Abstract:
Disclosed is a process for manufacturing an aluminum support for a planographic printing plate material, the process comprising the steps of electrolytically surface-roughening an aluminum plate in an electrolytic solution, employing a sinewave alternating current; and anodizing the surface-roughened aluminum plate, the electrolytically surface-roughening step comprising a first stage of electrolytically surface-roughening the aluminum plate in a first electrolytic solution containing hydrochloric acid as a main component at a current density of D1 for t1 at a quantity of electricity of Q1 and a second stage of electrolytically surface-roughening the aluminum plate in a second electrolytic solution containing hydrochloric acid as a main component at a current density of D2 for t2 at a quantity of electricity of Q2.
Abstract:
Initiator system comprising: (a) at least one substance capable of absorbing IR radiation, (b) at least one compound capable of forming free radicals, and (c) at least one 1,4-dihydropyridine derivative of the formula (I)
Abstract:
A lithographic printing plate precursor, which comprises: a support; an image-recording layer; and a protective layer, in this order, wherein at least one of the image-recording layer and the protective layer comprises a phosphonium salt having a specific structure, and a lithographic printing process, which comprises: exposing a lithographic printing plate precursor; supplying an oil-based ink and a fountain solution comprising a phosphonium salt having a specific structure to the exposed lithographic printing plate precursor on a printing machine to remove an unexposed area of an image-recording layer; and conducting printing.
Abstract:
A manufacturing method of a lithographic printing plate, which comprises: imagewise exposing a lithographic printing plate precursor comprising a support and an image-recording layer; and removing a non-image area of the image-recording layer in a development processing tank that has a reservoir of a first aqueous solution having pH of from 2 to 10 by rubbing the non-image area with at least one rubbing member in a state of being immersed in the reservoir of the first aqueous solution, wherein the removal of the non-image area with the at least one rubbing member is carried out after an elapse of 2 seconds or more from an immersion in the reservoir of the first aqueous solution.
Abstract:
A radical polymerizable composition comprising (A) an alkali-soluble resin containing a radical polymerizable group, (B) a radical polymerizable compound, and (C) a radical initiator, wherein reactivity of a polymerizable group of the polymerizable compound 4B) to a polymerizable group of the polymerizable compound (B) is larger than reactivity of a polymerizable group of the polymerizable compound (B) to a radical polymerizable group of the alkali-soluble resin (A), and a reactivity of a radical polymerizable group of the alkali-soluble resin (A) to a polymerizable group of the polymerizable compound (B) is larger than reactivity of a radical polymerizable group of the alkali-soluble resin (A) to a radical polymerizable group of the alkali-soluble resin (A).
Abstract:
A photosensitive lithographic printing plate comprising: an aluminum support; a photopolymerizable photosensitive layer; and an oxygen blocking layer in this order, wherein the photopolymerizable photosensitive layer contains (1) a polyurethane binder, (2) a polymerizable compound having a urethane bond and two ethylenically unsaturated bonds, (3) a polymerizable compound having a urethane bond and four or more ethylenically unsaturated bonds, and (4) a photopolymerization initiator.
Abstract:
A presensitized plate comprising a support for a lithographic printing plate including an anodized layer formed on an aluminum plate and a recording layer recordable by infrared laser exposure on the support, wherein in a section of the anodized layer after the recording layer is provided, an atomicity ratio of carbon to aluminum (C/Al) represented by Auger Electron Spectroscopic analysis is 1.0 or less. In the case of being used as an on-machine development type, it exhibits a good on-machine development characteristic, a high sensitivity, a high press life, and high scum resistance during printing and while left (ink discharging). In the case of being used as a conventional thermal positive or negative working type, it exhibits an efficient use of heat for image formation, a high sensitivity, a high press life, and a slight possibility of scum occurrence at non-image areas.
Abstract:
A polymer, which contains a structural unit having a carboxyl group represented by the following formula (1) at a side chain of the structural unit, wherein no deposition is formed, when the polymer is dissolved in an alkali aqueous solution having a pH of 10 or more and kept at 25° C. for 60 days: wherein R1 represents a hydrogen atom or a methyl group; R2 represents an (n+1)-valent organic linking group containing an ester group represented by —O(C═O)—; A represents an oxygen atom or NR3—; R3 represents a hydrogen atom, or an monovalent hydrocarbon group having from 1 to 10 carbon atoms; and n indicates an integer of from 1 to 5.
Abstract translation:在聚合物溶解在pH为10的碱性水溶液中的情况下,在结构单元的侧链含有具有下述式(1)表示的羧基的结构单元的聚合物,其中没有形成沉积物 或更高,并保持在25℃下60天:其中R 1表示氢原子或甲基; R 2表示含有由-O(C-O) - 表示的酯基的(n + 1)价有机连接基团; A表示氧原子或NR 3 - ; R 3表示氢原子或具有1至10个碳原子的一价烃基; n表示1〜5的整数。
Abstract:
This invention provides a support for a lithographic printing plate, and an original form of a heat-sensitive lithographic printing plate, which comprises a hydrophilic film formed on a metallic base whose surface has been roughened, said hydrophilic film having a heat conductivity of 0.05–0.5 W/(m·K) in the direction of its film thickness, which when used as the development on machine type, exhibits good on-press, or good non-treatment developability, a high sensitivity, a long press life and a preferable stain resistance and ink removal property upon printing and which, when used as a conventional thermal positive or negative type, makes efficient utilization of heat for the formation of image, has a high sensitivity and exhibits a long press life and a good stain resistance in a nonimage area, wherein the non-treatment in which the development is not performed.
Abstract:
The invention discloses a positive photosensitive composition comprising (A) a compound represented by the following formula (1) which is decomposed by exposure to light to generate an acid, (B) a high-molecular compound having a phenolic hydroxyl group and (C) an infrared-light absorber. The invention also provides a positiveplanographic printing plate precursor using this photosensitive composition for the recording layer. In the formula, R represents an alkyl, cycloalkyl, aralkyl or aryl group having an acid group, Y represents a bivalent to tetravalent connecting group having at least one partial structure selected from the following group of partial structures or a terminal group selected from one of the partial structures and a terminal hydrogen atom, and Z does not exist when Y is a terminal group, but represents a monovalent to tetravalent connecting group or terminal group when Y is a connecting group.