公开(公告)号：US20050038142A1

公开(公告)日：2005-02-17

申请号：US10888563

申请日：2004-07-09

Applicant: James Butler ,  Kevin Kelly ,  Paul Buras

Inventor： James Butler ,  Kevin Kelly ,  Paul Buras

IPC: C08L95/00 ,  C08J3/00

CPC classification number: C08L95/00 ,  C08L2666/02 ,  C08L25/00 ,  C08L33/00 ,  C08L2666/04 ,  C08L53/00 ,  C08L2666/08

Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents include compositions of mercaptobenzothiazole, zinc oxide and elemental sulfur; compositions of mercaptobenzothiazole, zinc oxide, and mixed polythiomorpholine; and compositions of zinc 2-mercaptobenzothiazole and dithiodimorpholine.

Abstract translation: 本发明提供一种制备沥青和热塑性弹性体组合物的方法。 该方法包括将在搅拌槽中切割的沥青加热到足以允许在罐中搅拌沥青的温度。 在沥青中继续搅拌沥青时，加入热塑性弹性体或橡胶。 将混合物以足以增加弹性体分配到沥青中的速度搅拌一段时间。 搅拌速度降低，温度升高，向罐中加入交联剂。 搅拌持续一段时间，足以改善沥青中交联剂分散体的分布。 交联剂包括巯基苯并噻唑，氧化锌和元素硫的组合物; 巯基苯并噻唑，氧化锌和混合多硫代吗啉的组成; 和2-巯基苯并噻唑锌和二硫代二吗啉的组合物。

公开(公告)号：US20130231513A1

公开(公告)日：2013-09-05

申请号：US13867295

申请日：2013-04-22

Applicant: Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler ,  Joe Hunter ,  Taylor Rives

Inventor： Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/84

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

Abstract translation: 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

公开(公告)号：US08450546B2

公开(公告)日：2013-05-28

申请号：US12494138

申请日：2009-06-29

Applicant: Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler ,  Joe Hunter ,  Taylor Rives

Inventor： Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler ,  Joe Hunter ,  Taylor Rives

IPC: C07C2/66

CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

Abstract translation: 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

公开(公告)号：US08318999B2

公开(公告)日：2012-11-27

申请号：US12763234

申请日：2010-04-20

Applicant: Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler

Inventor： Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler

IPC: C07C1/24

CPC classification number: C07C2/862 ,  C07C2/864 ,  C07C2/867 ,  C07C2529/08 ,  C07C2529/60 ,  C07C15/46 ,  C07C15/073

Abstract: A process is disclosed for making styrene or ethylbenzene by reacting toluene with a C1 source that is selected from the group consisting of methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, and combinations thereof.

Abstract translation: 公开了通过使甲苯与选自甲醇，甲醛，福尔马林，三恶烷，甲基甲缩醛，多聚甲醛，甲缩醛及其组合的C1源反应制备苯乙烯或乙苯的方法。

公开(公告)号：US08283273B2

公开(公告)日：2012-10-09

申请号：US12751321

申请日：2010-03-31

Applicant: Kevin Kelly ,  James Butler

Inventor： Kevin Kelly ,  James Butler

IPC: B01J29/06

CPC classification number: C07C2/66 ,  B01J29/061 ,  B01J29/7057 ,  B01J37/0009 ,  B01J2229/42 ,  C07C15/073

Abstract: A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethylbenzene.

Abstract translation: 提供了包含金属/沸石的金属改性烷基化催化剂，其中金属是选自钇和除了铈之外的镧系稀土稀土的一种或两种。 在使用两种金属的情况下，可以使用Ce或La，金属促进的沸石可用作通过苯在液相或临界相中乙基化生产乙苯的分子筛芳烃烷基化催化剂。 生产含有乙苯作为主要产物的烷基化产物，伴随着生产不超过乙苯的10-60重量％的较重的烷基化副产物。

公开(公告)号：US08178738B2

公开(公告)日：2012-05-15

申请号：US12391063

申请日：2009-02-23

Applicant: James Butler

Inventor： James Butler

IPC: C07C5/333

CPC classification number: C07C5/3332 ,  B01J23/78 ,  C07C2523/745 ,  C07C15/46

Abstract: Methods and systems for extending the life of a dehydrogenation catalyst are described herein. For example, one embodiment includes providing an alkyl aromatic hydrocarbon feed stream to a reaction chamber, contacting the feed stream with a dehydrogenation catalyst to form a vinyl aromatic hydrocarbon, the dehydrogenation catalyst including iron oxide and an alkali metal catalysis promoter and supplying a catalyst life extender to at least one reaction chamber, the reaction chamber loaded with the dehydrogenation catalyst, wherein the catalyst life extender includes a potassium salt of a carboxylic acid.

Abstract translation: 本文描述了用于延长脱氢催化剂寿命的方法和系统。 例如，一个实施方案包括向反应室提供烷基芳族烃进料流，使进料流与脱氢催化剂接触以形成乙烯基芳族烃，脱氢催化剂包括氧化铁和碱金属催化促进剂并提供催化剂寿命 延伸至至少一个反应室，反应室装载有脱氢催化剂，其中催化剂生命延长剂包括羧酸的钾盐。

公开(公告)号：US20100331174A1

公开(公告)日：2010-12-30

申请号：US12494088

申请日：2009-06-29

Applicant: Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler

Inventor： Sivadinarayana Chinta ,  Joseph Thorman ,  James Butler

IPC: B01J23/10 ,  B01J23/02

CPC classification number: B01J23/04 ,  B01J23/002 ,  B01J23/10 ,  B01J23/36 ,  B01J2523/00 ,  C07C2/84 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/36 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/46 ,  C07C11/04 ,  C07C9/06 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/3706 ,  B01J2523/24 ,  B01J2523/12 ,  B01J2523/15 ,  B01J2523/74

Abstract: A catalyst includes: (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

Abstract translation: 催化剂包括：（A）选自镧系元素，Mg，Ca和元素周期表第4族元素中的至少一种元素（Ti，Zr和Hf）; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

公开(公告)号：US20070016665A1

公开(公告)日：2007-01-18

申请号：US11423480

申请日：2006-06-12

Applicant: James Butler

Inventor： James Butler

IPC: G06F15/173

CPC classification number: G06Q30/06

Abstract: A system for providing granular functionality called web services to commercial customers includes among other things a client to issue service requests and receive responses, a web server configured to accept and process service requests, and a means of accounting for usage. The current art specifies standards for functional interactions between web service clients and servers. A set of commercial extensions are defined herein to enable maintenance interactions. This “maintenance protocol” includes operations such as client software that is self-updating in response to server changes and the capability of reconciling client usage logs with service provider invoicing.

Abstract translation: 用于向商业客户提供称为Web服务的粒度功能的系统包括发布服务请求和接收响应的客户端，被配置为接受和处理服务请求的web服务器以及对使用进行计费的手段。 当前的艺术指定了Web服务客户机和服务器之间的功能交互的标准。 这里定义了一组商业扩展，以实现维护交互。 这种“维护协议”包括诸如响应于服务器改变而自我更新的客户端软件和将客户端使用日志与服务提供商开具发票协调的能力的操作。

公开(公告)号：US20060194994A1

公开(公告)日：2006-08-31

申请号：US11066951

申请日：2005-02-25

Applicant: James Butler ,  Kevin Kelly

Inventor： James Butler ,  Kevin Kelly

IPC: C07C2/68

CPC classification number: C07C2/66 ,  C07C6/126 ,  Y02P20/544 ,  C07C15/073

Abstract: A process for the production of ethylbenzene by the ethylation of benzene in the critical phase in a reaction zone containing a molecular sieve aromatic alkylation catalyst comprising cerium-promoted zeolite beta. A polyethylbenzene is supplied into the reaction zone and into contact with the cerium-promoted zeolite beta having a silica/alumina mole ratio within the range of 20-500. The reaction zone is operated at temperature and pressure conditions in which benzene is in the supercritical phase to cause ethylation of the benzene and the transalkylation of polyethylbenzene and benzene in the presence of the zeolite beta catalyst. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated byproducts of no more than 60 wt. % of the ethylbenzene. The alkylation reaction zone is operated under conditions providing a composite byproduct yield of propyl benzene and butyl benzene relative to ethylbenzene, which is no more than one half of the corresponding yield byproduct for zeolite beta promoted with lanthanum. The production of ethylbenzene in the critical phase alkylation reaction zone is attended by recycle of a polyalkylated aromatic component of the reaction product back to the reaction zone.

Abstract translation: 在包含铈促进沸石β的分子筛芳族烷基化催化剂的反应区中通过苯在临界阶段乙苯化生产乙苯的方法。 将聚乙苯供入反应区并与二氧化硅/氧化铝摩尔比在20-500范围内的铈促进沸石β接触。 反应区在苯处于超临界阶段的温度和压力条件下进行，以在沸石β催化剂存在下引起苯的乙基化和多乙基苯和苯的烷基转移。 生产含有乙苯作为主要产物的烷基化产物，伴随产生不超过60重量％的较重烷基化副产物。 ％的乙苯。 烷基化反应区在相对于乙苯提供丙基苯和丁基苯的复合副产物产率的条件下操作，其不超过用镧促进的沸石β的相应产率副产物的一半。 通过将反应产物的多烷基化芳族组分再循环回到反应区，可以在临界相烷基化反应区中生产乙苯。

公开(公告)号：US20060116450A1

公开(公告)日：2006-06-01

申请号：US11250665

申请日：2005-10-14

Applicant: Paul Buras ,  William Lee ,  James Butler

Inventor： Paul Buras ,  William Lee ,  James Butler

IPC: E01C7/26

CPC classification number: C08L95/00 ,  C08L9/06 ,  C08L81/04 ,  E01C7/18 ,  C08L2666/08

Abstract: Methods of modifying crude fractions are described herein. The methods generally include blending a crude fraction with an emissions reducing additive to form a modified crude fraction, wherein the modified crude fraction exhibits reduced sulfur emissions. The emissions reducing additive generally includes a dispersion of a metal oxide.