Octane improvement of a hydrocarbon stream
    1.
    发明授权
    Octane improvement of a hydrocarbon stream 有权
    辛烷值改善烃流

    公开(公告)号:US06875339B2

    公开(公告)日:2005-04-05

    申请号:US10795895

    申请日:2004-03-08

    CPC分类号: C10G59/00

    摘要: The invention relates to methods for improving the octane number of a synthetic naphtha stream and optionally for producing olefins and/or solvents. In one embodiment, the method comprises aromatizing at least a portion of a synthetic naphtha stream to produce an aromatized hydrocarbon stream; and isomerizing at least a portion of the aromatized hydrocarbon stream to produce an isomerized aromatized hydrocarbon stream having a higher octane rating than the synthetic naphtha stream. Alternatively, the method comprises providing at least three synthetic naphtha cuts comprising a C4-C5 stream; a C6-C8 stream and a C9-C11 stream; aromatizing some of the C6-C8 stream to form an aromatized hydrocarbon stream with a higher octane number; steam cracking some of the C6-C8 stream and optionally the C9-C11 stream to form olefins; and selling some portions of C9-C11 stream as solvents. In preferred embodiments, the synthetic naphtha is derived from Fischer-Tropsch synthesis.

    摘要翻译: 本发明涉及用于改进合成石脑油流的辛烷值并任选地用于生产烯烃和/或溶剂的方法。 在一个实施方案中,该方法包括将至少一部分合成石脑油流芳构化以产生芳族烃流; 并使至少一部分芳构化烃物流异构化以产生具有比合成石脑油流更高辛烷值的异构化芳构化烃物流。 或者,该方法包括提供包含C4-C5流的至少三个合成石脑油切割; C6-C8流和C9-C11流; 使一些C 6 -C 8流芳构化以形成具有较高辛烷值的芳构化烃流; 蒸汽裂解一些C6-C8流和任选的C9-C11流以形成烯烃; 并将C9-C11流的一些部分作为溶剂出售。 在优选的实施方案中,合成石脑油衍生自费 - 托合成。

    Octane improvement of a hydrocarbon stream
    2.
    发明授权
    Octane improvement of a hydrocarbon stream 有权
    辛烷值改善烃流

    公开(公告)号:US07541504B2

    公开(公告)日:2009-06-02

    申请号:US11050188

    申请日:2005-02-03

    IPC分类号: C07C15/00 C07C4/04

    CPC分类号: C10G59/00

    摘要: The invention relates to methods for improving the octane number of a synthetic naphtha stream and optionally for producing olefins and/or solvents. In one embodiment, the method comprises aromatizing at least a portion of a synthetic naphtha stream to produce an aromatized hydrocarbon stream; and isomerizing at least a portion of the aromatized hydrocarbon stream to produce an isomerized aromatized hydrocarbon stream having a higher octane rating than the synthetic naphtha stream. Alternatively, the method comprises providing at least three synthetic naphtha cuts comprising a C4-C5 stream; a C6-C8 stream and a C9-C11 stream; aromatizing some of the C6-C8 stream to form an aromatized hydrocarbon stream with a higher octane number; steam cracking some of the C6-C8 stream and optionally the C9-C11 stream to form olefins; and selling some portions of C9-C11 stream as solvents. In preferred embodiments, the synthetic naphtha is derived from Fischer-Tropsch synthesis.

    摘要翻译: 本发明涉及用于改进合成石脑油流的辛烷值并任选地用于生产烯烃和/或溶剂的方法。 在一个实施方案中,该方法包括将至少一部分合成石脑油流芳构化以产生芳族烃流; 并使至少一部分芳构化烃物流异构化以产生具有比合成石脑油流更高辛烷值的异构化芳构化烃物流。 或者,该方法包括提供包含C4-C5流的至少三个合成石脑油切割; C6-C8流和C9-C11流; 使一些C 6 -C 8流芳构化以形成具有较高辛烷值的芳构化烃流; 蒸汽裂解一些C6-C8流和任选的C9-C11流以形成烯烃; 并将C9-C11流的一些部分作为溶剂出售。 在优选的实施方案中,合成石脑油衍生自费 - 托合成。

    Process for converting alkanes to carbon filaments
    3.
    发明授权
    Process for converting alkanes to carbon filaments 有权
    将烷烃转化为碳丝的方法

    公开(公告)号:US07078008B2

    公开(公告)日:2006-07-18

    申请号:US10263315

    申请日:2002-10-01

    IPC分类号: D01F9/127

    CPC分类号: B82Y30/00 D01F9/1271

    摘要: The present invention includes a process for producing carbon filaments and synthesis gas from a mixture of alkanes, preferably natural gas, comprising converting a first portion of the alkanes, preferably C2+ hydrocarbons, directly to carbon filaments and converting a second portion of the alkanes, preferably methane, to syngas. The natural gas may be separated into a first feed stream comprising ethane, propane, and butane and a second feed stream comprising methane. The first feed stream is fed to a carbon filament CF reactor to produce carbon filaments and hydrogen. The second feed stream is fed to a syngas production reactor to produce syngas. Alternatively, the natural gas is fed to at least one carbon filament reactor that is maintained at an effective temperature to convert C2+ hydrocarbons in the natural gas to carbon filaments and hydrogen, thereby filtering methane from the natural gas.

    摘要翻译: 本发明包括从烷烃,优选天然气的混合物生产碳丝和合成气的方法,包括将第一部分烷烃,优选C 2 O 3, 碳氢化合物直接转化为碳丝并将第二部分烷烃,优选甲烷转化为合成气。 天然气可以分离成包含乙烷,丙烷和丁烷的第一进料流和包含甲烷的第二进料流。 将第一进料流送入碳丝CF反应器以产生碳丝和氢。 将第二进料流送入合成气生产反应器以产生合成气。 或者,将天然气进料至至少一个碳丝反应器,其保持在有效温度以将天然气中的C 2 O 2 CO 2烃转化为碳丝和氢 从而从天然气中过滤甲烷。

    Non-oxidative conversion of gas to liquids
    5.
    发明授权
    Non-oxidative conversion of gas to liquids 失效
    气体对液体的非氧化转化

    公开(公告)号:US07019184B2

    公开(公告)日:2006-03-28

    申请号:US10139502

    申请日:2002-05-06

    摘要: The present invention provides a process for natural gas in the form, e.g., of stranded gas or associated gas to transportable liquids. More particularly, the present invention provides a process in which the gas is non-oxidatively converted to aromatic liquid, preferably in proximity to the welihead, which may be onshore or offshore. In one aspect, the present invention provides integration of separation of wellhead fluids into associated gas and crude with blending of the aromatic liquid derived from the gas with the crude. Alternatively, or in combination, in another aspect, the present invention provides integration of conversion of byproduct hydrogen to power with non-oxidative conversion of gas to aromatic liquid.

    摘要翻译: 本发明提供了一种天然气的方法,其形式为例如绞合气体或与可输送液体相关联的气体。 更具体地说,本发明提供了一种方法,其中气体被非氧化转化成芳香族液体,优选靠近可能在陆上或近海的井头。 在一个方面,本发明提供了将来自气体的芳香族液体与原油共混的井口流体分离成相关气体和粗品的整合。 或者或组合地,在另一方面,本发明提供副产物氢转化为动力与气体与芳族液体的非氧化转化的整合。

    Reactor and process for converting alkanes to alkenes
    6.
    发明授权
    Reactor and process for converting alkanes to alkenes 有权
    将烷烃转化为烯烃的反应器和工艺

    公开(公告)号:US07074977B2

    公开(公告)日:2006-07-11

    申请号:US10731748

    申请日:2003-12-09

    IPC分类号: C07C5/333

    摘要: The invention relates to a reactor comprising two reaction zones and processes for the production of alkenes from alkanes. A first reaction zone includes a combustion catalyst, and a second reaction zone comprises a heating zone in thermal contact with the first reaction zone. One process comprises generating heat and an effluent by the combustion of a fuel with oxygen in the first reaction zone; passing an alkane feed through the heating zone of the second reaction zone such that the alkane feed absorbs a sufficient amount of the heat generated in the first reaction zone to initiate the conversion of alkanes to alkenes in the second reaction zone. In other embodiments, the effluent comprises oxygen, and the second reaction zone excludes a catalyst; alternatively, the effluent is substantially free of oxygen, and the second reaction zone comprises a supplemental oxygen feed and may or may not include a catalyst.

    摘要翻译: 本发明涉及一种包含两个反应区的反应器和用于从烷烃生产烯烃的方法。 第一反应区包括燃烧催化剂,第二反应区包括与第一反应区热接触的加热区。 一个方法包括通过在第一反应区中燃烧具有氧气的燃料产生热量和流出物; 使烷烃进料通过第二反应区的加热区,使得烷烃进料吸收足够量的在第一反应区中产生的热量以引发烷烃转化为第二反应区中的烯烃。 在其它实施方案中,流出物包含氧,第二反应区排除催化剂; 或者,流出物基本上不含氧,并且第二反应区包含补充的氧气进料,并且可以包括或可以不包括催化剂。

    Method for treating alkanes
    7.
    发明授权
    Method for treating alkanes 失效
    烷烃处理方法

    公开(公告)号:US07057081B2

    公开(公告)日:2006-06-06

    申请号:US10436684

    申请日:2003-05-09

    IPC分类号: C07C29/74

    CPC分类号: C07C29/06 C07C31/10 C07C31/08

    摘要: Methods are disclosed for converting propane and higher alkanes to their corresponding alcohols through a multi-step process with olefin as an intermediate. Methods are also disclosed for facilitating the transportation, purification or other treatment of propylene and higher olefins using a chemical conversion to the corresponding alcohol and reconversion to olefin. Methods are also disclosed for converting propane and higher alkanes to olefins using the corresponding alcohol as a temporary intermediate to minimize purification, transportation and/or other treatment costs.

    摘要翻译: 公开了通过多步法将丙烷和高级烷烃转化成其相应的醇的方法,其中烯烃作为中间体。 还公开了促进丙烯和高级烯烃的运输,纯化或其它处理的方法,其中使用化学转化成相应的醇并重新转化成烯烃。 还公开了使用相应的醇作为临时中间体将丙烷和高级烷烃转化为烯烃的方法,以最小化纯化,运输和/或其他处理成本。

    Recover and recycle rhodium from spent partial oxidation catalysts
    10.
    发明授权
    Recover and recycle rhodium from spent partial oxidation catalysts 失效
    从废部分氧化催化剂回收和回收铑

    公开(公告)号:US06923922B2

    公开(公告)日:2005-08-02

    申请号:US10828598

    申请日:2004-04-21

    摘要: A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600° C. to 800° C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.

    摘要翻译: 从废负载型催化剂中回收铑的方法。 在一个实施方案中,用于从主体材料回收铑的方法包括在足以将至少一部分铑转化为Rh 2 O 3 N / N的温度下在空气中焙烧主体材料 >,将主体材料浸入具有与Rh 2 O 3 3反应的浸出成分的溶液中以形成第一中间物质,使第一中间物质溶于 与酸化组分或络合剂形成第二中间体物质,并纯化第二中间物质。 优选地,焙烧温度为约600℃至800℃,持续0.5至10小时。 在一些实施方案中,将主体材料研磨至0.1至10mm范围内的颗粒。