公开(公告)号：US4444900A

公开(公告)日：1984-04-24

申请号：US375076

申请日：1982-05-05

Applicant: Clarence D. Chang ,  Joseph N. Miale

Inventor： Clarence D. Chang ,  Joseph N. Miale

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/28

CPC classification number: B01J29/06 ,  B01J29/703 ,  B01J2229/18 ,  B01J2229/37 ,  B01J29/40 ,  B01J29/65

Abstract: A method for enhancing the activity of a synthetic crystalline zeolite, including a zeolite having a silica-to-alumina mole ratio greater than 100, which has been synthesized from a reaction mixture containing a diamine as a cation source, is disclosed which involves reacting the zeolite with a dilute aqueous solution of hydrogen fluoride, contacting the hydrogen fluoride reacted zeolite with aluminum chloride, treating the aluminum chloride contacted zeolite by contact with an ammonium salt solution or ammonolysis and calcining the final product.

Abstract translation: 公开了一种用于增强合成结晶沸石活性的方法，该方法包括从含有二胺作为阳离子源的反应混合物合成的二氧化硅与氧化铝的摩尔比大于100的沸石，其包括使 沸石与氟化氢的稀释水溶液接触，使氟化氢反应的沸石与氯化铝接触，通过与铵盐溶液接触或氨解处理氯化铝接触的沸石并煅烧最终产物。

公开(公告)号：US4214107A

公开(公告)日：1980-07-22

申请号：US919194

申请日：1978-06-26

Applicant: Clarence D. Chang ,  Norman J. Morgan

Inventor： Clarence D. Chang ,  Norman J. Morgan

IPC: C07C29/04

CPC classification number: C07C29/04

Abstract: A process for directly hydrating linear olefins having up to 4 carbon atoms to form alcohols, catalyzed by a novel class of highly siliceous zeolites exemplified by HZSM-5.

Abstract translation: 直接水合具有多至4个碳原子的直链烯烃以形成醇的方法，由HZSM-5举例说明的一类新型高硅酸盐沸石催化。

公开(公告)号：US4193864A

公开(公告)日：1980-03-18

申请号：US912126

申请日：1978-06-02

Applicant: Clarence D. Chang

Inventor： Clarence D. Chang

IPC: C10G45/28 ,  C10G65/00 ,  C10G23/02

CPC classification number: C10G45/28 ,  C10G2300/107

Abstract: A process is provided for the desulfurization of residual oil by(a) separating the residual oil into a first and a second fraction;(b) reacting the first fraction with hydrogen over a hydrodesulfurization catalyst in a first reaction zone at hydrodesulfurization conditions such that a liquid effluent of lower sulfur content than the residual oil is obtained;(c) combining the hydrodesulfurization liquid effluent with the second residual oil fraction; and(d) reacting the resultant mixture over a hydrogenation/dehydrogenation catalyst in a second reaction zone at hydrogen transfer conditions.This process provides for desulfurization of residual oils at lower hydrogen consumptions than conventional processes.

Abstract translation: 提供了通过（a）将残油分离成第一和第二馏分来对残油进行脱硫的方法; （b）在加氢脱硫条件下使第一级分与氢气在第一反应区中在加氢脱硫催化剂上反应，使得获得的硫含量低于残油的液体流出物; （c）将加氢脱硫液体流出物与第二残余油馏分组合; 和（d）在氢转移条件下在第二反应区中使所得混合物在氢化/脱氢催化剂上反应。 该方法提供了比常规方法更低氢消耗的残油的脱硫。

公开(公告)号：US4138442A

公开(公告)日：1979-02-06

申请号：US856966

申请日：1977-12-02

Applicant: Clarence D. Chang ,  Anthony J. Silvestri

Inventor： Clarence D. Chang ,  Anthony J. Silvestri

IPC: B01J29/40 ,  C07C29/151 ,  C07C41/06 ,  C07C43/04

CPC classification number: B01J29/40 ,  C10G1/002 ,  C10G2/30 ,  C10K3/04 ,  B01J2229/36 ,  C10G2300/1022 ,  C10G2400/02 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/1659 ,  C10J2300/1807 ,  Y02E50/32 ,  Y02P20/52 ,  Y10S208/95

Abstract: Synthesis gas comprising a mixture of carbon monoxide and hydrogen is derived from fossil fuels and catalytically converted in a first reaction zone to a mixture of methanol and dimethyl ether which in turn is converted in a separate reaction zone in contact with a crystalline aluminosilicate zeolite catalyst having a silica to alumina ratio of at least about 12 and a constraint index of about 1 to 12, and preferably a crystal density in the hydrogen form of not substantially below about 1.6 grams per cubic centimeter to a product which is resolved into a high octane gasoline fraction, a light hydrocarbon gas fraction which may be liquefied and a hydrogen-rich gaseous by-product which is recycled to the conversion of fossil fuels to synthesis gas or may be otherwise used.

公开(公告)号：US4096163A

公开(公告)日：1978-06-20

申请号：US730871

申请日：1976-10-08

Applicant: Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri ,  Robert L. Smith

Inventor： Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri ,  Robert L. Smith

IPC: B01J29/40 ,  B01J29/46 ,  B01J29/65 ,  B01J29/70 ,  C07C1/04

CPC classification number: B01J29/405 ,  B01J29/46 ,  C07C1/043 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2523/26 ,  C07C2523/72 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/52 ,  Y10S585/943

Abstract: Synthesis gas is contacted with an intimate mixture of a carbon monoxide hydrogen reduction catalyst, comprising a methanol synthesis catalyst in combination with a selective class of acidic crystalline aluminosilicate having a silica/alumina ratio greater than 12, a pore dimension greater than about 5 Angstroms to produce hydrocarbon mixtures useful in the manufacture of heating fuels, gasoline, aromatic hydrocarbons, and chemicals intermediates.

Abstract translation: 合成气与一氧化碳氢还原催化剂的紧密混合物接触，所述催化剂包括甲醇合成催化剂与二氧化硅/氧化铝比大于12的选择性酸性结晶硅铝酸盐，大于约5埃的孔尺寸， 生产用于制造加热燃料，汽油，芳烃和化学品中间体的烃混合物。

公开(公告)号：US4062905A

公开(公告)日：1977-12-13

申请号：US747581

申请日：1976-12-06

Applicant: Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri

Inventor： Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri

IPC: C07C1/20

CPC classification number: C07C1/20 ,  C07C2529/50 ,  C07C2529/70 ,  Y02P30/42

Abstract: A catalytic process is provided for converting a charge consisting essentially of methanol, dimethyl ether or mixtures thereof to a hydrocarbon product rich in ethylene and propylene by contact, under conversion conditions, with a catalyst comprising a crystalline aluminosilicate zeolite characterized by pores, the major dimension of which is less than 6 Angstroms and the capability, under said conditions, of producing less than 20 weight percent methane in said hydrocarbon product.

Abstract translation: 提供了一种催化方法，用于在转化条件下，将基本上由甲醇，二甲醚或其混合物组成的电荷转化成富含乙烯和丙烯的烃产物，其中催化剂包含以孔为特征的结晶硅铝酸盐沸石，其主要尺寸 其中小于6埃，并且在所述条件下能够在所述烃产物中产生小于20重量％的甲烷的能力。

公开(公告)号：US4025576A

公开(公告)日：1977-05-24

申请号：US593139

申请日：1975-07-03

Applicant: Clarence D. Chang ,  William H. Lang

Inventor： Clarence D. Chang ,  William H. Lang

IPC: C10L1/00 ,  B01J29/00 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C11/02 ,  C07C67/00 ,  C10L1/06

CPC classification number: C10L1/06 ,  B01J29/18 ,  B01J29/40 ,  C07C1/20 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2521/08 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P30/42 ,  Y10S208/95 ,  Y10S585/906

Abstract: A lower alcohol and/or ether feed is selectively converted to a mixture of light olefins, including ethylene and propylene, by catalytic contact of the feed, for example methanol or dimethyl ether, at subatmospheric partial pressure, with certain crystalline aluminosilicate zeolite catalysts exemplified by HZSM-5. Low durene-content gasoline or gasoline blending stock are made from methanol or dimethyl ether by this process.

Abstract translation: 低级醇和/或醚进料选择性地转化为轻质烯烃（包括乙烯和丙烯）的混合物，通过在低于大气压的压力下将进料例如甲醇或二甲醚与某些结晶硅铝酸盐沸石催化剂催化接触， HZSM-5。 这种方法由甲醇或二甲醚制成低含杜烯含量汽油或汽油混合料。

公开(公告)号：US3998898A

公开(公告)日：1976-12-21

申请号：US592434

申请日：1975-07-02

Applicant: Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri

Inventor： Clarence D. Chang ,  William H. Lang ,  Anthony J. Silvestri

IPC: B01J29/18 ,  B01J29/40 ,  C07C29/154 ,  C10G3/00 ,  C07C1/20

CPC classification number: C07C29/154 ,  B01J29/18 ,  B01J29/40 ,  C10G3/49 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/42 ,  C07C2529/44 ,  C07C2529/46 ,  C07C2529/65 ,  C07C2529/70 ,  C10G2300/4006 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/30 ,  Y02P30/20

Abstract: Reacting mixtures of difficultly convertible aliphatic organic oxygenate compounds, such as short chain aldehydes, carboxylic acids or carbohydrates with easily convertible aliphatic alcohols, ethers, acetals and analogs thereof over a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index of about 1 to 12, at elevated temperatures, 0.5 to 50 LHSV and 1 to 200 atmospheres to produce a product comprising water, full range highly aromatic hydrocarbon gasoline and light aliphatic hydrocarbon gases having an improved production of C.sub.6 and C.sub.10 monocyclic aromatic hydrocarbons.

公开(公告)号：US06541408B2

公开(公告)日：2003-04-01

申请号：US10041215

申请日：2001-10-29

Applicant: Clarence D. Chang ,  Paul G. Rodewald, Jr.

Inventor： Clarence D. Chang ,  Paul G. Rodewald, Jr.

IPC: B01J2906

CPC classification number: B01J29/061 ,  B01J2229/12 ,  B01J2229/32 ,  C07C6/123 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/46 ,  C07C2529/65 ,  C07C2529/67 ,  C07C2529/68 ,  C07C2529/70 ,  C07C2529/72 ,  C07C2529/74 ,  Y02P20/52 ,  C07C15/08

Abstract: A zeolite catalyst suitable for use in shape-selective hydrocarbon conversion processes. The catalyst is modified by incorporation therein of a hydrogenation-dehydrogenation functional metal, followed by gradient selectivation with an organosilicon compound under conversion conditions, wherein the gradient selectivation conditions are characterized by a progressive temperature gradient. The use of a progressive temperature gradient during the in situ selectivation procedure unexpectedly yields a catalyst in which the hydrogenation-dehydrogenation function is stabilized, thereby enabling long duration hydrocarbon conversion processes with low by-product make.

公开(公告)号：US06290755B1

公开(公告)日：2001-09-18

申请号：US09563693

申请日：2000-05-03

Applicant: Clarence D. Chang ,  Suzanne Elaine Schramm ,  Clarence Edward Chase

Inventor： Clarence D. Chang ,  Suzanne Elaine Schramm ,  Clarence Edward Chase

IPC: B01D5314

CPC classification number: B01D53/1493 ,  B01D53/1487 ,  Y02C10/06

Abstract: The present invention provides a bisglycoluril derivative composition useful for selectively covering methane from a gas stream including carbon dioxide.

Abstract translation: 本发明提供了可用于从包括二氧化碳的气流中选择性地覆盖甲烷的双甘脲尿素衍生物组合物。