摘要:
Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R, R.sup.1, R.sup.2, A and X have the meanings given in the disclosure, and a substituted cyclohexane-1,3-dione derivative of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, X and n have the meanings given in the disclosure, or a metal salt or ammonium salt of this cyclohexane-1,3-dione derivative.The ratio of N-azolylmethylhaloacetanilide of the formula I to cyclohexane-1,3-dione derivative of the formula II is from 1:0.125 to 1:10 parts by weight. The agents are suitable for combating unwanted grassy plants.
摘要:
Salicylaldehyde derivatives and salicylic acid derivatives of the formula I ##STR1## where A is an unsubstituted or substituted phenyl radical, an unsubstituted or substituted 5-membered heteroaromatic radical having from 2 to 4 nitrogen atoms or two nitrogen atoms and additionally one sulfur or oxygen atom or an unsubstituted or substituted thienyl, pyridyl, naphthyl, quinolyl, indazolyl or benzotriazolyl radical, X is oxygen or sulfur, and the radicals R.sup.1 to R.sup.4 have the meanings given in the specification, processes and intermediates for their production, and their use as herbicides and bioregulators.
摘要:
Carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy and/or C.sub.1 -C.sub.4 -alkylthio;R.sup.3 is hydrogen, hydroxyl, cyano, nitro, formyl, halogen, unsubstituted or substituted amino, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.6 -alkynyloxy;R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl;R.sup.5 is unsubstituted or substituted five-membered hetaryl or isoxazolinyl or --CR.sup.6 .dbd.NOR.sup.7 ;R.sup.6 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;R.sup.7 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkyl or phenyl;A is oxygen or sulfur;X is nitrogen or methine .dbd.CR.sup.8 --;R.sup.8 is one of the radicals R.sup.3, or R.sup.8 and R.sup.3 together form unsubstituted or substituted 1,3-butadiene-1,4-yl or aza-1,3-butadiene-1,4-yl, andY and Z are each nitrogen or methine .dbd.CH--, their preparation and agents containing them.
摘要:
Novel chloroacetic acid cyclohexylamides of the formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 have the meanings given in the description, their preparation and their use as herbicides.
摘要:
Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or linear or branched alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole which is attached via a ring nitrogen atom and is unsubstituted or mono- or poly-substituted by halogen, phenyl, alkyl, alkoxy, alkylthio or perfluoroalkyl, each of a maximum of 4 carbon atoms, cyano, carboxy, carbalkoxy of a maximum of 4 carbon atoms in the alkoxy, or alkanoyl of a maximum of 4 carbon atoms, A also denoting a salt of an azole containing 2 or 3 nitrogen atoms, and a haloacetanilide of the formula ##STR2## where R denotes linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting linear or branched alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-yl or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is linear or branched alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to haloacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.
摘要:
The present invention relates to acetanilides, processes for the manufacture of these acetanilides, herbicides containing these compounds, and processes for combating the growth of unwanted plants with these compounds.
摘要:
Herbicidal agents containing an N-azolylmethylhaloacetanilide of the formula ##STR1## where R denotes hydrogen or alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.1 denotes hydrogen, halogen, or alkyl or alkoxy of a maximum of 5 carbon atoms, R.sup.2 denotes hydrogen, halogen, or alkyl or alkoxy of a maximum of 5 carbon atoms, R together with R.sup.2 forms an alkylene chain of a maximum of 6 carbon atoms which is linked in the o-position and is unsubstituted or substituted by linear alkyl of a maximum of 4 carbon atoms, X denotes chlorine or bromine, and A denotes an azole and a haloacetanilide of the formula ##STR2## where R denotes alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms, or --A--R.sup.1, A denoting alkylene of 1 or 2 carbon atoms which may be monosubstituted by ethyl or mono- or disubstituted by methyl, and R.sup.1 denoting alkoxy, haloalkoxy, alkenoxy, alkynoxy or alkoxyalkoxy, each of a maximum of 4 carbon atoms, cycloalkoxy or cycloalkylmethoxy with 3 to 6 carbon atoms in the cycloalkyl ring, 1,3-dioxolan-2-y1 or alkoxycarbonyl of a maximum of 4 carbon atoms in the alkoxy, X denotes chlorine or bromine, and Y.sup.1 and Y.sup.2 each denotes hydrogen or alkyl of a maximum of 4 carbon atoms, Y.sup.1 and Y.sup.2 only denoting hydrogen when R is alkyl, alkenyl or alkynyl, each of a maximum of 4 carbon atoms.The ratio of N-azolylmethylhaloacetanilide of the formula I to halcacetanilide of the formula II is from 1:0.5 to 1:20 parts by weight.
摘要:
Isoxazolylmethylthiol carbamates, herbicides containing these compounds, and methods of controlling the growth of unwanted plants with these compounds.
摘要:
Substituted N-aminomethylhaloacetanilides of the formula ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.2 -alkyl, R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.4 is cyano or --CO--NH.sub.2, R.sup.5 is C.sub.1 -C.sub.6 -alkyl and X is halogen, are used for controlling undesirable plant growth.
摘要:
Herbicidal agents containing ethyl-N-ethyl-N-bicyclo-[2.2.1]-hept-2-yl-thiolcarbamate of the formula ##STR1## as herbicidal active ingredient and at least one haloacylamide of the formula ##STR2## where R denotes linear or branched haloalkyl of a maximum of 3 carbon atoms, and R.sup.1 and R.sup.2 are identical or different and each denotes linear or branched alkyl of a maximum of 6 carbon atoms which is unsubstituted or substituted by alkoxy of a maximum of 4 carbon atoms or by cyano, R.sup.1 and R.sup.2 further denote cycloalkyl of 3 to 6 carbon atoms, or linear or branched alkenyl or alkynyl of a maximum of 4 carbon atoms, or R.sup.1 and R.sup.2, together with the nitrogen atom whose substituents they are, form a 4- to 9-membered, saturated monocyclic or bicyclic ring which is unsubstituted or mono- or polysubstituted by linear or branched alkyl of a maximum of 4 carbon atoms, or a tetrahydro-1,3-oxazine ring of the formula ##STR3## where R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are identical or different and each denotes hydrogen or linear or branched alkyl of a maximum of 3 carbon atoms, R.sup.8 denotes hydrogen or linear or branched alkyl of a maximum of 8 carbon atoms, R.sup.9 denotes hydrogen, linear or branched alkyl of a maximum of 8 carbon atoms, alkoxyalkyl of a maximum of 6 carbon atoms or dialkoxyalkyl of a maximum of 8 carbon atoms, or R.sup.8 and R.sup.9 may together form a methylene chain of 4 or 5 carbon atoms, as antagonistic agent.The weight ratio of ethyl-N-ethyl-N-bicyclo-[2.2.1]-hept-2-yl-thiolcarbamate to antagonistic agent is, whether applied together or separately, from 1:1 to 1:0.01.