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    Microbicidal composition
    51.
    发明授权
    Microbicidal composition 失效
    杀菌组合物

    公开(公告)号：US4207338A

    公开(公告)日：1980-06-10

    申请号：US39011

    申请日：1979-05-11

    申请人： Wolfgang Eckhardt ,  Walter Kunz ,  Adolf Hubele

    发明人： Wolfgang Eckhardt ,  Walter Kunz ,  Adolf Hubele

    IPC分类号： A01N37/44 ,  A01N37/22 ,  A01N37/46 ,  C07C67/00 ,  C07C241/00 ,  C07C243/14 ,  C07C243/18 ,  C07C243/22 ,  A61K31/24 ,  C07C101/447

    CPC分类号： C07C243/00 ,  A01N37/46

    摘要： Hydrazino-acetanilide derivatives of the formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,R.sub.2 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,R.sub.3 is hydrogen, C.sub.1 -C.sub.3 alkyl or halogen,R.sub.4 is hydrogen or methyl, with the total number of C atoms of the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 in the phenyl ring not exceeding 6,R.sub.5 is C.sub.1 -C.sub.5 alkyl which is unsubstituted or substituted by halogen, or it is phenyl which is unsubstituted or substituted by methyl, nitro and/or halogen, or it is the benzyl group, andR.sub.6 is hydrogen or C.sub.1 -C.sub.5 alkyl,possess valuable microbicidal properties, and contained in appropriate compositions these derivatives can be used in particular for combating phytopathogenic fungi.

    摘要翻译： 式I的肼基 - 乙酰苯胺衍生物其中R 1是C 1 -C 4烷基，C 1 -C 4烷氧基或卤素，R 2是C 1 -C 3烷基，C 1 -C 4烷氧基或卤素，R 3是氢，C 1 -C 3 烷基或卤素，R 4为氢或甲基，苯环中取代基R 1，R 2，R 3和R 4的C原子总数不超过6，R 5为未被取代或被卤素取代的C 1 -C 5烷基，或 它是未取代的或被甲基，硝基和/或卤素取代的苯基，或它是苄基，R6是氢或C1-C5烷基，具有有价值的杀微生物性质，并且包含在合适的组合物中，这些衍生物可以用于 特别用于防治植物病原真菌。

    Azinyliminodithietanes and their fungicidal and nematocidal methods of use
    52.
    发明授权
    Azinyliminodithietanes and their fungicidal and nematocidal methods of use 失效
    Azinyl亚基二环己烷及其杀真菌剂和杀线虫剂的使用方法

    公开(公告)号：US5190945A

    公开(公告)日：1993-03-02

    申请号：US794537

    申请日：1991-11-19

    申请人： Wolfgang Eckhardt ,  Urs Muller

    发明人： Wolfgang Eckhardt ,  Urs Muller

    IPC分类号： A01N43/54 ,  A01N43/60 ,  C07D409/12

    CPC分类号： C07D409/12 ,  A01N43/54 ,  A01N43/60

    摘要： 2-(Pyrimidyl or pyrazinyl)-imino-1,3-dithietanes ##STR1## wherein Ar is one of the radicals ##STR2## R is unsubstituted C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is substituted by halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio or cyano, independently of one another, or is unsubstituted or halo-substituted C.sub.3 -C.sub.7 alkenyl, unsubstituted or halo-substituted C.sub.3 -C.sub.7 alkynyl, or C.sub.3 -C.sub.5 cycloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylamino, nitro or halogen,n is a number from 0 to 3,X.sub.1 and X.sub.2 independently of each other are hydrogen or halogen, including the addition salts formed with acids of the formula H.sup..sym. X.sup..crclbar. in which the anion X.sup..crclbar. is Cl.sup..crclbar., Br.sup..crclbar., I.sup..crclbar., HSO.sub.4 -, H.sub.2 PO.sub.4 -, H.sub.2 PO.sub.3 -, NO.sub.3 -, CH.sub.3 COO.sup..crclbar., CH.sub.2 ClCOO-, CF.sub.3 COO-, HOCH.sub.2 COO-, CH.sub.3 CH(OH)COO.sup..crclbar., HOOCCOO.sup..crclbar., HOOCCH.sub.2 COO.sup..crclbar., HOOCCH.dbd.CHCOO.sup..crclbar., ##STR3## a process for the preparation of the compounds of formula I, and novel intermediates of the preparation process are described.The compounds of formula I have nematicidal and fungicidal properties. Nematicidal and fungicidal compositions that contain at least one compound of formula I as active ingredient, and also methods of using the compounds and the compositions in the control of nematodes and fungi, are described.

    摘要翻译： 2-（嘧啶基或吡嗪基） - 亚氨基-1,3-二硫代环己基（I）其中Ar是基团之一R是未被取代的C 1 -C 3烷基或被卤素取代的C 1 -C 3烷基， C 1 -C 3烷基，C 1 -C 3烷氧基，C 1 -C 3烷硫基或氰基，彼此独立地是未取代的或卤素取代的C 3 -C 7链烯基，未取代或卤素取代的C 3 -C 7炔基或C 3 -C 5环烷基，C 1 -C 3烷氧基， C 3烷基氨基，硝基或卤素，n为0至3的数，X 1和X 2彼此独立地为氢或卤素，包括与式H（+）X（ - ）的酸形成的加成盐，其中阴离子X （ - ）为Cl（ - ），Br（ - ），I（ - ），HSO4-，H2PO4-，H2PO3-，NO3-，CH3COO（ - ），CH2ClCOO-，CF3COO-，HOCH2COO-，CH3CH （ - ），HOOCCOO（ - ），HOOCCH2COO（ - ），HOOCCH = CHCOO（ - ），制备式I化合物的方法和制备方法的新中间体。 式I的化合物具有杀线虫和杀真菌性质。 描述了含有至少一种式I化合物作为活性成分的杀线虫和杀真菌组合物，以及使用化合物和组合物控制线虫和真菌的方法。

    Compositions for protecting plants against disease
    53.
    发明授权
    Compositions for protecting plants against disease 失效
    防治疾病的植物的组合物

    公开(公告)号：US5112840A

    公开(公告)日：1992-05-12

    申请号：US594889

    申请日：1990-10-09

    申请人： Helmut Zondler ,  Alfred Meyer ,  Wolfgang Eckhardt ,  Walter Kunz

    发明人： Helmut Zondler ,  Alfred Meyer ,  Wolfgang Eckhardt ,  Walter Kunz

    IPC分类号： A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  C07D213/81 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D413/14

    CPC分类号： C07D213/81 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14

    摘要： Novel substituted isonicotinic acid amides of the general formula ##STR1## in which X in ortho/ortho'-position are equal and represent fluorine, chlorine, bromine or iodine;Q.sub.1 is unsubstituted pyrimidin-4-yl, or pyrimidin-4-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.2 is unsubstituted pyrimidin-2-yl, or pyrimidin-2-yl substituted by R.sub.1,R.sub.2 and R.sub.3 ;Q.sub.3 is unsubstituted pyrimidin-5-yl, or pyrimidin-5-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.4 is pyridin-2-yl, pyridin-3-yl or pyridin-4-yl each of which is unsubstituted or substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.5 is pyridazin-3-yl or pyridazin-4-yl each of which is unsubstituted or substituted by R.sub.1, R.sub.2 and R.sub.3 ;Q.sub.6 is unsubstituted pyrazin-2-yl, or pyrazin-2-yl substituted by R.sub.1, R.sub.2 and R.sub.3 ;R.sub.1, R.sub.2, R.sub.3 are hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl having from 1 to 3 halogen atoms, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkoxyalkyl, C.sub.1 -C.sub.6 thioalkyl, C.sub.1 -C.sub.6 haloalkoxy having from 1 to 5 halogen atoms, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 thioalkenyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 cycloalkyl substituted by methyl, or nitro, cyano, the radical CH(OR.sub.4).sub.2 or COOR.sub.4 in which R.sub.4 is C.sub.1 -C.sub.4 alkyl; also phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl; or phenyl, phenoxy, thiophenyl, benzyl, benzyloxy or thiobenzyl each substituted at least once by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano; and also N(R.sub.5)R.sub.6 in which R.sub.5 and R.sub.6, independently of one another, are each C.sub.1 -C.sub.6 alkyl; and furthermore piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl, or piperidinyl, pyrrolidinyl, morpholinyl, imidazolyl or triazolyl each substituted by C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkyl having from 1 to 3 halogen atoms, halogen, nitro or by cyano.The novel ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.

    Pesticidal compositions
    56.
    发明授权
    Pesticidal compositions 失效
    杀虫剂组合物

    公开(公告)号：US4694009A

    公开(公告)日：1987-09-15

    申请号：US746432

    申请日：1985-06-19

    申请人： Adolf Hubele ,  Helmut Zondler ,  Peter Riebli ,  Wolfgang Eckhardt

    发明人： Adolf Hubele ,  Helmut Zondler ,  Peter Riebli ,  Wolfgang Eckhardt

    IPC分类号： A01N43/54 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  A61K31/505

    CPC分类号： C07D239/42 ,  A01N43/54 ,  C07D239/47

    摘要： The invention discloses novel N-(2-nitrophenyl)-2-aminopyrimidine derivatives of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen, NO.sub.2 or CF.sub.3, with the proviso that only R.sub.1 or R.sub.2 can be NO.sub.2 ;R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio;R.sub.5, R.sub.6 and R.sub.7 are each independently halogen, nitro, cyano, thiocyano, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.8 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 haloalkenyloxy, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 haloalkynyloxy, C.sub.1 -C.sub.8 alkyl which is substituted by halogen, cyano and/or C.sub.1 -C.sub.4 alkoxy, or are unsubstituted C.sub.1 -C.sub.8 alkoxy or halogen-substituted C.sub.1 -C.sub.8 alkoxy, the alkyl moiety of which may be interrupted by one or more single oxygen atoms, or are the Q--(E).sub.n --(X).sub.m group, in which n is 0 or 1, m is 0 or 1, Q is phenyl which is unsubstituted or substituted by halogen, nitro, C.sub.1 -C.sub.3 alkyl, CF.sub.3 and/or C.sub.1 -C.sub.3 alkoxy, or is a saturated or unsaturated heterocyclic radical containing one or more hetero atoms, E is a C.sub.1 -C.sub.3 alkylene bridge, and X is oxygen or sulfur, and R.sub.6 and/or one of the radicals R.sub.5 or R.sub.7 can also be hydrogen.Also disclosed are methods of preparing these compounds, and agrochemical compositions which contain one such compound as active ingredient. The invention further relates to the use of the novel compounds, or compositions containing them, in agriculture and related fields.

    摘要翻译： 本发明公开了通式I（I）的新型N-（2-硝基苯基）-2-氨基嘧啶衍生物，其中R 1和R 2是氢，NO 2或CF 3，条件是只有R 1或R 2可以是NO 2; R 4是氢或-C（O）R'基团，其中R'是未被取代或被卤素，C 1 -C 3烷氧基或C 1 -C 3烷硫基取代的C 1 -C 4烷基; R5，R6和R7各自独立地为卤素，硝基，氰基，氰基，C1-C12烷基，C3-C8环烷基，C1-C8烷硫基，C1-C6烷基磺酰基，C1-C6烷基亚磺酰基，C3-C6链烯基，C3-C6卤代烯基，C3-C6炔基， C 6卤代炔基，C 3 -C 6烯氧基，C 3 -C 6卤代烯氧基，C 3 -C 6烯基硫基，C 3 -C 6炔氧基，C 3 -C 6卤代炔氧基，被卤素，氰基和/或C 1 -C 4烷氧基取代的C 1 -C 8烷基，或未取代的C 1 -C 8烷氧基或卤素取代的C 1 C 1-8烷氧基，其烷基部分可被一个或多个单个氧原子间隔，或是Q-（E）n-（X）m基团，其中n为0或1，m为0或1，Q 是未取代的或被卤素，硝基，C 1 -C 3烷基，CF 3和/或C 1 -C 3烷氧基取代的苯基，或是含有一个或多个杂原子的饱和或不饱和杂环基，E是C 1 -C 3亚烷基桥，X是 氧或硫，R6和/或基团R5或R7之一也可以是氢。 还公开了制备这些化合物的方法和含有一种这样的化合物作为活性成分的农药组合物。 本发明还涉及在农业和相关领域中使用含有它们的新化合物或组合物。

    Bactericides
    57.
    发明授权
    Bactericides 失效
    杀菌剂

    公开(公告)号：US4562210A

    公开(公告)日：1985-12-31

    申请号：US563841

    申请日：1983-12-21

    申请人： Willy Meyer ,  Werner Topfl ,  Haukur Kristinsson ,  Wolfgang Eckhardt

    发明人： Willy Meyer ,  Werner Topfl ,  Haukur Kristinsson ,  Wolfgang Eckhardt

    IPC分类号： A01N47/34 ,  A01N47/36 ,  C07C311/54 ,  C07C127/19 ,  C07C157/09

    CPC分类号： C07C309/89 ,  A01N47/36 ,  C07C311/65

    摘要： Novel N-[2-(1,2-dichlorovinyloxy)phenylsulfonyl]-(thio)ureas of the general formula I ##STR1## in which X is oxygen or sulfur, R.sub.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkinyl; and R.sub.2 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkinyl or C.sub.1 -C.sub.6 -alkoxy; and the salts of these compounds are described.These compounds have pronounced bactericidal properties and can be used without problems against bacteria which damage plants, especially in the agricultural sector.

    摘要翻译： 通式I的新型N- [2-（1,2-二氯乙烯氧基）苯基磺酰基] - （硫代）脲其中X是氧或硫，R 1是氢，C 1 -C 12烷基，C 2 -C 1-6 - 烯基或C 2 -C 6 - 炔基; 并且R 2是氢，C 1 -C 12 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基或C 1 -C 6 - 烷氧基; 并描述了这些化合物的盐。 这些化合物具有显着的杀菌性质，并且可以在不损害特别是农业部门的植物细菌的情况下使用。

    Microbicidal 2-(1H-1,2,4-triazolylmethyl-1'-yl)-2-siloxy-2-phenyl-acetates
    58.
    发明授权
    Microbicidal 2-(1H-1,2,4-triazolylmethyl-1'-yl)-2-siloxy-2-phenyl-acetates 失效

    公开(公告)号：US4533659A

    公开(公告)日：1985-08-06

    申请号：US499725

    申请日：1983-05-31

    申请人： Wolfgang Eckhardt ,  Walter Kunz

    发明人： Wolfgang Eckhardt ,  Walter Kunz

    IPC分类号： C07D233/60 ,  A01N43/50 ,  A01N43/653 ,  A01N55/00 ,  A01N55/10 ,  C07F7/18 ,  A61K31/555 ,  C07D207/30

    CPC分类号： A01N55/00 ,  C07F7/1856

    摘要： The invention relates to microbicidal silyloxyalkane azoles of the formula I ##STR1## wherein X is the bridge member --CH.dbd. or --N.dbd.,Ar is a phenyl, diphenyl or naphthyl group,R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, nitro, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkyl,R is one of the groups --COOR.sub.5, --COSR.sub.6, ##STR2## or --CN, R.sub.5 is C.sub.2 -C.sub.10 alkenyl which is unsubstituted or substituted by halogen; C.sub.2 -C.sub.10 alkynyl which is unsubstituted or substituted by halogen; or is a C.sub.3 -C.sub.8 cycloalkyl group or a phenyl group which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CN or --CF.sub.3 ; or is a C.sub.1 -C.sub.12 alkyl chain which from C.sub.2 alkyl may be interrupted by oxygen or sulfur and is unsubstituted or substituted by a member selected from the group consisting of halogen, phenyl, --COO--C.sub.1 --C.sub.4 alkyl, --CO--C.sub.1 --C.sub.4 alkyl, --CO--phenyl, an unsaturated or saturated 5- or 6-membered ring containing oxygen or sulfur as heteroatom, with each phenyl moiety being unsubstituted or substituted by one or more identical or different halogen atoms,R.sub.6 is C.sub.1 -C.sub.10 alkyl, or is a phenyl or benzyl group, each unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --CN or --CF.sub.3,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.7 cycloalkyl, or a phenyl or benzyl group in each of which the aromatic ring is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 alkoxy, --CN or --CF.sub.3, or one of R.sub.7 and R.sub.8 is also the --N(R.sub.9)(R.sub.10) group or both taken together form a 5- or 6-membered saturated or unsaturated heterocyclic ring which may additionally contain 1 or 2 further N atoms,R.sub.9 and R.sub.10, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl or a phenyl radical which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl, --CN or --CF.sub.3 ; andR.sub.4 is the --Si(R.sub.11)(R.sub.12)(R.sub.13) group, wherein each of R.sub.11, R.sub.12 and R.sub.13 independently is a radical selected from C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.7 alkenyl or phenyl, each unsubstituted or substituted by one or more halogen atoms,and the acid addition salts and metal complexes thereof.Also disclosed are methods of preparing these compounds and also pesticidal compositions which contain at least one of the novel compounds as active ingredient. A method of controlling phytopathogenic microorganisms with the aid of the novel compounds of the invention is also described.

    Azolylmandelic acid derivatives and use thereof for controlling microorganisms
    59.
    发明授权
    Azolylmandelic acid derivatives and use thereof for controlling microorganisms 失效
    唑基扁桃酸衍生物及其用于控制​​微生物的用途

    公开(公告)号：US4517194A

    公开(公告)日：1985-05-14

    申请号：US503966

    申请日：1983-06-13

    申请人： Walter Kunz ,  Wolfgang Eckhardt

    发明人： Walter Kunz ,  Wolfgang Eckhardt

    IPC分类号： A01N43/50 ,  A01N43/653 ,  A01N47/04 ,  C07D233/60 ,  C07D233/64 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64 ,  C07D249/06

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  A01N47/04 ,  C07D233/56 ,  C07D249/08

    摘要： The invention relates to microbicidal mandelic acid derivatives of the formula I ##STR1## wherein X is the bridge member --CH.dbd. or --N.dbd.,Ar is a phenyl, diphenyl or naphthyl group,R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, nitro, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkyl,R is one of the groups ##STR2## R.sub.5 is C.sub.2 -C.sub.10 alkenyl which is unsubstituted or substituted by halogen; C.sub.2 -C.sub.10 alkynyl which is unsubstituted or substituted by halogen; or is a C.sub.3 -C.sub.8 cycloalkyl group or a phenyl group which is unsubstituted or substituted; or is a C.sub.1 -C.sub.12 alkyl chain which from C.sub.2 alkyl may be interrupted by oxygen or sulfur and is unsubstituted or substituted by a member selected from the group consisting of halogen, phenyl, --COO--C.sub.1 --C.sub.4 alkyl, --CO--C.sub.1 --C.sub.4 alkyl, --CO-phenyl, an unsaturated or saturated 5- or 6-membered ring containing oxygen or sulfur as heteroatom, with each phenyl moiety being unsubstituted or substituted by one or more identical or different halogen atoms, is C.sub.1 -C.sub.10 alkyl, or is a phenyl or benzyl group, each unsubstituted or substitutedR.sub.4 is C.sub.1 -C.sub.12 alkyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.4 alkyl, or is phenyl or benzyl, each unsubstituted or substituted or is the --N(R.sub.9)(R.sub.10) group, whereinR.sub.9 is C.sub.1 -C.sub.6 alkyl andR.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkylsulfenyl, --SC.sub.6 H.sub.5 or --SC(CH.sub.3).sub.2 CN,and the acid addition salts and metal complexes thereof.

    摘要翻译： 本发明涉及式I（I）的杀微生物扁桃酸衍生物，其中X是桥连构成基团-CH =或-N =，Ar是苯基，二苯基或萘基，R 1，R 2和R 3独立地是一个 另一个是氢，硝基，卤素，C 1 -C 3烷基，C 1 -C 3烷氧基或C 1 -C 3卤代烷基，R是基团之一。R 5是未被取代或被卤素取代的C 2 -C 10烯基; 未被取代或被卤素取代的C 2 -C 10炔基; 或者是C3-C8环烷基或未取代或取代的苯基; 或者是C 2 -C 12烷基链，其可以被C 2 -C 12烷基取代或被氧或硫中断，并且未被取代或被选自卤素，苯基，-COO-C 1 -C 4烷基，-CO-C 1 -C 4烷基， CO-苯基，不饱和或饱和的含有氧或硫作为杂原子的5-或6-元环，每个苯基部分未被取代或被一个或多个相同或不同的卤素原子取代，是C 1 -C 10烷基，或是苯基或 苄基，每个未取代或取代的R4是未被取代或被卤素或C1-C4烷基取代的C1-C12烷基，或为苯基或苄基，各自未取代或取代或为-N（R9）（R10）基团，其中R9为 C1-C6烷基和R10是氢，C1-C4烷基，C1-C4卤代烷基亚磺酰基，-SC6H5或-SC（CH3）2CN，及其酸加成盐和金属配合物。

    Homoserine derivatives and their use as microbicides
    60.
    发明授权
    Homoserine derivatives and their use as microbicides 失效
    高丝氨酸衍生物及其作为杀微生物剂的用途

    公开(公告)号：US4442117A

    公开(公告)日：1984-04-10

    申请号：US199903

    申请日：1980-10-23

    申请人： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele ,  Peter Riebli

    发明人： Walter Kunz ,  Wolfgang Eckhardt ,  Adolf Hubele ,  Peter Riebli

    IPC分类号： C07C231/12 ,  A01N37/46 ,  A01N41/04 ,  A01N43/08 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N47/12 ,  A01N47/16 ,  A01N47/20 ,  A01N53/00 ,  C07C233/54 ,  C07D307/24 ,  C07D521/00 ,  A01N37/22 ,  C07C103/66 ,  C07C103/737

    CPC分类号： C07D231/12 ,  A01N37/46 ,  A01N41/04 ,  A01N43/08 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N47/12 ,  A01N47/16 ,  A01N47/20 ,  A01N53/00 ,  C07D233/56 ,  C07D249/08 ,  C07D307/24

    摘要： There are described novel homoserine derivatives of the formula (I) ##STR1## which possess valuable microbicidal properties. In the formula: Ar is substituted phenyl or naphthyl; R.sub.1 is C.sub.2 -C.sub.6 alkyl optionally interrupted by oxygen or sulfur, 2-furyl, 2-tetrahydrofuryl, 1H-1,2,4-triazolylmethyl, 1-imidazolylmethyl, 1-pyrazolylmethyl, C.sub.2 -C.sub.4 alkenyl or cyclopropyl, each of which is optionally substituted by halogen; R.sub.2 is hydrogen or methyl; R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl; and B is halogen or an ester, thioester, sulfonic acid ester or sulfonic acid amide group. Additionally, where B is halogen, R.sub.1 may be halomethyl. The novel derivatives can be used for combating microorganisms harmful to plants, particularly for combating phytopathogenic fungi, and they have for practical requirements a very favorable curative and protective action for protecting cultivating plants, without the plants being impaired as a result of undesirable secondary effects. A notable feature is their stability to heat and to solar irradiation. They can be used in practice on their own or in the form of pesticidal compositions.

    摘要翻译： 描述了具有有价值的杀微生物性质的式（I）的新颖高丝氨酸衍生物。 式中Ar是取代的苯基或萘基; R1是任选被氧或硫中断的C 2 -C 6烷基，2-呋喃基，2-四氢呋喃基，1H-1,2,4-三唑基甲基，1-咪唑基甲基，1-吡唑基甲基，C 2 -C 4烯基或环丙基， 任选被卤素取代; R2是氢或甲基; R3是氢或C1-C4烷基; 和B是卤素或酯，硫酯，磺酸酯或磺酸酰胺基。 另外，当B是卤素时，R 1可以是卤代甲基。 新型衍生物可用于对抗对植物有害的微生物，特别是用于防治植物病原性真菌，并且它们具有非常有利的治疗和保护作用，用于保护栽培植物，而不会由于不期望的二次作用而损害植物。 它的一个显着特点是它们对热和太阳辐射的稳定性。 它们可以自己使用或以农药组合物的形式使用。