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    Compact sulfur recovery plant and process
    43.
    发明授权
    Compact sulfur recovery plant and process 有权
    紧凑型硫磺回收厂和工艺

    公开(公告)号：US07226572B1

    公开(公告)日：2007-06-05

    申请号：US11367077

    申请日：2006-03-03

    申请人： Alfred E. Keller ,  Sriram Ramani ,  Joe D. Allison ,  Steven E. Lusk ,  Nathan A. Hatcher ,  Larry D. Swinney ,  Kerri J. Kirkendall ,  Gilbert E. Torres ,  Paul D. Stewart ,  Terry D. Pruitt

    发明人： Alfred E. Keller ,  Sriram Ramani ,  Joe D. Allison ,  Steven E. Lusk ,  Nathan A. Hatcher ,  Larry D. Swinney ,  Kerri J. Kirkendall ,  Gilbert E. Torres ,  Paul D. Stewart ,  Terry D. Pruitt

    IPC分类号： B01J12/00 ,  B01J12/02 ,  B01J19/00 ,  C01B17/04

    CPC分类号： C01B17/046 ,  C01B17/0404 ,  Y02P20/129 ,  Y10S423/06

    摘要： A compact sulfur recovery system is disclosed which comprises a primary structure including a catalytic partial oxidation reaction zone, a first temperature-control zone, a first Claus catalytic reaction zone, a second temperature-control zone, a first liquid sulfur outlet, and a first effluent gas outlet. In some embodiments, a secondary structure follows the primary structure and comprises a second Claus catalytic reaction zone, a third temperature-control zone, a second liquid sulfur outlet, and a second effluent gas outlet. One or more components of the system employ heat transfer enhancement material in the temperature-control zones, and one or more components deter accumulation of liquid sulfur in the Claus catalytic reaction zones. A process for recovering elemental sulfur from hydrogen sulfide-containing gas streams comprises regulating the temperature of certain components to favor the partial oxidation reaction, and the Claus reaction, as appropriate, and deters pooling of liquid sulfur on the Claus catalyst(s).

    摘要翻译： 公开了一种紧凑的硫回收系统，其包括主要结构，其包括催化部分氧化反应区，第一温度控制区，第一克劳斯催化反应区，第二温度控制区，第一液硫出口和第一 废气出口。 在一些实施方案中，二级结构遵循一级结构，并且包括第二克劳斯催化反应区，第三温度控制区，第二液体硫出口和第二流出气体出口。 该系统的一个或多个组件在温度控制区中采用传热增强材料，并且一个或多个组分阻止了克劳斯催化反应区中液体硫的积聚。 从含硫化氢的气流中回收元素硫的方法包括调节某些组分的温度以有利于部分氧化反应，适当地克劳斯反应，并阻止液体硫在克劳斯催化剂上的混合。

    Process for converting alkanes to carbon filaments
    44.
    发明授权
    Process for converting alkanes to carbon filaments 有权
    将烷烃转化为碳丝的方法

    公开(公告)号：US07078008B2

    公开(公告)日：2006-07-18

    申请号：US10263315

    申请日：2002-10-01

    申请人： Joe D. Allison ,  Sriram Ramani ,  Priya Rangarajan ,  Kenneth M. York ,  Troy L. Amundson ,  Gary E. Welch

    发明人： Joe D. Allison ,  Sriram Ramani ,  Priya Rangarajan ,  Kenneth M. York ,  Troy L. Amundson ,  Gary E. Welch

    IPC分类号： D01F9/127

    CPC分类号： B82Y30/00 ,  D01F9/1271

    摘要： The present invention includes a process for producing carbon filaments and synthesis gas from a mixture of alkanes, preferably natural gas, comprising converting a first portion of the alkanes, preferably C2+ hydrocarbons, directly to carbon filaments and converting a second portion of the alkanes, preferably methane, to syngas. The natural gas may be separated into a first feed stream comprising ethane, propane, and butane and a second feed stream comprising methane. The first feed stream is fed to a carbon filament CF reactor to produce carbon filaments and hydrogen. The second feed stream is fed to a syngas production reactor to produce syngas. Alternatively, the natural gas is fed to at least one carbon filament reactor that is maintained at an effective temperature to convert C2+ hydrocarbons in the natural gas to carbon filaments and hydrogen, thereby filtering methane from the natural gas.

    摘要翻译： 本发明包括从烷烃，优选天然气的混合物生产碳丝和合成气的方法，包括将第一部分烷烃，优选C 2 O 3， 碳氢化合物直接转化为碳丝并将第二部分烷烃，优选甲烷转化为合成气。 天然气可以分离成包含乙烷，丙烷和丁烷的第一进料流和包含甲烷的第二进料流。 将第一进料流送入碳丝CF反应器以产生碳丝和氢。 将第二进料流送入合成气生产反应器以产生合成气。 或者，将天然气进料至至少一个碳丝反应器，其保持在有效温度以将天然气中的C 2 O 2 CO 2烃转化为碳丝和氢 从而从天然气中过滤甲烷。

    MCrAlY supported catalysts for oxidative dehydrogenation of alkanes
    45.
    发明授权
    MCrAlY supported catalysts for oxidative dehydrogenation of alkanes 失效
    MCrAlY负载催化剂用于烷烃的氧化脱氢

    公开(公告)号：US06831204B2

    公开(公告)日：2004-12-14

    申请号：US10269174

    申请日：2002-10-11

    申请人： Zhen Chen ,  Sriram Ramani ,  Lisa M. Carmichael ,  Joe D. Allison

    发明人： Zhen Chen ,  Sriram Ramani ,  Lisa M. Carmichael ,  Joe D. Allison

    IPC分类号： C07C5327

    CPC分类号： C07C5/48 ,  C07C2523/76 ,  C07C2523/89 ,  C07C11/02

    摘要： A new family of oxidative dehydrogenation catalysts having MCrAlY supports can be used in the production of olefins. Olefins are produced by heating a feed stream comprising at least an alkane and an oxidant to a temperature between 25° C. and 800° C.; contacting the feed stream with a catalyst comprising an MCrAlY structure and, optionally, a Group VIII promoter metal coating, wherein M is a base metal, or combination of base metals; and maintaining a contact time of the alkane with the catalyst of less than 200 milliseconds under conditions sufficient to achieve oxidative dehydrogenation of the alkane. M may comprise a metal selected from the group consisting of Group IB-VIIB metals, Group IIIA-VA metals, lanthanide metals, iron, cobalt, nickel, and combinations thereof. More particularly, M may comprise a metal selected from the group consisting Tb, Sm, Pr, Fe, Ni, Co, and combinations thereof.

    摘要翻译： 具有MCrAlY载体的新的氧化脱氢催化剂系列可用于烯烃的生产。 通过将包含至少一种烷烃和氧化剂的进料流加热至25℃至800℃之间的温度来生产烯烃; 使进料流与包含MCrAlY结构和任选的VIII族助催化剂金属涂层的催化剂接触，其中M是贱金属或贱金属的组合; 并且在足以实现烷烃的氧化脱氢的条件下，保持烷烃与催化剂的接触时间小于200毫秒。 M可以包含选自IB-VIIB族金属，IIIA-VA族金属，镧系金属，铁，钴，镍及其组合的金属。 更具体地，M可以包含选自Tb，Sm，Pr，Fe，Ni，Co及其组合的金属。

    Methanation Reaction Methods Utilizing Enhanced Catalyst Formulations and Methods of Preparing Enhanced Methanation Catalysts
    47.
    发明申请
    Methanation Reaction Methods Utilizing Enhanced Catalyst Formulations and Methods of Preparing Enhanced Methanation Catalysts 有权
    使用增强催化剂配方的甲烷化反应方法和制备增强甲烷化催化剂的方法

    公开(公告)号：US20120238647A1

    公开(公告)日：2012-09-20

    申请号：US13421118

    申请日：2012-03-15

    申请人： Scott A. Scholten ,  Joe D. Allison ,  Brian C. Dunn

    发明人： Scott A. Scholten ,  Joe D. Allison ,  Brian C. Dunn

    IPC分类号： C07C27/00

    CPC分类号： C07C9/04 ,  B01J21/08 ,  B01J23/866 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  C07C1/12 ,  C07C2523/26 ,  C07C2523/755

    摘要： Enhanced mixed metal catalysts are provided which allow high conversions of carbon dioxide to methane, in some cases up to about 100% conversion. Methods of preparing enhanced mixed metal catalysts comprise a series of steps involving combining nickel and chromium salts with a nucleation promoter in a base environment to form a gel, allowing the gel to digest to form a solid and a mother liquor, isolating the solid, washing the solid, drying the solid, and thermally treating the solid to form a nickel-chromium catalyst. Methanation processes using the catalysts are also provided. The enhanced mixed metal catalysts provide more efficient conversion and lower operating temperatures for carbon dioxide methanation when compared to conventional methanation catalysts. Additionally, these enhanced catalyst formulations allow realization of higher value product from captured carbon dioxide.

    摘要翻译： 提供了增强的混合金属催化剂，其允许二氧化碳高达甲烷的转化率，在一些情况下高达约100％的转化率。 制备增强的混合金属催化剂的方法包括一系列步骤，包括将镍和铬盐与基础环境中的成核促进剂结合以形成凝胶，使凝胶消化形成固体和母液，分离固体，洗涤 固体，干燥固体，并对固体进行热处理以形成镍 - 铬催化剂。 还提供了使用催化剂的甲烷化方法。 与常规甲烷化催化剂相比，增强的混合金属催化剂提供了更有效的转化和降低二氧化碳甲烷化的操作温度。 此外，这些增强的催化剂配方允许从捕获的二氧化碳实现更高价值的产物。

    IN SITU CATALYTIC UPGRADING
    48.
    发明申请
    IN SITU CATALYTIC UPGRADING 审中-公开
    在现场催化升级

    公开(公告)号：US20120227966A1

    公开(公告)日：2012-09-13

    申请号：US13410891

    申请日：2012-03-02

    申请人： Wayne Reid Dreher, JR. ,  Joe D. Allison ,  Wendell P. Menard ,  Thomas J. Wheeler

    发明人： Wayne Reid Dreher, JR. ,  Joe D. Allison ,  Wendell P. Menard ,  Thomas J. Wheeler

    IPC分类号： E21B43/24 ,  E21B43/12

    CPC分类号： E21B43/243 ,  E21B36/04 ,  E21B43/305

    摘要： A system and method for in situ upgrading of crude oil is provided. The system includes at least one injection well, at least two first production wells, and at least one second production well. The at least one injection well has a vertical portion and a plurality of non-vertical portions connected to the vertical portion. The at least two first production wells are preferably equi-spaced and each has a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells is horizontally spaced apart. The at least one second production well has a horizontal portion with a second axial direction. The catalytic reactor is placed at the horizontal portion of the at least one second production well such that oil coming through the second production well will first go through the catalytic reactor for hydroprocessing.

    摘要翻译： 提供了原油原位升级的系统和方法。 该系统包括至少一个注入井，至少两个第一生产井和至少一个第二生产井。 至少一个注入井具有连接到垂直部分的垂直部分和多个非垂直部分。 所述至少两个第一生产井优选为等间隔的，并且每个具有第一轴向方向的水平部分，其中第一生产井的每个所述水平部分水平间隔开。 所述至少一个第二生产井具有具有第二轴向方向的水平部分。 将催化反应器放置在至少一个第二生产井的水平部分，使得通过第二生产井的油将首先经过用于加氢处理的催化反应器。

    Octane improvement of a hydrocarbon stream
    50.
    发明授权
    Octane improvement of a hydrocarbon stream 有权
    辛烷值改善烃流

    公开(公告)号：US07541504B2

    公开(公告)日：2009-06-02

    申请号：US11050188

    申请日：2005-02-03

    申请人： Priya Rangarajan ,  Steven R. McDonald ,  Joe D. Allison ,  Keith H. Lawson ,  Oluwaseyi A. Odueyungbo ,  Doug S. Jack ,  Rafael L. Espinoza

    发明人： Priya Rangarajan ,  Steven R. McDonald ,  Joe D. Allison ,  Keith H. Lawson ,  Oluwaseyi A. Odueyungbo ,  Doug S. Jack ,  Rafael L. Espinoza

    IPC分类号： C07C15/00 ,  C07C4/04

    CPC分类号： C10G59/00

    摘要： The invention relates to methods for improving the octane number of a synthetic naphtha stream and optionally for producing olefins and/or solvents. In one embodiment, the method comprises aromatizing at least a portion of a synthetic naphtha stream to produce an aromatized hydrocarbon stream; and isomerizing at least a portion of the aromatized hydrocarbon stream to produce an isomerized aromatized hydrocarbon stream having a higher octane rating than the synthetic naphtha stream. Alternatively, the method comprises providing at least three synthetic naphtha cuts comprising a C4-C5 stream; a C6-C8 stream and a C9-C11 stream; aromatizing some of the C6-C8 stream to form an aromatized hydrocarbon stream with a higher octane number; steam cracking some of the C6-C8 stream and optionally the C9-C11 stream to form olefins; and selling some portions of C9-C11 stream as solvents. In preferred embodiments, the synthetic naphtha is derived from Fischer-Tropsch synthesis.

    摘要翻译： 本发明涉及用于改进合成石脑油流的辛烷值并任选地用于生产烯烃和/或溶剂的方法。 在一个实施方案中，该方法包括将至少一部分合成石脑油流芳构化以产生芳族烃流; 并使至少一部分芳构化烃物流异构化以产生具有比合成石脑油流更高辛烷值的异构化芳构化烃物流。 或者，该方法包括提供包含C4-C5流的至少三个合成石脑油切割; C6-C8流和C9-C11流; 使一些C 6 -C 8流芳构化以形成具有较高辛烷值的芳构化烃流; 蒸汽裂解一些C6-C8流和任选的C9-C11流以形成烯烃; 并将C9-C11流的一些部分作为溶剂出售。 在优选的实施方案中，合成石脑油衍生自费 - 托合成。