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    Dealkylation process
    1.
    发明授权
    Dealkylation process 有权
    脱烷基化方法

    公开(公告)号：US09067854B2

    公开(公告)日：2015-06-30

    申请号：US14473464

    申请日：2014-08-29

    申请人： ExxonMobil Chemical Patents Inc.

    发明人： Kun Wang ,  James R. Lattner

    IPC分类号： C07C4/18 ,  C07C4/14 ,  C07C5/10

    CPC分类号： C07C4/18 ,  C07C5/10 ,  C07C2521/00 ,  C07C2523/00 ,  C07C2527/02 ,  C07C2527/16 ,  C07C2529/06 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  C07C15/107

    摘要： In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound.

    摘要翻译： 在聚烷基化芳族化合物的脱烷基化方法中，将包含至少一种选自聚丙基苯，聚丁基苯和聚环己基苯的多烷基化芳族化合物的进料引入反应区。 然后在有效使至少一部分聚烷基化芳族化合物脱烷基化的条件下，将该进料在反应区中与酸催化剂接触，并产生包含至少一种单烷基化芳族化合物的第一反应产物。

    Dealkylation Process
    2.
    发明申请
    Dealkylation Process 有权
    脱烷基化方法

    公开(公告)号：US20140371499A1

    公开(公告)日：2014-12-18

    申请号：US14473464

    申请日：2014-08-29

    申请人： ExxonMobil Chemical Patents Inc.

    发明人： Kun Wang ,  James R. Lattner

    IPC分类号： C07C4/18 ,  C07C5/10

    CPC分类号： C07C4/18 ,  C07C5/10 ,  C07C2521/00 ,  C07C2523/00 ,  C07C2527/02 ,  C07C2527/16 ,  C07C2529/06 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  C07C15/107

    摘要： In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound.

    摘要翻译： 在聚烷基化芳族化合物的脱烷基化方法中，将包含至少一种选自聚丙基苯，聚丁基苯和聚环己基苯的多烷基化芳族化合物的进料引入反应区。 然后在有效使至少一部分聚烷基化芳族化合物脱烷基化的条件下，将该进料在反应区中与酸催化剂接触，并产生包含至少一种单烷基化芳族化合物的第一反应产物。

    GAS PHASE PROCESS FOR ACRYLATE PRODUCTION FROM ETHYLENE AND CARBON DIOXIDE
    3.
    发明公开
    GAS PHASE PROCESS FOR ACRYLATE PRODUCTION FROM ETHYLENE AND CARBON DIOXIDE 审中-公开

    公开(公告)号：US20230192586A1

    公开(公告)日：2023-06-22

    申请号：US17553165

    申请日：2021-12-16

    申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP

    发明人： Pasquale Iacono ,  Jamie N. Sutherland ,  Carlton E. Ash ,  Anand Ramanathan

    IPC分类号： C07C51/15

    CPC分类号： C07C51/15 ,  C07C2521/00 ,  C07C2523/00

    摘要： Catalysts and catalytic processes for the synthesis of acrylic acid and other α,β-unsaturated carboxylic acids and their salts, which are carried out in a diluent or in the absence of a diluent. In an aspect, ethylene and CO2 can be contacted with a Group 8-11 transition metal precursor compound or a Group 8-11 transition metal metalalactone compound in the presence of a metal-treated chemically-modified solid oxide (MT-CMSO) or a metal-treated solid oxide (MT-SO), to form a metal acrylate. As the catalytic activity wanes in either the presence or absence of a diluent, pressure cycling—that is, pressurizing the reaction system with CO2 and an olefin such as ethylene for a time period, releasing the pressure, then re-pressurizing with CO2 and ethylene—can rejuvenate the catalyst and restore its declining catalytic activity.

    Hydroalkylation Process
    4.
    发明申请
    Hydroalkylation Process 有权
    氢化烷基化方法

    公开(公告)号：US20150005531A1

    公开(公告)日：2015-01-01

    申请号：US14375967

    申请日：2012-11-30

    申请人： ExxonMobil Chemical Patents Inc.

    发明人： Christopher L. Becker ,  James R. Lattner ,  Keith H. Kuechler ,  Hari Nair

    IPC分类号： C07C2/74 ,  C07C45/53 ,  C07C5/32 ,  C07C37/08

    CPC分类号： C07C2/74 ,  C07C5/321 ,  C07C5/367 ,  C07C37/08 ,  C07C45/53 ,  C07C2521/00 ,  C07C2523/00 ,  C07C2529/74 ,  C07C2601/14 ,  C07C39/04 ,  C07C49/403 ,  C07C13/28 ,  C07C15/04

    摘要： In a process for producing phenol, benzene is hydroalkylated with hydrogen in the presence of a catalyst under conditions effective to produce a hydroalkylation reaction product comprising cyclohexylbenzene and cyclohexane. At least a portion of the cyclohexane from said hydroalkylation reaction product is then dehydrogenated to produce a dehydrogenation effluent comprising benzene, toluene and hydrogen. At least a portion of the dehydrogenation effluent is washed with a benzene-containing stream to transfer at least a portion of the toluene from the dehydrogenation effluent to the benzene-containing stream.

    摘要翻译： 在生产苯酚的方法中，在有效产生包含环己基苯和环己烷的加氢烷基化反应产物的条件下，在催化剂存在下，用氢加氢苯。 然后将来自所述加氢烷基化反应产物的至少一部分环己烷脱氢以产生包含苯，甲苯和氢的脱氢流出物。 至少一部分脱氢流出物用含苯物流洗涤，将至少一部分甲苯从脱氢流出物转移到含苯物流中。

    Dealkylation Process
    8.
    发明申请
    Dealkylation Process 有权
    脱烷基化方法

    公开(公告)号：US20120310024A1

    公开(公告)日：2012-12-06

    申请号：US13578755

    申请日：2011-02-03

    申请人： Kun Wang ,  James R. Lattner

    发明人： Kun Wang ,  James R. Lattner

    IPC分类号： C07C2/76 ,  C07C4/18 ,  C07C4/26

    CPC分类号： C07C4/18 ,  C07C5/10 ,  C07C2521/00 ,  C07C2523/00 ,  C07C2527/02 ,  C07C2527/16 ,  C07C2529/06 ,  C07C2529/70 ,  C07C2529/83 ,  C07C2529/85 ,  C07C15/107

    摘要： In a process for dealkylating a poly-alkylated aromatic compound, a feed comprising at least one poly-alkylated aromatic compound selected from polypropylbenzene, polybutylbenzene, and polycyclohexylbenzene is introduced into a reaction zone. The feed is then contacted in the reaction zone with an acid catalyst under conditions effective to dealkylate at least a portion of the poly-alkylated aromatic compound and produce a first reaction product comprising at least one mono-alkylated aromatic compound.

    摘要翻译： 在聚烷基化芳族化合物的脱烷基化方法中，将包含至少一种选自聚丙基苯，聚丁基苯和聚环己基苯的多烷基化芳族化合物的进料引入反应区。 然后在有效使至少一部分聚烷基化芳族化合物脱烷基化的条件下，将该进料在反应区中与酸催化剂接触，并产生包含至少一种单烷基化芳族化合物的第一反应产物。

    Process for the oxidative coupling of hydrocarbons
    10.
    发明授权
    Process for the oxidative coupling of hydrocarbons 有权
    碳氢化合物的氧化偶合方法

    公开(公告)号：US08796497B2

    公开(公告)日：2014-08-05

    申请号：US14072971

    申请日：2013-11-06

    申请人： Fina Technology, Inc.

    发明人： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

    IPC分类号： C07C2/84 ,  C07C2/66

    CPC分类号： C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

    摘要： A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    摘要翻译： 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。