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公开(公告)号：US5391592A
公开(公告)日：1995-02-21
申请号：US101221
申请日：1993-08-03
CPC分类号： G02B1/043 , C08B37/0012 , C08G77/42
摘要： A process for producing a contact lens and a contact lens comprising a crosslinked lipophilised cyclodextrin derivative, wherein each repeating cyclodextrin unit includes at least one polysiloxane group. The process for producing the contact lens includes the reaction of a cyclodextrin with a polysiloxane.
摘要翻译： 一种生产隐形眼镜和隐形眼镜的方法，所述隐形眼镜包含交联的亲脂化环糊精衍生物，其中每个重复环糊精单元包括至少一个聚硅氧烷基团。 隐形眼镜的制造方法包括环糊精与聚硅氧烷的反应。
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公开(公告)号：US5362767A
公开(公告)日：1994-11-08
申请号：US961105
申请日：1992-10-14
申请人： Peter Herbrechtsmeier , Horst Schafer , Bernhard Seiferling , Arnulf-Dieter Schluter , Harald Bothe , Rainer Freudenberger
发明人： Peter Herbrechtsmeier , Horst Schafer , Bernhard Seiferling , Arnulf-Dieter Schluter , Harald Bothe , Rainer Freudenberger
摘要： The invention relates to contact lenses made from a copolymer comprising units of formula I ##STR1## wherein R.sup.1 and R.sup.2 are each independently of the other hydrogen, alkyl, alkoxyalkyl, organosilylalkyl or organosilyl, R.sup.3 and R.sup.4 are each hydrogen or, taken together, are a divalent alkylene radical containing up to 8 carbon atoms, and A is a divalent substituted 1,2-ethylene radical which is derived from a copolymerisable vinyl monomer by virtue of the vinyl double bond being replaced with a single bond. The invention further relates to the copolymers themselves, to the use thereof for making contact lenses, and to a process for making contact lenses from such copolymers.
摘要翻译： 本发明涉及由包含式I（I）单元的共聚物制成的隐形眼镜，其中R 1和R 2各自独立地为氢，烷基，烷氧基烷基，有机甲硅烷基烷基或有机甲硅烷基，R 3和R 4各自为氢或被取代 一起是含有至多8个碳原子的二价亚烷基，A是由可共聚的乙烯基单体衍生的二价取代的1,2-亚乙基，因为乙烯基双键被单键取代。 本发明还涉及共聚物本身，其用于制造隐形眼镜的用途以及由这种共聚物制造隐形眼镜的方法。
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公开(公告)号：US5264878A
公开(公告)日：1993-11-23
申请号：US6085
申请日：1993-01-19
IPC分类号： C08F220/22 , C08F230/08 , C08F290/06 , G02B1/04 , G02C7/04
CPC分类号： G02B1/043 , C08F220/22 , C08F230/08 , C08F290/068
摘要： The present invention relates to novel polymers, to processes for the preparation thereof, to contact lenses consisting substantially of those polymers and to processes for the manufacture thereof and to the use of the novel polymers for the manufacture of contact lenses. The polymers according to the invention are especially the copolymerisation products of monomer mixtures comprising the following monomers:______________________________________ a) 20-60% siloxane monovinyl component b) 1-25% siloxane oligovinyl component c) 10-55% fluorine-containing vinyl component d) 3-30% hydrophobic vinyl component having a bulky hydrocarbon radical, e) 0-10% hydrophilic vinyl component f) 0-15% additional cross-linking vinyl component. ______________________________________ The novel polymers and the contact lenses made therefrom are distinguished by a high degree of hardness while at the same time being highly permeable to oxygen.
摘要翻译： 本发明涉及新型聚合物，其制备方法，基本上由这些聚合物组成的隐形眼镜及其制造方法以及用于制造隐形眼镜的新型聚合物的用途。 根据本发明的聚合物特别是包含以下单体的单体混合物的共聚产物：-a）20-60％硅氧烷单乙烯基组分-b）1-25％硅氧烷低聚乙烯基组分-c）10-55％含氟乙烯基 组分-d）具有大体积烃基的3-30％疏水性乙烯基组分，-e）0-10％亲水性乙烯基组分-f）0-15％额外的交联乙烯基组分。 - 由其制成的新型聚合物和隐形眼镜的特征在于高度的硬度，同时对氧具有高度可渗透性。
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公开(公告)号：US5194556A
公开(公告)日：1993-03-16
申请号：US638949
申请日：1991-01-09
IPC分类号： C08F299/08 , C08F290/00 , C08F290/06 , C08F290/14 , G02B1/04 , G02C7/04
CPC分类号： C08F290/148 , C08F290/068 , G02B1/043
摘要： Hard polymers with extremely high oxygen permeability are described, which consist of the copolymerization product of 1-15% by weight of a poly(dimethylsiloxane) bearing multiple polymerizable vinyl groups and having a number-average molecular weight M.sub.n of 1000-7000, 20-50% of an oligosiloxanylalkyl (meth)acrylate, 25-50% of an at least three fluorine atoms containing vinyl-monomer, 0-30% of copolymerizable monomers, which by themselves as homo- or copolymers have a Shore-D hardness of at least 85, 1-25% of polyvinyl-crosslinking monomer of 200-1000 molecular weight, and 0-15% of a watersoluble, copolymerizable monomer. The novel polymers combine a Shore-D hardness of 70-85 with an oxygen permeability of 40-90 barrers, making them outstanding materials for the manufacture and use as rigid, gas-permeable contact lenses.
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公开(公告)号：US08092724B2
公开(公告)日：2012-01-10
申请号：US12834979
申请日：2010-07-13
摘要： The instant invention pertains to a method and a fluid composition for producing contact lenses with improved lens quality and with increased product yield. The method of the invention involves adding a phospholipid into a fluid composition including a lens-forming material in an amount sufficient to reduce an averaged mold separation force by at least about 40% in comparison with that without the phospholipids.
摘要翻译： 本发明涉及一种用于制造具有改善的镜片质量和增加的产品产量的隐形眼镜的方法和流体组合物。 本发明的方法包括将磷脂添加到包含透镜形成材料的流体组合物中，其量足以将平均的模具分离力与没有磷脂的模具分离力相比降低至少约40％。
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公开(公告)号：US20090160074A1
公开(公告)日：2009-06-25
申请号：US12316993
申请日：2008-12-18
摘要： The instant invention pertains to a method and a fluid composition for producing contact lenses with improved lens quality and with increased product yield. The method of the invention involves adding a phospholipid into a fluid composition including a lens-forming material in an amount sufficient to reduce an averaged mold separation force by at least about 40% in comparison with that without the phospholipids.
摘要翻译： 本发明涉及一种用于制造具有改善的镜片质量和增加的产品产量的隐形眼镜的方法和流体组合物。 本发明的方法包括将磷脂添加到包含透镜形成材料的流体组合物中，其量足以将平均的模具分离力与没有磷脂的模具分离力相比降低至少约40％。
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公开(公告)号：US20080152800A1
公开(公告)日：2008-06-26
申请号：US12004002
申请日：2007-12-19
摘要： The invention relates to a process for the manufacture of a hydrophilic coating on a biomedical article, which comprises treating the biomedical article for a time period of ≦5 minutes with a solution of an organic solvent comprising a polyanionic compound with a number average molecular weight Mn of >5000, wherein the solution comprises less than 10% by weight of water, and wherein the solution is devoid of a cationic polymer. The coated biomedical articles obtainable by the process of the invention have desirable characteristics regarding adherence to the substrate, durability, hydrophilicity, wettability, biocompatibility and permeability and are thus especially useful in the field of ophthalmic devices.
摘要翻译： 本发明涉及在生物医学制品上制造亲水性涂层的方法，该方法包括用含有数均分子量的聚阴离子化合物的有机溶剂溶液处理生物医药制品<= 5分钟的时间 其中溶液包含小于10重量％的水，并且其中该溶液没有阳离子聚合物。 通过本发明的方法可获得的涂覆的生物医学制品具有关于对基底的粘附，耐久性，亲水性，润湿性，生物相容性和渗透性的期望特性，因此在眼科装置领域中特别有用。
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公开(公告)号：US5871675A
公开(公告)日：1999-02-16
申请号：US875532
申请日：1997-09-18
IPC分类号： G02B7/04 , B29D11/00 , C08F8/00 , C08F16/06 , C08F226/06 , C08J3/24 , G02B1/04 , G02B1/10 , G02B1/12 , C07C43/00 , C08F224/00 , C08G63/91
CPC分类号： G02B1/043 , C08F8/00 , C08F8/12 , C08F8/30 , C08F226/10 , C08F2800/20 , C08F2810/20 , C08F2810/30 , C08F2810/50
摘要： The invention relates to a novel process for the production of tinted mouldings, in particular tinted contact lenses, in which a crosslinkable tinted polymer comprising units containing a crosslinkable group and units containing a reactive dye radical is crosslinked in solution, and to tinted mouldings, in particular tinted contact lenses, obtainable by this process. The present invention likewise relates to novel crosslinkable tinted polymers comprising units containing a crosslinkable group and units containing a reactive dye radical which can be employed in the novel process, in particular derivatives of a polyvinyl alcohol having a molecular weight of at least about 2000, to crosslinked tinted polymers, either homopolymers or copolymers, made from these novel crosslinkable tinted polymers containing a reactive dye radical, a process for the preparation of the novel crosslinkable tinted polymers comprising units containing a crosslinkable group and units containing a reactive dye radical and the homopolymers and copolymers obtainable therefrom, to tinted mouldings made from said homopolymers or copolymers, in particular tinted contact lenses made from these homopolymers or copolymers, and to a process for the production of tinted contact lenses using said homopolymers or copolymers.
摘要翻译： PCT No.PCT / EP96 / 00252 Sec。 371日期：1997年9月18日 102（e）1997年9月18日PCT PCT 1996年1月23日PCT公布。 公开号WO96 / 24076 日期1996年8月8日本发明涉及一种生产有色成型品，特别是着色隐形眼镜的新方法，其中包含含有可交联基团的单元的交联着色聚合物和含有活性染料基团的单元在溶液中交联， 用于通过该方法获得的有色成型品，特别是有色隐形眼镜。 本发明同样涉及包含可交联基团的单元的新型交联着色聚合物和可用于新方法的反应性染料基团的单元，特别是分子量至少为约2000的聚乙烯醇的衍生物，至 交联着色聚合物，均聚物或共聚物，由含有活性染料基团的这些新型可交联着色聚合物制成，制备包含可交联基团的单元的新交联着色聚合物的方法和含有活性染料基团的单元和均聚物和 可从其获得的共聚物到由所述均聚物或共聚物制成的着色模制品，特别是由这些均聚物或共聚物制成的着色隐形眼镜，以及使用所述均聚物或共聚物生产着色隐形眼镜的方法。
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公开(公告)号：US5198477A
公开(公告)日：1993-03-30
申请号：US841920
申请日：1992-02-25
CPC分类号： G02B1/043
摘要： The invention relates to contact lenses made from a polymer comprising macrocycles that are made up of units of formula I--(--CR.sup.1 .dbd.CR.sup.2 --A--)-- (I)wherein A is alkylene or alkenylene each having from 3 to 10 carbon atoms and each of which may be substituted by one or more R.sup.3 radicals, each of R.sup.1 and R.sup.2, independently of the other, is hydrogen or lower alkyl, and R.sup.3 is lower alkyl, fluorinated lower alkyl or a siloxane radical.They exhibit a combination of a high degree of hardness and oxygen permeability. They can be produced in an especially advantageous manner, that is to say by hot compression moulding.
摘要翻译： 本发明涉及由包含大环的聚合物制成的隐形眼镜，其由式I - （ - CR1 = CR2-A - ） - （I）单元组成，其中A为具有3至10个碳原子的亚烷基或亚烯基， 其各自可被一个或多个R 3基团取代，R 1和R 2各自独立地为氢或低级烷基，R 3为低级烷基，氟化低级烷基或硅氧烷基。 它们表现出高硬度和透氧性的组合。 它们可以以特别有利的方式制造，也就是说通过热压缩成型。
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公开(公告)号：US08158192B2
公开(公告)日：2012-04-17
申请号：US12004002
申请日：2007-12-19
摘要： The invention relates to a process for the manufacture of a hydrophilic coating on a biomedical article, which comprises treating the biomedical article for a time period of ≦5 minutes with a solution of an organic solvent comprising a polyanionic compound with a number average molecular weight Mn of >5000, wherein the solution comprises less than 10% by weight of water, and wherein the solution is devoid of a cationic polymer.The coated biomedical articles obtainable by the process of the invention have desirable characteristics regarding adherence to the substrate, durability, hydrophilicity, wettability, biocompatibility and permeability and are thus especially useful in the field of ophthalmic devices.
摘要翻译： 本发明涉及一种在生物医学制品上制造亲水涂层的方法，其包括用含有数均分子量的聚阴离子化合物的有机溶剂溶液处理生物医学制品一段时间; Mn> 5000，其中所述溶液包含小于10重量％的水，并且其中所述溶液不含阳离子聚合物。 通过本发明的方法可获得的涂覆的生物医学制品具有关于对基底的粘附，耐久性，亲水性，润湿性，生物相容性和渗透性的期望特性，因此在眼科装置领域中特别有用。
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