公开(公告)号：US4945036A

公开(公告)日：1990-07-31

申请号：US359304

申请日：1989-05-31

申请人： Naoki Arai ,  Kazuo Kagawa

发明人： Naoki Arai ,  Kazuo Kagawa

IPC分类号： G03C1/12 ,  G03C1/005 ,  G03C1/035 ,  G03C1/18 ,  G03C1/26

CPC分类号： G03C1/26 ,  G03C1/0051 ,  G03C1/18 ,  G03C2001/03564 ,  G03C2001/0357 ,  G03C2001/03594 ,  G03C2007/3025 ,  Y10S430/167

摘要： A silver halide photosensitive material is described, comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of the said monodisperse silver halide emulsions has an average grain size of at least 0.7 .mu.m, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 .mu.m, with a coated silver weight of from 2.3 to 3.8 g/m.sup.2, and which contains a sensitizing dye represented by formula (I) ##STR1## wherein Z and Z.sub.1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R.sub.0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R.sub.1 each represents an alkyl group or an aryl group; L, L.sub.1, and L.sub.2 each represents a methine group; X represents an anion; and m represents 0 or 1, and an internal salt is formed when m is 0.

摘要翻译： 描述了卤化银感光材料，其包含两种或更多种不同平均粒径的单分散卤化银乳剂，其中至少一种所述单分散卤化银乳剂具有至少0.7μm的平均粒径，并且在 卤化银乳剂中的至少一种具有比另一种更小的平均粒径，卤化银乳剂的平均粒径整体在0.33至0.54μm的范围内，涂层银的重量为2.3至 3.8g / m2，其中含有由式（I）表示的增感染料，其中Z和Z1各自表示一组形成噻唑核的非金属原子，苯并噻唑核或苯并恶唑核; R 0表示具有1〜6个碳原子的烷基，烯丙基或芳烷基; R和R 1各自表示烷基或芳基; L，L1和L2各自表示次甲基; X表示阴离子; m表示0或1，当m为0时，形成内部盐。

公开(公告)号：US4894323A

公开(公告)日：1990-01-16

申请号：US53673

申请日：1987-05-26

申请人： Kiyoshi Kawai ,  Mikio Ihama

发明人： Kiyoshi Kawai ,  Mikio Ihama

IPC分类号： G03C1/08 ,  G03C1/043 ,  G03C1/06 ,  G03C1/12 ,  G03C1/18

CPC分类号： G03C1/043 ,  G03C1/12 ,  G03C1/18

摘要： A novel silver halide photographic material is provided comprising a support having provided thereon at least one silver halide emulsion layer and containing at least one polyoxyethylenic compound in the emulsion layer or at least one other hydrophilic colloid layer, wherein silver halide grains contained in the emulsion layer are chemically sensitized in the presence of a water-soluble sensitizing dye having a solubility in 20.degree. C. water of 0.2 g/100 ml H.sub.2 O or more, or said water-soluble sensitizing dye is added to the silver halide emulsion after chemical sensitization and before coating. Such a water-soluble sensitizing dye is preferably selected from methine dyes and styryl dyes such as a cyanine dye, a merocyanine dye, a hemicyanine dye, a rhodacyanine dye, an oxonol dye, and a hemioxonol dye.

摘要翻译： 提供了一种新颖的卤化银照相材料，其包括其上设置有至少一个卤化银乳剂层并且在乳剂层或至少一个其它亲水胶体层中含有至少一种聚氧化烯化合物的载体，其中包含在乳剂层中的卤化银颗粒 在水溶性为0.2g / 100ml H2O或以上的水溶性的水溶性增感染料的存在下进行化学增感，或者化学增感后将所述水溶性增感染料加入到卤化银乳剂中， 涂层前。 这样的水溶性敏化染料优选选自次甲基染料和苯乙烯基染料，例如花青染料，部花青染料，半花青染料，多花青素染料，氧杂菁染料和半氧杂醇染料。

公开(公告)号：USH674H

公开(公告)日：1989-09-05

申请号：US116229

申请日：1987-11-03

申请人： Satoru Nagasaki ,  Akio Suzuki ,  Eiji Yoshida ,  Masumi Arai ,  Nobuaki Tsuji

发明人： Satoru Nagasaki ,  Akio Suzuki ,  Eiji Yoshida ,  Masumi Arai ,  Nobuaki Tsuji

IPC分类号： B05C5/00 ,  B05C9/04 ,  G03C1/005 ,  G03C1/18 ,  G03C1/38 ,  G03C1/46 ,  G03C1/74 ,  G03C1/95 ,  G03C5/16

CPC分类号： G03C5/16 ,  B05C5/007 ,  B05C9/04 ,  G03C1/005 ,  G03C1/18 ,  G03C1/38 ,  G03C1/46 ,  G03C1/74 ,  G03C1/95 ,  G03C2001/7425 ,  G03C2200/52

摘要： A silver halide photographic light-sensitive material comprising a support having the first photographic structural layer comprising one or more layers on a side of the support and the second photographic structural layer comprising one or more layers on the other side of the support, in which at least one of the photographic structural layers comprises a silver halide light-sensitive emulsion layer, and the total amount of gelatin contained in the photographic structural layer comprising the silver halide emulsion layer is within the range of from 2.25 g/m.sup.2 to 3.15 g/m.sup.2. The uppermost layer of the photographic structural layer comprising the silver halide emulsion is formed by coating of a solution having a surface tension of from 15 to 26 dyn/cm, and the second photographic structural layer is coated and gelled simultaneously with coating and drying of the first photographic structural layer. The photographic material is improved in the adaptability for super-rapid processing with the total duration of 20 to 60 sec. and the anti-scratch property.

公开(公告)号：US4830958A

公开(公告)日：1989-05-16

申请号：US147691

申请日：1988-01-25

申请人： Mitsuhiro Okumura ,  Keiji Ohbayashi ,  Shigeo Tanaka

发明人： Mitsuhiro Okumura ,  Keiji Ohbayashi ,  Shigeo Tanaka

IPC分类号： G03C1/035 ,  G03C1/06 ,  G03C1/08 ,  G03C1/18 ,  G03C7/388 ,  G03C7/392

CPC分类号： G03C1/035 ,  G03C1/08 ,  G03C7/39296 ,  G03C1/18 ,  G03C2001/03511 ,  G03C2001/03517 ,  G03C2200/33 ,  G03C2200/40 ,  G03C7/3885

摘要： A photographic material having an excellent rapid processability, a high sensitivity and a less sensitivity variation due to a change of standing of the silver halide emulsion in the course of preparation of the light-sensitive material, and its preparation process are disclosed. The silver halide photographic light-sensitive material comprises a support bearing at least one silver halide emulsion layer thereon, and at least one silver halide emulsion layer contains highly chloride-containing silver halide grains having a silver chloride content of not less than 90 mol %, a water-soluble bromide of from 0.05 mol % to 2 mol % per mol of silver halide and a high boiling organic solvent having a dielectric constant of not higher than 6.0.

公开(公告)号：US4806461A

公开(公告)日：1989-02-21

申请号：US165085

申请日：1988-03-07

申请人： Hideo Ikeda ,  Munehisa Fujita ,  Shingo Ishimaru ,  Hiroshi Ayato ,  Shigeharu Urabe

发明人： Hideo Ikeda ,  Munehisa Fujita ,  Shingo Ishimaru ,  Hiroshi Ayato ,  Shigeharu Urabe

IPC分类号： G03C1/035 ,  G03C1/005 ,  G03C1/18 ,  G03C1/02

CPC分类号： G03C1/0051 ,  G03C1/18

摘要： A silver halide emulsion comprises a dispersion medium and silver halide grains, the silver halide emulsion containing tabular silver halide grains having a thickness of less than 0.5 .mu.m, a diameter of 0.3 .mu.m or more, and a mean diameter-to-thickness ratio of 2 or more. The tabular grains occupy at least 50% of a projected area of all the silver halide grains, and 50% or more (number) of the tabular grains include 10 or more dislocations per grain. A photographic light-sensitive material comprises the aforementioned silver halide emulsion.

公开(公告)号：US4789626A

公开(公告)日：1988-12-06

申请号：US940839

申请日：1986-12-12

申请人： Kei Sakanoue ,  Shinzo Kishimoto ,  Tadashi Ikeda

发明人： Kei Sakanoue ,  Shinzo Kishimoto ,  Tadashi Ikeda

IPC分类号： G03C7/38 ,  G03C1/18 ,  G03C7/327 ,  G03C11/00 ,  G03C7/00 ,  G03C1/08 ,  G03C7/32 ,  G03C7/40

CPC分类号： G03C1/18 ,  G03C7/3275

摘要： A method for processing a silver halide color photographic material by fixing or bleach-fixing the material and immediately thereafter subjecting it to washing or stabilization, wherein (A) the silver halide color photographic material contains at least one of sensitizing dyes represented by the formulae (I) and (II) specified in the specification and at least one two-equivalent magenta polymer coupler which is derived from a specified monomer coupler, and (B) the amount of a replenisher in the washing step and/or the stabilization step falls within the range of 3 to 50 times, based on unit area of the material after being processed, the amount of each processing solution having been carried over from the preceding bath.

摘要翻译： 一种通过固定或漂白固定材料并立即进行洗涤或稳定处理卤化银彩色照相材料的方法，其中（A）卤化银彩色照相材料含有至少一种由式 I）和（II）和由特定单体成色剂衍生的至少一种二等价品红色聚合物成色剂，和（B）洗涤步骤和/或稳定步骤中补充剂的量落入 基于处理后的材料的单位面积的3〜50倍的范围，从前一个浴中移出的各处理液的量。

公开(公告)号：US4722884A

公开(公告)日：1988-02-02

申请号：US757973

申请日：1985-07-23

申请人： Nobuaki Inoue ,  Senzo Sasaoka ,  Kenichi Kuwabara ,  Kimitaka Kameoka

发明人： Nobuaki Inoue ,  Senzo Sasaoka ,  Kenichi Kuwabara ,  Kimitaka Kameoka

IPC分类号： G03C1/035 ,  G03C1/06 ,  G03C1/16 ,  G03C1/18 ,  G03C5/29 ,  G03C5/24 ,  G03C1/02

CPC分类号： G03C1/035 ,  G03C1/061 ,  G03C1/16 ,  G03C1/18 ,  G03C2001/03535 ,  G03C2001/03558 ,  G03C2200/06 ,  Y10S430/15

摘要： A negative silver halide photographic light-sensitive material is provided, having a silver halide emulsion layer, which layer comprises silver haloiodide grains prepared in the presence of an iridium salt in an amount of 1.times.10.sup.-8 to 1.times.10.sup.-5 mole per one mole of silver, wherein the silver iodide content in the surface part of said grain is larger than the average silver iodide content in said grain, and additionally containing in said emulsion layer or in some other hydrophilic colloid layer, a compound of formula (I):R.sub.1 --NHNH--CHO (I)wherein R.sub.1 represents an aliphatic group or an aromatic group. Said photographic light-sensitive material is, after being exposed imagewise, developed with a developer containing 0.15 mole/l or more sulfite ion and having a pH value of 9.5-12.3, to form negative images having ultra-high contrast. The present photographic light-sensitive material has good photographic characteristics of sensitivity and gamma value, and the preservation stability thereof is good.

摘要翻译： 提供负卤化银照相感光材料，其具有卤化银乳剂层，该层包含在铱盐存在下制备的碘卤化银颗粒，其量为每摩尔银1×10-8至1×10-5摩尔 其中所述晶粒的表面部分中的碘化银含量大于所述晶粒中的平均碘化银含量，并且还包含在所述乳剂层或一些其它亲水胶体层中的式（I）化合物：R1- NHNH-CHO（I）其中R1表示脂族基团或芳族基团。 所述照相感光材料在成像曝光后，用含有0.15摩尔/升以上亚硫酸根离子并且pH值为9.5-12.3的显影剂显影，形成具有超高对比度的负像。 本照相感光材料具有良好的感光度和γ值的照相特性，其保存稳定性良好。

公开(公告)号：US4675279A

公开(公告)日：1987-06-23

申请号：US758622

申请日：1985-07-24

申请人： Sadanobu Shuto ,  Toshinao Ukai ,  Shunichi Aida

发明人： Sadanobu Shuto ,  Toshinao Ukai ,  Shunichi Aida

IPC分类号： G03C1/005 ,  G03C1/035 ,  G03C1/18 ,  G03C1/28 ,  G03C1/02 ,  G03C7/26

CPC分类号： G03C1/18 ,  G03C1/28

摘要： A silver halide photographic light-sensitive material is described, which comprises a support having thereon at least one layer comprising a silver halide emulsion containing tabular silver halide particles wherein at least 50% of the total projected area of silver halide particles contained in the silver halide emulsion in said at least one layer is occupied by the tabular silver halide particles having an average aspect ratio of 5:1 or more, and wherein said silver halide emulsion contains a compound represented by general formula (I) or (II): ##STR1## wherein a is an integer of 1 to 8;R.sub.1, R.sub.2 and R.sub.3, which are the same or different, each represents a group of the formula --CH.sub.2 (CF.sub.2).sub.b H or a substituted or unsubstituted alkyl group, with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 has an acid radical;b, which is the same as or different from a, is an integer of 1 to 8;l is 0 or an integer of 1 to 8; m is 0 or an integer of 1 to 8; with the proviso that l+m>0;R.sub.4, R.sub.5 and R.sub.6, which are the same or different, each represents a group of the formula --(CH.sub.2).sub.j (CF.sub.2).sub.k F or a substituted or unsubstituted alkyl group, with the proviso that at least one or R.sub.4, R.sub.5 and R.sub.6 has an acid radical;j is 0 or an integer of 1 to 8; k is 0 or an integer of 1 to 8; with the proviso that j+k>0;V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7 and V.sub.8, which are the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group or a trifluoromethyl group;X is an anion; andn is 1 to 2; with the proviso that when said compound forms an internal salt, n is 1.

摘要翻译： 描述了一种卤化银照相感光材料，其包括其上具有至少一层包含含有片状卤化银颗粒的卤化银乳剂的载体的载体，其中卤化银颗粒中包含的卤化银颗粒总投影面积的至少50％ 所述至少一层中的乳液被具有5:1或更高的平均纵横比的片状卤化银颗粒占据，并且其中所述卤化银乳剂含有由通式（I）或（II）表示的化合物： 0; R 4，R 5和R 6相同或不同，各自表示式 - （CH 2）j（CF 2）k F或取代或未取代的烷基的基团，条件是至少一个或R 4，R 5和R 6 有酸根; j为0或1〜8的整数; k为0或1〜8的整数， 条件是j + k> 0; V1，V2，V3，V4，V5，V6，V7和V8各自表示氢原子，卤素原子，取代或未取代的烷基，烷氧基，酰基，酰氧基 烷氧基羰基，氨基甲酰基，氨磺酰基，氰基或三氟甲基; X是阴离子; n为1〜2; 条件是当所述化合物形成内盐时，n为1。

公开(公告)号：US4555481A

公开(公告)日：1985-11-26

申请号：US573760

申请日：1984-01-25

申请人： Toshinao Ukai ,  Masaki Okazaki ,  Haruo Takei ,  Ichizo Toya

发明人： Toshinao Ukai ,  Masaki Okazaki ,  Haruo Takei ,  Ichizo Toya

IPC分类号： G03C1/18 ,  G03C7/26 ,  G03C1/10 ,  G03C7/32

CPC分类号： G03C1/18

摘要： A silver halide photographic emulsion is disclosed which contains at least one of benzimidazolocarbocyanine dyes represented by the general formula (I) or (II): ##STR1## wherein a represents an integer of 1 to 8, R.sub.1, R.sub.2 and which may be identical with or different from one another, represent each --CH.sub.2 (CF.sub.2).sub.b H or a substituted or unsubstituted alkyl group, but at least one of R.sub.1, R.sub.2 and R.sub.3 contains an acid group-containing alkyl group, wherein b, which may be identical with or different from a, represents an integer of 1 to 8, l represents 0 or an integer of 1 to 8, and m represents 0 or an integer of 1 to 8, but l+m>0; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different from one another, represent each --(CH.sub.2).sub.j (CF.sub.2).sub.k F or a substituted or unsubstituted alkyl group, but at least one of R.sub.4, R.sub.5 and R.sub.6 represents an acid group (for example, sulfo group or carboxyl group, etc.)-containing alkyl group; j represents 0 or an integer of 1 to 8; and k represents 0 or an integer of 1 to 8, but j+k>0; V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7 and V.sub.8, which may be identical with or different from one another, represent each a hydrogen atom, a halogen atom, a substituted alkyl group, an unsubstituted alkyl group, an alkoxy group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group or a trifluoromethyl group; X represents an anion; and n represents 1 or 2 but represents 1 when the dye forms an inner salt.The emulsion has good stability to the passage of time, in which an increase of fog under a high temperature or under a high temperature and a high humidity is controlled and reduction of sensitivity with the passage of time is minimized.

摘要翻译： 公开了一种卤化银照相乳剂，其含有由通式（I）或（II）表示的苯并咪唑并花青染料中的至少一种：其中a表示1至8的整数， R1，R2可以相同或不同，表示每个-CH2（CF2）bH或取代或未取代的烷基，但R1，R2和R3中的至少一个含有含酸基团的烷基， 其中可以与a相同或不同的b表示1〜8的整数，l表示0或1〜8的整数，m表示0或1〜8的整数，但l + m> 0 ; 可以相同或不同的R 4，R 5和R 6表示 - （CH 2）j（CF 2）k F或取代或未取代的烷基，但R 4，R 5和R 6中的至少一个表示酸基 例如磺基或羧基等）的烷基; j表示0或1〜8的整数， k表示0或1〜8的整数，而j + k> 0。 V1，V2，V3，V4，V5，V6，V7和V8可以相同或不同，表示氢原子，卤素原子，取代的烷基，未取代的烷基，烷氧基 酰基，酰氧基，烷氧基羰基，氨基甲酰基，氨磺酰基，氰基或三氟甲基; X表示阴离子; 而n代表1或2，当染料形成内盐时，它代表1。 该乳液在时间上具有良好的稳定性，其中控制在高温或高温和高湿度下的雾的增加，并且随着时间的推移降低灵敏度。

公开(公告)号：US4490463A

公开(公告)日：1984-12-25

申请号：US471615

申请日：1983-03-03

申请人： David P. Gilbert

发明人： David P. Gilbert

IPC分类号： C09B23/00 ,  C09B23/04 ,  G03C1/12 ,  G03C1/18 ,  G03C1/26 ,  G03C1/02

CPC分类号： G03C1/12 ,  C09B23/00 ,  C09B23/04 ,  G03C1/26

摘要： Alkanediyl bridged benzimidazolo monomethine cyanine dyes are disclosed wherein at least one benzimidazolo nucleus is provided with an electron-withdrawing group. A disclosed preparation of the dyes includes producing an electron-withdrawing group substituted bis(2-nitrophenyl)-2-R.sup.1 -propanediamide, where R.sup.1 is hydrogen or alkyl; converting the nitro groups to primary amine substituents; removing the elements of water to effect ring closure; and thereafter providing the -CR.sup.1 - linked benzimidazole nuclei so formed with an N,N'-alkanediyl bridging group and quaternizing substituents. Dye synthesis is completed by reducing the -CR.sup.1 - linking group to the corresponding methine. The dyes are useful as sensitizers in silver halide emulsions and photographic elements.

摘要翻译： 公开了烷烃基桥联的苯并咪唑单甲氰基染料，其中至少一个苯并咪唑核具有吸电子基团。 所公开的染料的制备包括制备吸电子基团取代的双（2-硝基苯基）-2-R 1 - 丙二酰胺，其中R 1是氢或烷基; 将硝基转化为伯胺取代基; 去除水分的元素以实现闭环; 然后提供与N，N'-烷二基桥连基团和季铵化取代基形成的-CR1-连接的苯并咪唑核。 通过将-CR1-连接基团还原成相应的次甲基来完成染料合成。 这些染料可用作卤化银乳剂和照相元件中的敏化剂。