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    Method and catalyst system for producing aromatic carbonates
    41.
    发明授权
    Method and catalyst system for producing aromatic carbonates 失效
    用于生产芳族碳酸酯的方法和催化剂体系

    公开(公告)号：US06372683B2

    公开(公告)日：2002-04-16

    申请号：US09757247

    申请日：2001-01-10

    Applicant: Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Donald Wayne Whisenhunt, Jr.

    Inventor： Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Donald Wayne Whisenhunt, Jr.

    IPC: B01J3100

    CPC classification number: C07C68/005 ,  C07C69/96

    Abstract: A method and catalyst system for producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the method includes the step of contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system having catalytic amounts of the following components: a Group VIII B metal source; a combination of inorganic co-catalysts including a copper source and at least one of a titanium source or a zirconium source; an onium chloride composition; and a base. Alternative embodiments include inorganic co-catalyst combinations of a lead source and at least one of a titanium source or a manganese source.

    Abstract translation: 用于由芳族羟基化合物制备芳族碳酸酯的方法和催化剂体系。 在一个实施方案中，该方法包括在具有催化量的以下组分的羰基化催化剂体系的存在下使至少一种芳族羟基化合物与氧和一氧化碳接触的步骤：VIIIB族金属源; 包括铜源和至少一种钛源或锆源的无机助催化剂的组合; 氯化铟组合物; 和一个基地。 替代实施方案包括铅源和钛源或锰源中的至少一种的无机助催化剂组合。

    Supported double metal cyanide catalysts, method for producing them, and their use for producing polyether alcohols
    44.
    发明授权
    Supported double metal cyanide catalysts, method for producing them, and their use for producing polyether alcohols 失效
    负载型双金属氰化物催化剂，其制备方法及其制备聚醚醇的用途

    公开(公告)号：US06362126B1

    公开(公告)日：2002-03-26

    申请号：US09623553

    申请日：2000-09-09

    Applicant: Georg Heinrich Grosch ,  Harald Larbig ,  Reinhard Lorenz ,  Dieter Junge ,  Ulrich Kammel

    Inventor： Georg Heinrich Grosch ,  Harald Larbig ,  Reinhard Lorenz ,  Dieter Junge ,  Ulrich Kammel

    IPC: B01J3100

    CPC classification number: C08G65/2693 ,  B01J27/26 ,  C08G65/2663

    Abstract: Double-metal cyanide catalysts of the formula M1a[M2(CN)b(A)c]d. fM1gXn. h (H2O). eL, where M1 is a metal ion selected from the group consisting of Zn2+, Fe2+, Co3+, Ni2+, Mn2+, Co2+, Sn2+, Pb2+, Mo4+, Mo6+, Al3+, V4+, V5+, Sr2+, W4+, W6+, Cr2+, Cr3+ and Cd2+, M2 is a metal ion selected from the group consisting of Fe2+, Fe3+, Co2+, Co3+, Mn2+, Mn3+, V4+, V5+, Cr2+, Cr3+, Rh3+, Ru2+ and Ir3+ and M1 and M2 are identical or different, A is an anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and nitrate, X is an anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and nitrate, L is a water-miscible ligand selected from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, ureas, amides, nitriles and sulfides, a, b, c, d, g and n are selected so as to make the compound electrically neutral, and e denotes the coordination number of the ligand, e and f denote fractions or integers greater than or equal to zero, h denotes a fraction or integer greater than or equal to zero, wherein the double-metal cyanides have been applied to or incorporated into solid, inert, unfoamed supports or have been shaped to give moldings.

    Abstract translation: 式M1的双金属氰化物催化剂是选自Zn2 +，Fe2 +，Co3 +，Ni2 +，Mn2 +，Co2 +，Sn2 +，Pb2 +，Mo4 +，Mo6 +，Al3 +，V4 +，V5 +，Sr2 +，W4 +，W6 + Cr2 +，Cr3 +和Cd2 +，M2是选自Fe2 +，Fe3 +，Co2 +，Co3 +，Mn2 +，Mn3 +，V4 +，V5 +，Cr2 +，Cr3 +，Rh3 +，Ru2 +和Ir3 +的金属离子，M1和M2相同或相同 不同的是，A是选自卤化物，氢氧化物，硫酸盐，碳酸盐，氰化物，硫氰酸盐，异氰酸盐，氰酸盐，羧酸盐，草酸盐和硝酸盐的阴离子，X是选自卤化物，氢氧化物，硫酸盐， 碳酸盐，氰化物，硫氰酸盐，异氰酸盐，氰酸盐，羧酸盐，草酸盐和硝酸盐，L是选自醇，醛，酮，醚，聚醚，酯，脲，酰胺，腈和硫化物的水混溶配体， 选择b，c，d，g和n以使化合物电中性，并且e表示配位数 r的配体，e和f表示大于或等于零的分数或整数，h表示大于或等于零的分数或整数，其中双金属氰化物已经施加到固体，惰性，未发泡的 支撑或已经成形为赋予模制品。

    Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst
    48.
    发明授权
    Catalyst for trimerization of ethylene and process for trimerizing ethylene using the catalyst 有权
    乙烯三聚催化剂和使用催化剂使乙烯三聚的方法

    公开(公告)号：US06337297B1

    公开(公告)日：2002-01-08

    申请号：US09457522

    申请日：1999-12-09

    Applicant: Hideyuki Mimura ,  Motohiro Oguri ,  Toshihide Yamamoto ,  Hideyuki Murakita ,  Hisanori Okada ,  Toru Yoshida

    Inventor： Hideyuki Mimura ,  Motohiro Oguri ,  Toshihide Yamamoto ,  Hideyuki Murakita ,  Hisanori Okada ,  Toru Yoshida

    IPC: B01J3100

    CPC classification number: B01J31/2409 ,  B01J31/16 ,  B01J31/1815 ,  B01J31/20 ,  B01J2231/328 ,  B01J2531/0247 ,  B01J2531/62 ,  C07C2/32 ,  C07C2531/22 ,  Y02P20/52 ,  C07C11/107

    Abstract: A catalyst for trimerization of ethylene is disclosed which comprises (a) a chromium complex having a neutral multidentate ligand having a tripod structure, represented by the formula, ACrJnQ3-n wherein A is a neutral multidentate ligand having a tripod structure, J is a carbonyl ligand or halogen, n is an integer of 0-3, and Q is at least one member selected from hydrogen, a C1-C10 hydrocarbon group, a C1-C10 carboxylate group, a C3-C10 diketonato group, an amide group, an imide group, an C1-C10 alkoxide group, a C1-C10 thioalkoxide group, an C6-C15 arene ligand, an C2-C10 alkene ligand, an C2-C15 alkyne ligand, an amine ligand, an imine ligand, an isonitrile ligand, a phosphine ligand, a phosphine oxide ligand, a phosphite ligand, an ether ligand, a sulfide ligand, a sulfone ligand and a sulfoxide ligand, and (b) a metal alkyl compound. The catalyst optionally further comprises (c) at least one compound selected from aromatic tertiary amine compounds, except for an imine, and nitrogen-containing heterocyclic compounds, and (d) a radical anion compound.

    Abstract translation: 公开了一种用于乙烯三聚的催化剂，其包含（a）具有三角架结构的中性多齿配体的铬络合物，其由式ACrJnQ3-n表示，其中A是具有三脚架结构的中性多齿配体，J是羰基 配体或卤素，n为0-3的整数，Q为选自氢，C1-C10烃基，C1-C10羧酸酯基，C3-C10二酮基，酰胺基，酰胺基， 酰亚胺基，C1-C10烷氧基，C1-C10硫代烷氧基，C6-C15芳烃配体，C2-C10烯配体，C2-C15炔配体，胺配体，亚胺配体，异腈配体， 膦配体，氧化膦配体，亚磷酸酯配体，醚配体，硫化物配体，砜配体和亚砜配体，和（b）金属烷基化合物。 催化剂任选地还包含（c）至少一种选自除了亚胺以外的芳族叔胺化合物和含氮杂环化合物的化合物，和（d）自由基阴离子化合物。

    Process for preparing aromatic olefins in the presence of palladium catalysts comprising phosphite ligands
    50.
    发明授权
    Process for preparing aromatic olefins in the presence of palladium catalysts comprising phosphite ligands 失效
    在含有亚磷酸酯配体的钯催化剂存在下制备芳族烯烃的方法

    公开(公告)号：US06291383B1

    公开(公告)日：2001-09-18

    申请号：US09326404

    申请日：1999-06-04

    Applicant: Alexander Zapf ,  Thomas Riermeier ,  Matthias Beller

    Inventor： Alexander Zapf ,  Thomas Riermeier ,  Matthias Beller

    IPC: B01J3100

    CPC classification number: C07C231/12 ,  C07B37/04 ,  C07C2/861 ,  C07C17/266 ,  C07C41/30 ,  C07C45/68 ,  C07C201/12 ,  C07C2531/02 ,  C07C2531/22 ,  C07C22/08 ,  C07C49/796 ,  C07C233/11 ,  C07C205/56 ,  C07C43/215

    Abstract: The invention relates to process for preparing monofunctional, bifunctional or/and polyfunctional olefins of the formulae (Ia), (Ib), (Ic) or/and (Id), where R1 to R3 are, independently of one another, hydrogen, (C1-C8)-alkyl, CN, COOH, COO-alkyl-(C1-C8), CO-alkyl-(C1-C8), aryl-(C6-C10), COO-aryl-(C6-C10), CO-aryl-(C6-C10), O-alkyl-(C1-C8), O—CO-alkyl-(C1-C8) or N-alkyl2-(C1-C8) and aryl is an aromatic radical containing up to 14 carbon atoms, where aryl is as defined above, and Ar is a heteroaromatic, by reacting haloaromatics, haloolefins or/and heterohaloaromatics of the formulae (IIa), (IIb), (IIc) or/and (IId) with olefins of the formula (III), wherein a mixture of a palladium(0) complex or a palladium(II) salt with phosphite ligands of the formulae (IVa) or/and (IVb) is used as catalyst.

    Abstract translation: 本发明涉及制备式（Ia），（Ib），（Ic）或/和（Id）的单官能，双功能或/和多官能烯烃的方法，其中R 1至R 3彼此独立地为氢，（ C 1 -C 8）烷基，CN，COOH，COO-烷基 - （C 1 -C 8），CO-烷基 - （C 1 -C 8），芳基 - （C 6 -C 10），COO-芳基 - （C 6 -C 10） 芳基 - （C 6 -C 10），O-烷基 - （C 1 -C 8），O-CO-烷基 - （C 1 -C 8）或N-烷基-2-（C 1 -C 8）芳基是芳族基团， 碳原子，其中芳基如上定义，Ar是杂芳族化合物，通式（IIa），（IIb），（IIc）或/和（IId）的卤代芳烃，卤代烯烃或/和杂卤代芳烃与式 （III），其中使用钯（0）配合物或钯（II）盐与式（IVa）或/和（IVb）的亚磷酸酯配体的混合物作为催化剂。

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