公开(公告)号：US5227365A

公开(公告)日：1993-07-13

申请号：US840195

申请日：1992-02-24

申请人： Jaak S. Van den Sype

发明人： Jaak S. Van den Sype

IPC分类号： C01G1/00 ,  C01G3/00 ,  C04B35/45 ,  C04B35/622 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/2419 ,  C04B35/45 ,  C04B35/62231 ,  Y10S428/902 ,  Y10S428/93 ,  Y10S505/739 ,  Y10S505/74 ,  Y10S505/78 ,  Y10S505/785 ,  Y10T428/30

摘要： Process for producing superconducting metal-oxide textiles comprising impregnating a preformed, organic textile material with metal compounds in a desired atomic ratio, heating the material in a weakly oxidizing atmosphere to pyrolize and oxidize the organic material, maintaining the material at temperature in an oxidizing atmosphere, and cooling the material in an oxidizing atmosphere, so as to form a crystalline structure capable of superconducting.

摘要翻译： 制造超导金属氧化物纺织品的方法包括用预期的有机织物材料以所需的原子比浸渍金属化合物，在弱氧化气氛中加热该材料以热处理和氧化有机材料，将材料保持在氧化气氛中的温度 ，并在氧化气氛中冷却材料，以形成能够超导的结晶结构。

公开(公告)号：US5215565A

公开(公告)日：1993-06-01

申请号：US817965

申请日：1992-01-08

申请人： Akira Urano ,  Kenichi Takahashi ,  Kazuya Ohmatsu ,  Masashi Onishi

发明人： Akira Urano ,  Kenichi Takahashi ,  Kazuya Ohmatsu ,  Masashi Onishi

IPC分类号： C03B37/026 ,  C03B37/027 ,  C03B37/028 ,  H01L39/24

CPC分类号： C03B37/027 ,  C03B37/026 ,  C03B37/028 ,  H01L39/248 ,  Y10S505/704 ,  Y10S505/74

摘要： A method of the production of the ceramic superconductor filament comprisesa step including mixing raw materials of ceramic superconductor, subsequently shaping the mixed ceramic superconductor into a ceramic superconductor body of a predetermined shape and preliminarily sintering thereof and further subsequently crushing the sintered ceramic superconductor body into ceramic superconductor powder;a step of filling the ceramic superconductor powder in a glass tube;a step of heating the glass tube including ceramic superconductor powder so that the ceramic superconductor powder is molten; anda step of spinning the glass tube including the ceramic superconductor materialwhereby a ceramic super conductor covered with the glass material can be obtained.

摘要翻译： 制造陶瓷超导体丝的方法包括：将陶瓷超导体的原料混合，然后将混合陶瓷超导体成形为规定形状的陶瓷超导体，并预先烧结，然后将烧结陶瓷超导体体破碎成 陶瓷超导体粉末; 将陶瓷超导体粉末填充到玻璃管中的步骤; 加热包括陶瓷超导体粉末的玻璃管，使陶瓷超导体粉末熔融的步骤; 以及纺丝包含陶瓷超导体材料的玻璃管的步骤，由此可以获得覆盖有玻璃材料的陶瓷超导体。

公开(公告)号：US5210071A

公开(公告)日：1993-05-11

申请号：US845511

申请日：1992-02-27

申请人： Dominic N. LoIacono ,  John T. Plewes

发明人： Dominic N. LoIacono ,  John T. Plewes

IPC分类号： H01L39/24

CPC分类号： H01L39/248 ,  Y10S505/739 ,  Y10S505/74

摘要： A method for forming elongated articles including metallic oxide superconductor material by hydrostatic extrusion at temperatures less than about 800.degree. C., and even at temperatures less than about 450.degree. C. The method includes providing superconductive core material that is substantially free of carbon or organic additives and that has an equivalent density at least about 55% of full density, and enclosing the densified material in a metal container, to become a cladding, prior to extrusion. In a preferred embodiment, the cladding material is a dispersion hardened metal or metal alloy.

摘要翻译： 一种用于通过在低于约800℃的温度以及甚至在低于约450℃的温度下静压挤出来形成包括金属氧化物超导体材料的细长制品的方法。该方法包括提供基本上不含碳或有机物的超导芯材料 添加剂，并且具有至少约55％的全密度的等效密度，并且在挤出之前将致密材料包封在金属容器中以成为包层。 在优选实施例中，包层材料是分散硬化的金属或金属合金。

公开(公告)号：US5192739A

公开(公告)日：1993-03-09

申请号：US723032

申请日：1991-06-28

申请人： Kenneth W. Lay

发明人： Kenneth W. Lay

IPC分类号： C01G1/00 ,  C01G29/00 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/248 ,  Y10S505/739 ,  Y10S505/74

摘要： A method of forming a superconducting tape having a silver sheath and a polycrystalline oxide superconductor core includes, forming at least one silver foil to have a receiving surface for supporting a deposit, and at least one enclosing surface that can cover the deposit and overlap another portion of the foil so that the surfaces form the sheath. The foil has a first thickness at the receiving surface and a second thickness at the enclosing surface. A precursor deposit of the superconductor is formed on the receiving surface. The enclosing surface is wrapped to cover the deposit and overlap another portion of the foil to form the sheath. The first and second thicknesses being preselected so that the thickness of the overlapping foils is equivalent to the thickness of foil oppositely facing the overlapping foils. The overlapping foils are sealed, and annealed to reaction-sinter the sealed deposit and form the tape.

摘要翻译： 形成具有银鞘和多晶氧化物超导体芯的超导带的方法包括：形成至少一个银箔以具有用于支撑沉积物的接收表面，以及至少一个可覆盖沉积物并且覆盖另一部分的封闭表面 的箔，使得表面形成护套。 箔在接收表面具有第一厚度，在封闭表面具有第二厚度。 在接收表面上形成超导体的前体沉积物。 封闭的表面被包裹以覆盖沉积物并与箔的另一部分重叠以形成护套。 第一和第二厚度被预选为使得重叠的箔的厚度等于相对于重叠箔的箔的厚度。 重叠的箔被密封，并退火以对密封的沉积物进行反应烧结并形成带。

公开(公告)号：US5171735A

公开(公告)日：1992-12-15

申请号：US438762

申请日：1989-11-17

申请人： James C. W. Chien

发明人： James C. W. Chien

IPC分类号： H01L39/24

CPC分类号： H01L39/248 ,  Y10S505/734 ,  Y10S505/737 ,  Y10S505/74

摘要： A method for forming a high T.sub.c metal oxide superconductor in the form of a hollow fiber. The method includes the steps of: forming a polymer-metal complex precursor; filling a decomposable hollow fiber mold with the precursor; and heating the filled mold to decompose the mold and convert the precursor to a metal oxide superconductor in the form of a hollow fiber. Ag-doped metal oxide superconductor structures can also be produced by the above method.

摘要翻译： 一种形成中空纤维形式的高Tc金属氧化物超导体的方法。 该方法包括以下步骤：形成聚合物 - 金属络合物前体; 用前体填充可分解的中空纤维模具; 并加热填充的模具以分解模具并将前体转化为中空纤维形式的金属氧化物超导体。 Ag掺杂的金属氧化物超导体结构也可以通过上述方法制备。

公开(公告)号：US5122510A

公开(公告)日：1992-06-16

申请号：US605564

申请日：1990-10-29

申请人： Kuo-Chun Chen ,  Khodabakhsh S. Mazdiyasni

发明人： Kuo-Chun Chen ,  Khodabakhsh S. Mazdiyasni

IPC分类号： C01G3/00 ,  C04B35/45 ,  H01L39/24

CPC分类号： H01L39/2425 ,  C01G3/006 ,  C04B35/4508 ,  C01P2002/34 ,  C01P2002/76 ,  Y10S505/734 ,  Y10S505/735 ,  Y10S505/738 ,  Y10S505/74

摘要： A method of making high T.sub.c 1-2-3 superconductors having perovskite structure using solution techniques is disclosed. The process uses two solvent systems to form a resinous preceramic material having a controlled viscosity for facilitating its formation into superconducting articles such as fibers, wires, ribbons, films and the like. The process yields a pre-ceramic which is flexible and which has sufficient structural integrity to withstand normal handling.

公开(公告)号：US5100867A

公开(公告)日：1992-03-31

申请号：US477970

申请日：1990-06-11

申请人： Karl-Heinz Gunzelmann ,  Reiner Muller ,  Werner Herkert ,  Joachim Grosse ,  Gunter Tiefel

发明人： Karl-Heinz Gunzelmann ,  Reiner Muller ,  Werner Herkert ,  Joachim Grosse ,  Gunter Tiefel

IPC分类号： B21F19/00 ,  B30B11/00 ,  B30B11/22 ,  C04B35/45 ,  C04B35/645 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/248 ,  C04B35/4504 ,  C04B35/4512 ,  C04B35/4521 ,  C04B35/6455 ,  Y10S505/739 ,  Y10S505/74 ,  Y10S505/786 ,  Y10T29/49014 ,  Y10T428/12354 ,  Y10T428/12896 ,  Y10T428/12924

摘要： In a known process, oxide powders derived from the four-component systems yttrium-barium-copper-oxygen or lanthanum-strontium-copper-oxygen are mixed, pressed, sintered, ground and then heat-treated to produce a superconducting material which can be shaped to the desired cross-section. According to the invention, the powder is compacted by isostatic pressing and the blank so obtained is extruded at a temperature.gtoreq.500.degree. C. to form a metallic sheath with a deformation ratio of at least 50%. The extruded blank is then converted to wire or strip. The current-carrying capacity of the high-temperature superconductor is improved by the extrusion and the resulting alignment of the crystallites. The process can be implemented using known high-temperatures superconducting material.

摘要翻译： PCT No.PCT / DE88 / 00763 Sec。 371 1990年6月11日第 102（e）日期1990年6月11日PCT提交1988年12月13日PCT公布。 公开号WO89 / 06053 日本1982年6月29日。在已知的方法中，将由四组分体系钇 - 钡 - 铜 - 氧或镧 - 锶 - 铜 - 氧衍生的氧化物粉末混合，压制，烧结，研磨，然后热处理 产生可以成形为期望横截面的超导材料。 根据本发明，粉末通过等静压压实，将得到的坯料在≥500℃的温度下挤出，形成变形率至少为50％的金属护套。 然后将挤出的坯料转化成导线或带材。 高温超导体的载流能力通过挤出和微晶的排列得到改善。 该方法可以使用已知的高温超导材料来实现。

公开(公告)号：US5070071A

公开(公告)日：1991-12-03

申请号：US255792

申请日：1988-10-11

申请人： Theodore H. Geballe ,  Robert S. Feigelson ,  Dan Gazit

发明人： Theodore H. Geballe ,  Robert S. Feigelson ,  Dan Gazit

IPC分类号： C04B35/45 ,  C04B35/653 ,  C23C2/04 ,  H01L39/24

CPC分类号： H01L39/248 ,  C04B35/4521 ,  C04B35/653 ,  C23C2/04 ,  Y10S505/704 ,  Y10S505/733 ,  Y10S505/74

摘要： A method is provided for making a flexible superconductive composite wire by drawing a wire of noble metal through a melt formed from solid superconducting material. The preferred superconducting material comprises the Bi-Sr-Ca-Cu-O class of materials.

摘要翻译： 提供了一种用于通过由固体超导材料形成的熔体拉伸贵金属丝来制造柔性超导复合材料线的方法。 优选的超导材料包括Bi-Sr-Ca-Cu-O类材料。

公开(公告)号：US5045527A

公开(公告)日：1991-09-03

申请号：US251847

申请日：1988-10-03

申请人： Yoshimitsu Ikeno ,  Osamu Kohno ,  Kenji Goto ,  Atsushi Kume ,  Shin'ya Aoki ,  Nobuyuki Sadakata ,  Masaru Sugimoto ,  Toshio Usui ,  Mikio Nakagawa ,  Taichi Yamaguchi

发明人： Yoshimitsu Ikeno ,  Osamu Kohno ,  Kenji Goto ,  Atsushi Kume ,  Shin'ya Aoki ,  Nobuyuki Sadakata ,  Masaru Sugimoto ,  Toshio Usui ,  Mikio Nakagawa ,  Taichi Yamaguchi

IPC分类号： C04B35/45 ,  H01L39/24

CPC分类号： C04B35/4512 ,  C04B35/45 ,  C04B35/4504 ,  C04B35/4521 ,  H01L39/248 ,  Y10S505/74

摘要： A method of producing a superconductor including a superconductive oxide. At least one material is pressed for forming a filling material, the at least one material being selected from the group consisting of a starting material powder of the superconductive oxide, a powder of the superconductive oxide and a compact made of the starting material powder and/or the superconductive oxide powder, for forming a filling material. The filling material is charged into a metallic pipe to form a preform. The preform is moved along an axis thereof. During moving, the preform is swaged perpendicularly to the axis thereof to form a composite having a metallic sheath, made of the metallic pipe, and a core sheathed with the metallic sheath. The core of the composite is heated for producing the superconductive oxide.

摘要翻译： 一种制造包括超导氧化物的超导体的方法。 至少一种材料被压制以形成填充材料，所述至少一种材料选自由超导氧化物的原料粉末，超导氧化物的粉末和由原料粉末制成的压块和/ 或超导氧化物粉末，用于形成填充材料。 将填充材料装入金属管中以形成预制件。 预成型件沿其轴线移动。 在移动过程中，将预制件垂直于其轴线锻压，以形成具有由金属管制成的金属护套的复合材料，以及用金属护套包覆的芯。 加热复合材料的核心以生产超导氧化物。

公开(公告)号：US5039658A

公开(公告)日：1991-08-13

申请号：US457672

申请日：1989-12-27

申请人： Che-Hsiung Hsu

发明人： Che-Hsiung Hsu

IPC分类号： H01L39/24

CPC分类号： H01L39/248 ,  Y10S505/74

摘要： Bi.sub.2 Sr.sub.2 Ca,Cu.sub.2 2212 superconductive oxide fiber having enhanced current carrying capacity is prepared by forming an intimate mixture of the Bi.sub.2 Sr.sub.2 Ca.sub.1 Cu.sub.2 superconductive oxide precursors or their functional equivalents, firing the mixture at a temperature of at least 400.degree. C. but below the melting point of the superconductive oxide, dispersing the fired mixture in an organic binder, extruding the dispersion as fiber extrudate, firing the fiber at a temperature sufficient to cause the organic binder to burn off and to cause melting of the superconductive oxide while substantially retaining the filamentary shape, and then cooling the fiber.

摘要翻译： 通过形成Bi2Sr2Ca1Cu2超导氧化物前体或其功能等价物的紧密混合物制备具有增强的载流能力的Bi2Sr2Ca，Cu2 2212超导氧化物纤维，在至少400℃但低于 将烧结的混合物分散在有机粘合剂中，将分散体挤出为纤维挤出物，在足以引起有机粘合剂燃烧并引起超导氧化物熔化同时基本保持丝状形状的温度下烧制纤维，以及 然后冷却纤维。