公开(公告)号：US3870690A

公开(公告)日：1975-03-11

申请号：US34975573

申请日：1973-04-10

申请人： HOECHST AG

发明人： GORDON WOLFGANG ,  RUST KURT ,  SCHROTT ERWIN

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F15/04 ,  C08F3/02 ,  C08F19/02

CPC分类号： C08F10/00 ,  C08F4/6495 ,  C08F4/6497

摘要： The invention relates to a process for the preparation of olefin polymers using a modified Ziegler-catalyst. As modifiers cyclic dipeptides are used. Polymers are obtained in a high yield having good crystallinity and good color quality.

摘要翻译： 本发明涉及使用改性齐格勒催化剂制备烯烃聚合物的方法。 作为改性剂使用环状二肽。 以高产率获得聚合物，具有良好的结晶度和良好的颜色品质。

公开(公告)号：US3733314A

公开(公告)日：1973-05-15

申请号：US3733314D

申请日：1971-02-03

申请人： PHILLIPS PETROLEUM CO

发明人： MARWIL S ,  HARRISON R

IPC分类号： C08F6/02 ,  C08F3/02 ,  C08F3/08

CPC分类号： C08F6/02 ,  C08L23/02

摘要： CRUDE AMORPHOUS POLYOLEFINS ARE PURIFIED IN A SEQUENTIAL TREATMENT PROCESS WITH A REDUCING TYPE INORGANIC COMPOUND, A POLYPHOSPHATE, AND AN ALCOHOL. THE AMORPHOUS POLYOLEFIN ISRECOVERED AS A SAFE-TO-HANDLE, ESSENTIALLY COLOR-FREE AND CATALYST RESIDUE-FREE, USUAL MATERIAL.

公开(公告)号：US3711457A

公开(公告)日：1973-01-16

申请号：US3711457D

申请日：1971-02-19

申请人： PHILLIPS PETROLEUM CO

发明人： AYRES C

IPC分类号： B01J19/00 ,  C08F2/00 ,  C08F10/00 ,  C08F1/96 ,  C08F3/02 ,  C08F3/06

CPC分类号： B01J19/0006 ,  C08F10/00 ,  Y10T137/0324 ,  Y10T137/0357 ,  Y10T137/0379 ,  C08F2/38

摘要： A FLUID CONTROL SYSTEM IS PROVIDED WHEREBY THE CONTINUOUS TRANSFER OF FLUID FROM A SOURCE LOCATION TO AN ULTIMATE LOCATION IS ACCOMPLISHED WHILE MAINTAINING IN THE SOURCE LOCATION A SUBSTANTIALLY CONSTANT PRESSURE AND WHILE MAINTAINING IN THE ULTIMATE LOCATION A SUBSTANTIALLY CONSTANT TEMPERATURE: BY CONTROLLING THE TRANSFER OF FLUID FROM THE SOURCE LOCATION TO THE ULTIMATE LOCATION IN RESPONSE TO THE PRESSURES IN THE SOURCE LOCATION AND IN THE TRANSFER CONDUIT CONNECTING THE SOURCE LOCATION AND THE ULTIMATE LOCATION; AND BY CONTROLLING THE HEATING OF FLUID IN THE TRANSFER CONDUIT IN RESPONSE TO THE TEMPERATURES IN ULTIMATE LOCATION AND IN THE TRANSFER CONDUIT.

公开(公告)号：US3705885A

公开(公告)日：1972-12-12

申请号：US3705885D

申请日：1969-12-02

申请人： STANDARD OIL CO

发明人： HOLLSTEIN ELMER J ,  HALL LEWIS W JR

IPC分类号： C08F6/04 ,  C08F15/00 ,  C08F1/94 ,  C08F3/02

CPC分类号： C08F6/04

摘要： A PROCESS FOR THE SEPARATION OF ALPHA-OLEFIN POLYMERS HAVING DIFFERENT STERIC STRUCTURES WHICH COMPRISES ADJUSTING THE CONCENTRATION OF A SOLUTION OF AMORPHOUS POLYMER CONTAINING IN SUSPENSION STEREO-REGULAR CRYSTALLINE POLYMER AND SEMICRYSTALLINE STEREOBLOCK POLYMER TO 10-40 WEIGHT PERCENT OF POLYMER, CENTRIFUGING AND RECOVERING A SUBSTANTIALLY PURE STEREOREGULAR POLYMER, AND A SOLUTION OF AMORPHOUS POLYMER CONTAINING IN SUSPENSION STEREOBLOCK POLYMER, ADJUSTING, IF NECESSARY, THE CONCENTRATION OF THE LATTER SOLUTION TO 5-15 WEIGHT PERCENT POLYMER, FILTERING THE SOLUTION TO RECOVER SUBSTANTIALLY PURE STEREOBLOCK POLYMER, AND A FILRATE CONTAINING AMORPHOUS POLYMER, AND RECOVERING SUBSTANTIALLY PURE AMORPHOUS POLYMER FROM THE FILTRATE.

公开(公告)号：US3694423A

公开(公告)日：1972-09-26

申请号：US3694423D

申请日：1971-01-18

申请人： GULF RESEARCH DEVELOPMENT CO

发明人： SMITH WAYNE E ,  BATCHELOR ROBERT L ,  FULK KENNETH J

IPC分类号： B01J3/02 ,  B01J4/00 ,  B01J8/00 ,  B01J19/18 ,  C08F2/00 ,  C08F10/00 ,  C08F1/98 ,  C08F3/02

CPC分类号： B01J4/007 ,  B01J3/02 ,  B01J4/002 ,  B01J8/0015 ,  B01J8/002 ,  B01J19/1837 ,  C08F10/00 ,  Y10S526/919 ,  C08F4/642 ,  C08F4/6495

摘要： In mono 1-olefin and diolefin polymerization processes, an improved method and apparatus for introducing a catalyst slurry into the polymerization zone which comprises pressurizing a catalyst slurry through a first transport zone to a second transport zone and thereafter sweeping the catalyst slurry through the second transport zone to the polymerization zone.

公开(公告)号：US3691144A

公开(公告)日：1972-09-12

申请号：US3691144D

申请日：1970-09-17

申请人： ERNEST A ZUECH ,  PHILLIPS PETROLEUM CO

发明人： ZUECH ERNEST A

IPC分类号： B01J31/14 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  B01J31/26 ,  C07C6/04 ,  C08F10/00 ,  C08F3/02 ,  C08F15/04

CPC分类号： B01J31/2295 ,  B01J31/143 ,  B01J31/181 ,  B01J31/2226 ,  B01J31/2404 ,  B01J2231/543 ,  B01J2531/64 ,  B01J2531/66 ,  C07C6/04 ,  C08F10/00 ,  Y10S585/94 ,  C08F4/69

摘要： A process for the conversion of olefinic hydrocarbons according to the olefin reaction (e.g., the olefin disproportionation reaction) by contacting the olefinic hydrocarbon with a catalyst comprising a coordination compound of molybdenum or tungsten complexed with NO, together with an organoaluminum adjuvant.

摘要翻译： 通过使烯烃与包含与NO络合的钼或钨的配位化合物的催化剂与有机铝佐剂接触，根据烯烃反应（例如烯烃歧化反应）转化烯烃的方法。

公开(公告)号：US3689471A

公开(公告)日：1972-09-05

申请号：US3689471D

申请日：1968-08-26

申请人： GOODYEAR TIRE & RUBBER

发明人： JUDY WILLIAM ALLEN

IPC分类号： C08F2/00 ,  C08F4/12 ,  C08F4/42 ,  C08F10/00 ,  C08G61/08 ,  C08F1/28 ,  C08F3/02 ,  C08F15/04

CPC分类号： C08F4/69 ,  C08G61/08

摘要： A METHOD FOR THE RING OPENING POLYMERIZATION OF UNSATURATED ALICYCLIC COMPOUNDS CONTAINING AT LEAST 4 AND NOT MORE THAN 5 CARBON ATOMS AND ONE DOUBLE BOND IN THE CYCLIC RING AND UNSATURATED ALICYCLIC COMPOUNDS CONTAINING AT LEAST 8 CARBON ATOMS AND AT LEAST ONE DOUBLE BOND IN THE CYCLIC RING IS DISCLOSED WHICH COMPRISES SUBJECTING SUCH UNSATURATED ALICYCLIC COMPOUNDS TO A CATALYST SYSTEM COMPRISING (A) A TUNGSTEN OR MOLYBDENUM HALIDE OR OXYHALIDE, (B) AT LEAST ONE LEWIS ACID OF THE FORMULA MXN WHERE M IS A METAL REPRESENTED BY ALUMINUM, ZINC, GALLIUM, TIN AND ANTIMONY; X IS A HALOGEN SUCH AS BROMINE, CHLORINE, IODINE AND FLUORINE AND N IS AN INTEGER EQUAL TO THE VALENCE OF M AND (C) A REFUCING AGENT SELECTED FROM THE GROUP CONSISTING OF METALS, METAL HYDRIDES, ALKYL SECONDARY AMINES, ALKYL TERTIARY AMINES, SATURATED ALKYL ALCOHOLS, ALKYL PHOSPHINES AND HYDROGEN.

公开(公告)号：US3687920A

公开(公告)日：1972-08-29

申请号：US3687920D

申请日：1971-01-25

申请人： UNION CARBIDE CORP

发明人： JOHNSON ROBERT N

IPC分类号： C08F4/58 ,  C08F10/00 ,  C08F1/44 ,  C08F3/02 ,  C08F15/04

CPC分类号： C08F10/00 ,  Y10S526/901 ,  Y10S526/905 ,  C08F4/78

摘要： Silane compounds of the structure H3Si(SiH2)mH and R4 nSiHn wherein m is 0 to 3 inclusive, n is 0 to 3 inclusive and R is C1 to C10 hydrocarbon are used with supported bis(cyclopentadienyl)chromium (II) catalysts for the polymerization of olefins in order to improve the productivity of the catalyst.

摘要翻译： 与负载的双（环戊二烯基）铬[II]催化剂一起使用结构H3Si [SiH2] mH和R4-nSiHn的硅烷化合物，其中m为0-3，包括端值，n为0-3，并且R为C1至C10烃。 烯烃的聚合以提高催化剂的生产率。

公开(公告)号：US3658780A

公开(公告)日：1972-04-25

申请号：US3658780D

申请日：1969-10-22

申请人： PHILLIPS PETROLEUM CO

发明人： SCOGGIN JACK S

IPC分类号： C08F10/00 ,  C08F3/02 ,  C08F3/08

CPC分类号： C08F10/00 ,  C08F110/06 ,  Y10S526/912 ,  C08F4/642 ,  C08F10/06 ,  C08F2/00

摘要： IN THE POLYMERIZATION OF AN OLEFIN, E.G., PROPYLENE, EMPLOYING HYDROGEN AS A MODIFIER IN THE POLYMERIZATION REACTION AND EXCESS MONOMER AS SOLVENT TO PRODUCE A DESIRED MELT INDEX POLYMER, RECYCLED UNPOLYMERIZED OR EXCESS MONOMER IS COMPLETELY FREED OF HYDROGEN BY FRACTIONATION OF THE RECOVERED MONOMER STREAM BY SUBMITTING THE SAME TO A DEGASSING OPERATION IN WHICH IN THE PREFERRED MODE OF OPERATION THE STREAM IS HEATED IN A FRACTIONATION ZONE TO EXPEL HYDROGEN THEREFROM AND THE OVERHEAD IS REFRIGERATED TO AVOID UNDUE LOSS OF MONOMER AND ALL OF THE MODIFIER HYDROGEN IS ADDED TO THE POLYMERIZATION REACTION FROM A SINGLE SOURCE.

公开(公告)号：US3647923A

公开(公告)日：1972-03-07

申请号：US3647923D

申请日：1968-07-15

申请人： GULF RESEARCH DEVELOPMENT CO

发明人： HAZEN STANLEY M ,  HEILMAN WILLIAM J

IPC分类号： C08K5/13 ,  C08F3/02 ,  C08F15/02 ,  C08F15/04

CPC分类号： C08K5/13 ,  C08L35/00 ,  C08L23/20

摘要： THE SHELF LIFE OF A LIQUID CURABLE RESIN SYSTEM IS INCREASED BY THE ADDITION OF A HINDERED PHENOL, SUCH AS 2,6DITERTIARYBUYLPHENOL OR 2,6-DITERTIARYBURTYL-P-CRESOL. THE LIQUID CURABLE RESIN SYSTEM COMPRISES A COPOLYMER OF MALEIC ANHYDRIDE AND AN ALPHA-OLEFIN SUCH AS HEXENE-1; A LIQUID UNSATURATED MONOEPOXIDE SUCH AS GLYCIDYL ACRYLATE OR GLYCIDYL METHACRYALTE; AND STYRENE. THE SYSTEM PREFERABLY CONTAINS LESS THAN 10 P.P.M. OF WATER.