公开(公告)号：US06225254B1

公开(公告)日：2001-05-01

申请号：US09392981

申请日：1999-09-09

申请人： Marcel J. G. Janssen ,  Machteld M. Mertens ,  Cornelius W. M. Van Oorschot ,  Stephen N. Vaughn ,  Hsiang-Ning Sun ,  David R. Lumgair

发明人： Marcel J. G. Janssen ,  Machteld M. Mertens ,  Cornelius W. M. Van Oorschot ,  Stephen N. Vaughn ,  Hsiang-Ning Sun ,  David R. Lumgair

IPC分类号： B01J27182

CPC分类号： C10G3/49 ,  B01J29/85 ,  B01J37/082 ,  B01J37/084 ,  B01J37/14 ,  B01J2229/40 ,  C07C1/20 ,  C07C2529/85 ,  C10G2300/703 ,  C10G2400/20 ,  Y02P30/20 ,  C07C11/02

摘要： This invention is directed to a molecular sieve having acid catalyst sites and a method of maintaining the acid catalyst sites of a template-containing silicoaluminophosphate molecular sieve. The method comprises providing a template-containing silicoaluminophosphate molecular sieve and heating the molecular sieve in an oxygen depleted environment under conditions effective to maintain or preserve the number of acid catalyst sites. The heated molecular sieve exhibits at least one peak in the infrared region in a range of from 3630 cm−1 to 3580 cm−1. Preferably, the heated molecular sieve exhibits a combined peak area in the 3630 cm−1 to 3580 cm−1 range of at least 10% of a total peak area of all peaks in an infrared region between 4000 cm−1 to 3400 cm−1.

摘要翻译： 本发明涉及具有酸催化剂位点的分子筛和保持含有模板的硅铝磷酸盐分子筛的酸催化剂位点的方法。 该方法包括提供含模板的硅铝磷酸盐分子筛，并在有效维持或保持酸催化剂位点的数量的条件下在贫氧环境中加热分子筛。 加热的分子筛在3630cm-1至3580cm -1的范围内显示红外区域中的至少一个峰。 优选地，加热的分子筛表现出在3630cm -1至3580cm -1范围内的组合峰面积，其在4000cm -1至3400cm -1之间的红外区域中的所有峰的总峰面积的至少10％ 。

公开(公告)号：US20120202954A1

公开(公告)日：2012-08-09

申请号：US13449424

申请日：2012-04-18

申请人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R.M. Martens ,  Mobae Afeworki

发明人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R.M. Martens ,  Mobae Afeworki

IPC分类号： C08F10/02 ,  C08F10/06 ,  C08F2/00

CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

摘要翻译： 在合成具有90％+ CHA骨架类型特征的硅铝磷酸盐分子筛的方法中，制备反应混合物，其包括首先将活性的铝源与磷的反应源混合以形成老化的初级混合物。 然后可以加入硅的反应性源和用于引导分子筛形成的模板以形成合成混合物。 然后在合成混合物中诱导结晶。 有利地，（i）硅源包含有机硅酸盐，（ii）磷源任选地包含有机磷酸盐，和（iii）结晶的硅铝磷酸盐分子筛具有使其平均晶体尺寸不大于5的晶体尺寸分布 μm。 分子筛可以优选用于烃（含氧化合物 - 烯烃）转化过程中。

公开(公告)号：US08182780B2

公开(公告)日：2012-05-22

申请号：US12477750

申请日：2009-06-03

申请人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R. M. Martens ,  Mobae Afeworki

发明人： Machteld M. Mertens ,  Stephen N. Vaughn ,  Guang Cao ,  Luc R. M. Martens ,  Mobae Afeworki

IPC分类号： C01B37/08 ,  B01J27/182 ,  C07C1/24

CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90%+CHA framework type character, a reaction mixture is prepared comprising first combining a reactive source of aluminum with a reactive source of phosphorus to form a primary mixture that is aged. A reactive source of silicon and a template for directing the formation of the molecular sieve can then be added to form a synthesis mixture. Crystallization is then induced in the synthesis mixture. Advantageously, (i) the source of silicon comprises an organosilicate, (ii) the source of phosphorus optionally comprises an organophosphate, and (iii) the crystallized silicoaluminophosphate molecular sieve has a crystal size distribution such that its average crystal size is not greater than 5 μm. The molecular sieve can then preferably be used in a hydrocarbon (oxygenates-to-olefins) conversion process.

摘要翻译： 在合成具有90％+ CHA骨架类型特征的硅铝磷酸盐分子筛的方法中，制备反应混合物，其包括首先将活性的铝源与磷的反应源混合以形成老化的初级混合物。 然后可以加入硅的反应性源和用于引导分子筛形成的模板以形成合成混合物。 然后在合成混合物中诱导结晶。 有利地，（i）硅源包含有机硅酸盐，（ii）磷源任选地包含有机磷酸盐，和（iii）结晶的硅铝磷酸盐分子筛具有使其平均晶体尺寸不大于5的晶体尺寸分布 μm。 分子筛可以优选用于烃（含氧化合物 - 烯烃）转化过程中。

公开(公告)号：US20100022722A1

公开(公告)日：2010-01-28

申请号：US12477808

申请日：2009-06-03

申请人： Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C01B39/04 ,  C07C1/02 ,  C08F4/18 ,  C08F2/00

CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.

摘要翻译： 在合成具有90 + CHA框架型特征的硅铝磷酸盐分子筛的方法中，制备包含水，硅，铝和磷源以及有机模板的反应混合物。 在一个方面，将反应混合物在大于10℃/小时加热至结晶温度，并保持在结晶温度或结晶温度范围内，结晶时间为16小时至350小时，以产生硅铝磷酸盐分子 筛。 在另一方面，将反应混合物在小于10℃/小时加热至约150℃至约225℃的结晶温度，然后将其保留在少于10小时以产生硅铝磷酸盐分子筛 。 然后可以从反应混合物中回收分子筛，并且优选用于烃转化方法，例如含氧化合物至烯烃。

公开(公告)号：US07402718B2

公开(公告)日：2008-07-22

申请号：US11805974

申请日：2007-05-25

申请人： Marcel J. G. Janssen ,  Teng Xu ,  Cor F. Van Egmond ,  Keith H. Kuechler ,  Stephen N. Vaughn ,  James Harding Beech, Jr.

发明人： Marcel J. G. Janssen ,  Teng Xu ,  Cor F. Van Egmond ,  Keith H. Kuechler ,  Stephen N. Vaughn ,  James Harding Beech, Jr.

IPC分类号： C07C1/20 ,  C07C27/00

CPC分类号： C07C1/20 ,  B01J29/85 ,  C07C2529/00 ,  Y02P30/42 ,  C07C11/02

摘要： The invention relates to a conversion process for making olefin(s) using a molecular sieve catalyst composition. More specifically, the invention is directed to a process for converting a feedstock comprising an oxygenate in the presence of a molecular sieve catalyst composition, wherein the feedstock is free of or substantially free of metal salts.

公开(公告)号：US07034196B2

公开(公告)日：2006-04-25

申请号：US10175285

申请日：2002-06-19

申请人： Kenneth Ray Clem ,  Stephen N. Vaughn ,  Teng Xu ,  Jeffrey L. White

发明人： Kenneth Ray Clem ,  Stephen N. Vaughn ,  Teng Xu ,  Jeffrey L. White

IPC分类号： C07C1/20

CPC分类号： B01J8/1827 ,  B01J19/26 ,  B01J2208/00176 ,  B01J2208/00274 ,  B01J2219/00119 ,  B01J2219/00155 ,  B01J2219/00254 ,  C07C1/20 ,  Y02P30/42 ,  Y10S585/92 ,  Y10S585/923

摘要： Disclosed is a method and apparatus for reducing the amount of metal catalyzed side-reaction byproducts formed in the feed vaporization and introduction system of a methanol to olefin reactor system by monitoring and/or maintaining the temperature of at least a portion of the feed vaporization and introduction system and/or of the feedstock contained therein below about 400° C., 350° C., 300° C., 250° C., 200° C. or below about 150° C. The temperature can be maintained in the desired range by jacketing at least a portion of the feed vaporization and introduction system, such as at least a portion of the feed introduction nozzle, with a thermally insulating material or by implementing a cooling system.

公开(公告)号：US06605749B2

公开(公告)日：2003-08-12

申请号：US10342601

申请日：2003-01-15

申请人： Stephen N. Vaughn ,  Luc R. M. Martens ,  Keith H. Kuechler ,  Albert E. Schweizer

发明人： Stephen N. Vaughn ,  Luc R. M. Martens ,  Keith H. Kuechler ,  Albert E. Schweizer

IPC分类号： C07C100

CPC分类号： B01J29/005 ,  B01J29/85 ,  B01J2229/26 ,  B01J2229/42 ,  C10G3/45 ,  C10G3/49 ,  C10G2300/4081 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10S502/514

摘要： Disclosed is a molecular sieve catalyst which contains molecular sieve-containing attrition particles and virgin molecular sieve, the attrition particles having been recycled from a catalyst manufacture process or from a reaction system. The catalyst can be used in a variety of catalytic reaction processes. A desired process is making olefins from an oxygenate feedstock. The recovery and use of the attrition particles in the catalyst is beneficial in minimizing waste, thereby reducing problems relating to both environmental and economic constraints.

公开(公告)号：US06541415B2

公开(公告)日：2003-04-01

申请号：US09894158

申请日：2001-06-27

申请人： Stephen N. Vaughn ,  Luc R. M. Martens ,  Keith H. Kuechler ,  Albert E. Schweizer

发明人： Stephen N. Vaughn ,  Luc R. M. Martens ,  Keith H. Kuechler ,  Albert E. Schweizer

IPC分类号： B01J27182

CPC分类号： B01J29/005 ,  B01J29/85 ,  B01J2229/26 ,  B01J2229/42 ,  C10G3/45 ,  C10G3/49 ,  C10G2300/4081 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S423/30 ,  Y10S502/514

摘要： Disclosed is a molecular sieve catalyst which contains molecular sieve-containing attrition particles and virgin molecular sieve, the attrition particles having been recycled from a catalyst manufacture process or from a reaction system. The catalyst can be used in a variety of catalytic reaction processes. A desired process is making olefins from an oxygenate feedstock. The recovery and use of the attrition particles in the catalyst is beneficial in minimizing waste, thereby reducing problems relating to both environmental and economic constraints.

公开(公告)号：US06437208B1

公开(公告)日：2002-08-20

申请号：US09481364

申请日：2000-01-11

申请人： Keith H. Kuechler ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Shun C. Fung ,  Nicolas P. Coute ,  Jeffrey Scott Smith ,  James R. Lattner ,  Jeffrey L. White ,  Teng Xu ,  William L. Kuechler, Sr. ,  Machteld M. Mertens ,  Cornelius W. M. Van Oorschot

发明人： Keith H. Kuechler ,  Marcel J. G. Janssen ,  Stephen N. Vaughn ,  Shun C. Fung ,  Nicolas P. Coute ,  Jeffrey Scott Smith ,  James R. Lattner ,  Jeffrey L. White ,  Teng Xu ,  William L. Kuechler, Sr. ,  Machteld M. Mertens ,  Cornelius W. M. Van Oorschot

IPC分类号： C07C120

CPC分类号： C10G50/00 ,  B01J29/85 ,  B01J29/90 ,  B01J35/0006 ,  B01J2229/123 ,  C10G3/49 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/1022 ,  C10G2300/1029 ,  C10G2300/4018 ,  C10G2300/708 ,  C10G2400/02 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P30/42

摘要： Disclosed is a method for making olefin product from an oxygenate-containing feedstock. In the method, a silicoaluminophosphate molecular sieve catalyst is contacted with the oxygenate-containing feedstock in a reactor at an average catalyst feedstock exposure index of at least 1.0. The method produces lower coke yield and provides an olefin product which is low in C1-C4 paraffin content. The invention is particularly effective in producing an olefin product having a very low propane content.

摘要翻译： 公开了一种从含氧化合物的原料制备烯烃产物的方法。 在该方法中，将硅铝磷酸盐分子筛催化剂在反应器中与含氧化合物的原料接触，平均催化剂原料暴露指数为至少1.0。 该方法产生较低的焦炭产量，并提供C1-C4链烷烃含量低的烯烃产物。 本发明在生产丙烷含量非常低的烯烃产物方面特别有效。

公开(公告)号：US08399578B2

公开(公告)日：2013-03-19

申请号：US13589289

申请日：2012-08-20

申请人： Machteld M. Mertens ,  Stephen N. Vaughn

发明人： Machteld M. Mertens ,  Stephen N. Vaughn

IPC分类号： C01B39/54 ,  C01B37/08 ,  C07C1/20 ,  C07C2/10

CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.

摘要翻译： 在合成具有90 + CHA框架型特征的硅铝磷酸盐分子筛的方法中，制备包含水，硅，铝和磷源以及有机模板的反应混合物。 在一个方面，将反应混合物在大于10℃/小时加热至结晶温度，并保持在结晶温度或结晶温度范围内，结晶时间为16小时至350小时，以产生硅铝磷酸盐分子 筛。 在另一方面，将反应混合物在小于10℃/小时加热至约150℃至约225℃的结晶温度，然后将其保留在少于10小时以产生硅铝磷酸盐分子筛 。 然后可以从反应混合物中回收分子筛，并且优选用于烃转化方法，例如含氧化合物至烯烃。