷基取代 最多4个碳原子,X表示氯或溴,A表示式II的唑和卤代乙酰苯胺,其中R表示最多4个碳原子的烷基,烯基或炔基,或-A- R1,A表示可被乙基单取代或被甲基单取代或被二取代的1或2个碳原子的亚烷基,R1表示最多4个碳原子的烷氧基,卤代烷氧基,链烯氧基,炔氧基或烷氧基烷氧基,环烷氧基或环烷基甲氧基 在t中具有3至6个碳原子 环烷基环,1,3-二氧戊环-2-基或烷氧基中最多4个碳原子的烷氧基羰基,X表示氯或溴,Y1和Y2各自表示氢或最多4个碳原子的烷基,Y1 而当R为烷基,烯基或炔基时,Y2仅表示氢,最多4个碳原子。 式I的N-吡唑基甲基卤代乙酰苯胺与式II的卤代乙酰苯胺的比例为1:0.5至1:20重量份。

    Herbicidal agents containing a thiolcarbamate
    50.
    发明授权
    Herbicidal agents containing a thiolcarbamate 失效
    含有硫代氨基甲酸酯的除草剂

    公开(公告)号:US4249933A

    公开(公告)日:1981-02-10

    申请号:US058259

    申请日:1979-07-17

    摘要: Herbicidal agents containing ethyl-N-ethyl-N-bicyclo-[2.2.1]-hept-2-yl-thiolcarbamate of the formula ##STR1## as herbicidal active ingredient and at least one haloacylamide of the formula ##STR2## where R denotes linear or branched haloalkyl of a maximum of 3 carbon atoms, and R.sup.1 and R.sup.2 are identical or different and each denotes linear or branched alkyl of a maximum of 6 carbon atoms which is unsubstituted or substituted by alkoxy of a maximum of 4 carbon atoms or by cyano, R.sup.1 and R.sup.2 further denote cycloalkyl of 3 to 6 carbon atoms, or linear or branched alkenyl or alkynyl of a maximum of 4 carbon atoms, or R.sup.1 and R.sup.2, together with the nitrogen atom whose substituents they are, form a 4- to 9-membered, saturated monocyclic or bicyclic ring which is unsubstituted or mono- or polysubstituted by linear or branched alkyl of a maximum of 4 carbon atoms, or a tetrahydro-1,3-oxazine ring of the formula ##STR3## where R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 3 carbon atoms, R.sup.8 denotes hydrogen or linear or branched alkyl of a maximum of 8 carbon atoms, R.sup.9 denotes hydrogen, linear or branched alkyl of a maximum of 8 carbon atoms, alkoxyalkyl of a maximum of 6 carbon atoms or dialkoxyalkyl of a maximum of 8 carbon atoms, or R.sup.8 and R.sup.9 may together form a methylene chain of 4 or 5 carbon atoms, as antagonistic agent.The weight ratio of ethyl-N-ethyl-N-bicyclo-[2.2.1]-hept-2-yl-thiolcarbamate to antagonistic agent is, whether applied together or separately, from 1:1 to 1:0.01.

    摘要翻译: 含有式“IMAGE”的乙基-N-乙基-N-双环[2.2.1] - 庚-2-基 - 硫代氨基甲酸酯作为除草活性成分的除草剂和至少一种式(I')I的卤代酰胺,其中 R表示最多3个碳原子的直链或支链卤代烷基,R1和R2相同或不同,表示最多6个碳原子的直链或支链烷基,未取代或被最多4个碳原子的烷氧基取代 或氰基,R 1和R 2还表示3至6个碳原子的环烷基,或最多4个碳原子的直链或支链烯基或炔基,或者R1和R2与它们取代基的氮原子一起形成4个 至9元饱和的单环或双环,其未被取代或被最多4个碳原子的直链或支链烷基单取代或多取代,或式“IMAGE”的四氢-1,3-恶嗪环,其中R3 ,R4,R5,R6和R7相同或不同,各自表示氢 或最多3个碳原子的直链或支链烷基,R8表示氢或最多8个碳原子的直链或支链烷基,R9表示氢,最多8个碳原子的直链或支链烷基,最大为 6个碳原子或最多8个碳原子的二烷氧基烷基,或R8和R9可以一起形成4或5个碳原子的亚甲基链作为拮抗剂。 乙基-N-乙基-N-双环[2.2.1] - 庚-2-基 - 硫代氨基甲酸乙酯与拮抗剂的重量比无论是一起使用还是单独使用,为1:1至1:0.01。