摘要:
A method of foaming thermoplastic aromatic polycarbonates is disclosed. Accordingly, a polycarbonate resin is mixed with 0.01 to 10%, the percent being relative to the total weight of polycarbonate resin and polysaccharide, of a particular polysaccharide and the mixture then processed thermoplastically without the application of negative pressure in an extruder, at temperatures of 180.degree. C. to 320.degree. C., or in an injection molding machine, at temperatures of 190.degree. C. to 330.degree. C., to obtain foamed molded articles.
摘要:
A process for the production of polycarbonate foam moldings is disclosed. Accordingly, a composition is prepared comprising mixing a thermoplastic polycarbonate resin and 0.01 to 1 mole-% of a transesterification catalyst anda) 0.1 to 5 mole-% of an aromatic polycarboxylic acid, optionally along with about 0.1 to 5 mole-% of at least one member selected from the group consisting of aliphatic hydroxy carboxylic acids and aliphatic polyalcohols, orb) 0.1 to 5 mole-% of H.sub.2 O, optionally along with at about 0.1 to 5 mole-% of at least one member selected from the group consisting of aliphatic hydroxycarboxylic acids and an aliphatic alcohols, orc) the additives of said a) and b), ord) 0.1 to 5 mole-% of at least one member selected from the group consisting of diarylcarbonates and oligocarbonates,said percent based in every case on moles aromatic carbonate structural units ##STR1## in which --O--R--O is a diphenolate residue. The composition obtained is processed to foam moldings by injection molding or by extrusion at temperatures of 210.degree. C. to 340.degree. C.
摘要:
A recipient for a gas ultracentrifuge which comprises an oblong cylindrical shell having a lid closing each end, a base flange having an upper end surrounding one end of the shell and a plastically deformable ring interposed between the base flange and the shell. In an embodiment of the invention, the plastically deformable ring comprises a ring-shaped section and a welding shoulder which forms a ring-shaped collar integral with the base flange, the thickness of the shell being greater than that of the ring-shaped collar and about the same thickness as that of the welding shoulder.
摘要:
A process for the production of optical fibers based on aromatic polycarbonates wherein the polycarbonate fibres are coated with a plastic, the improvement which comprises(a) to coat the fiber with an UV irradiation-polymerizable mixture which comprises(A) 25 to 75% by weight, based on the total weight of the polymerizable compounds, of a polyfunctional (meth)acrylic acid derivative of the formula ##STR1## (B) 75 to 25% by weight, based on the total weight of the polymerizable compounds, of a monofunctional (meth)acrylate of the formula ##STR2## (C) 0.1 to 10% by weight, based on the total weight of the polymerizable compounds, of a photoinitiator, and(b) to polymerize this mixture on the fibre by UV irradiation.
摘要:
Linear polycarbonate resin virtually free of surface defects that impair the suitability of the resin for demanding optical application is disclosed. Also disclosed is a process for the manufacture of the resin. The surface defects included in the resin are in the form of transparent fluorescing particles, the particle count of which portion that are 15 and 250 μm in size, is up to 1.8 counts/g, said count being determined by exciting the residue remaining after filtering a solution of said polycarbonate in methylene chloride through a Teflon filter of 5 μm pore size at a wavelength of 400-440 nm, 25× overall magnification and illumination time of 40 millisec. The polycarbonate is suitable for making films of improved optical properties.
摘要:
A process for treating the working surfaces of equipment used in the production and processing of polycarbonate is disclosed. The thermal treatment in an oxidative atmosphere results in resin and molded articles having improved optical quality.
摘要:
Continuous processes for preparing polycarbonates having a weight average molecular weight Mw, of 15,000 to 200,000 g/mol, the processes comprising reacting a dihydroxydiarylalkane and phosgene in the presence of a catalyst in a phase boundary process comprising: continuously dispersing in a disperser an organic phase comprising at least a portion of the phosgene and a solvent suitable for the polycarbonate and an aqueous phase comprising the dihydroxydiarylalkane, water and an alkali solution present in an amount of 1.5 to 2.5 moles per mole of the dihydroxydiarylalkane, to form a mixture; reacting the mixture in a first reactor with a residence time of less than 0.5 seconds; further reacting the mixture in a second reactor with addition of further alkali solution and, optionally, a chain terminator; and effecting further condensation in a third reactor with addition of further alkali solution and, optionally, a chain terminator, in the presence of the catalyst.
摘要:
The present invention relates to polycarbonate, polyester carbonate and polyester having end groups derived from alkylsiloxane-substituted phenols, as well as to the use of phenolic compounds having alkylsiloxane substituents as chain terminators in the preparation of polycarbonate, polyester carbonate and polyester, as well as to mouldings and extrudates produced from these polymers, to processes for the preparation of the polymers, and to novel phenolic compounds of formula (2).
摘要:
A process for purifying polycarbonate is disclosed. The process entails filtering molten polycarbonate having weight average molecular weight of 14,000 to 30,000 g/mol through at least one non-woven metal structure having a thickness of 5 to 1 mm, said structure including at least one dense layer, and at least one less dense layer wherein said dense layer is 0.05 to 0.2 mm thick and has pore size of 1 to 10 μm to obtain pure polycarbonate.