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51.发明授权O,O-Diethyl-O-[N-methoxy-2-nitrobenzimidoyl]-thiono-phosphoric acid esters 失效O，O-二乙基-O- {8 N-甲氧基-2-硝基苯甲亚氨基{9-硫代磷酸酯
公开(公告)号：US4054650A
公开(公告)日：1977-10-18
申请号：US726362
申请日：1976-09-24
CPC分类号： A01N57/14 , C07F9/1653
摘要： O,O-Diethyl-O-[N-methoxy-2-nitrobenzimidoyl]-thiono-phosphoric acid ester of the formula ##STR1## which possesses insecticidal and acaricidal properties.
摘要翻译： 具有杀虫和杀螨性质的式（I）的O，O-二乙基-O- [N-甲氧基-2-硝基亚氨基] - 硫代磷酸酯。
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52.发明授权Pesticidally active 2-phenyl-alk-1-enyl-cyclopropane-carboxylic acid esters 失效杀虫活性的2-苯基 - 烷-1-烯基 - 环丙烷 - 羧酸酯
公开(公告)号：US4344963A
公开(公告)日：1982-08-17
申请号：US143958
申请日：1980-04-25
IPC分类号： C07C69/747 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/06 , A01N53/08 , C07C61/37 , C07C67/00 , C07C67/08 , C07C67/14 , C07C69/757 , C07C201/00 , C07C205/55 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/62 , C07C69/743 , C07C121/75
CPC分类号： A01N53/00
摘要： 2-Phenyl-alk-1-enyl-cyclopropane-carboxylic acid esters of the formula ##STR1## in which R each independently ishydrogen, halogen, cyano, nitro and, in each case optionally halogen-substituted, alkyl, alkoxy, alkylenedioxy or alkylthio,R.sup.1 is optionally halogen-substituted alkyk, andR.sup.2 is a radical customary in the alcohol part of pyrethroidswhich exhibit insecticidal and acaricidal activity. They are made from the corresponding alkyl esters which are new and made by novel processes.
摘要翻译： 其中R各自独立地为氢，卤素，氰基，硝基，且在任何情况下均为卤素取代的烷基，烷氧基，亚烷基二氧基或烷硫基的2-苯基 - 烷-1-烯基 - 环丙烷 - 羧酸酯 R1任选是卤素取代的烷基，R2是拟除虫菊酯的醇部分中通常具有杀虫和杀螨活性的基团。 它们由相应的新的烷基酯制成，并通过新方法制成。
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53.发明授权O-Alkyl-O-[8-chloro-quinoxal-2-yl]-thionoalkanephosphonic acid esters 失效O-烷基-O- {8 8-氯 - 喹喔啉-2-基{9-硫代烷基膦酸酯
公开(公告)号：US4134978A
公开(公告)日：1979-01-16
申请号：US786914
申请日：1977-04-12
IPC分类号： A01N57/24 , C07F9/6509 , A01N9/36
CPC分类号： C07F9/650994 , A01N57/24
摘要： O-Alkyl-O-[8-chloro-quinoxal-2-yl]-thionoalkanephosphonic acid esters of the formula ##STR1## in which R and R.sup.1 each independently is alkyl with 1 to 6 carbon atoms, which possess arthropodicidal, especially insecticidal and acaricidal, properties.
摘要翻译： 具有式（I）的O-烷基-O- [8-氯 - 喹喔啉-2-基] - 硫代烷基膦酸酯，其中R和R 1各自独立地为具有1至6个碳原子的烷基，其具有节肢杀虫剂 ，特别是杀虫和杀螨的性质。
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54.发明授权O-Alkyl-S-[3-oxo-1,2 ,4-triazolobenzopyrazin(2)yl-methyl]-(thiono)thiolphosphoric(phosphonic) acid esters 失效O-烷基-S- {8-氧代-1,2,4-三唑并苯并吡嗪（2） - 甲基{9-（硫杂）硫代磷酸（膦酸）酯
公开(公告)号：US4076806A
公开(公告)日：1978-02-28
申请号：US669781
申请日：1976-03-24
IPC分类号： A01N57/24 , A01N57/16 , A01P7/04 , C07D241/44 , C07D487/04 , C07F9/6561 , C07F9/40 , A01N9/36 , C07F9/165
CPC分类号： C07D487/04 , C07D241/44 , C07F9/6561
摘要： O-Alkyl-S-[3-oxo-1,2,4-triazolobenzopyrazin(2)yl-methyl]-(thiono)thiolphosphoric(phosphonic) acid esters of the formula ##STR1## in which R is alkyl with 1 to 4 carbon atoms,R.sub.1 is alkyl or alkoxy with 1 to 4 carbon atoms, andX is oxygen or sulfur,Which possess insecticidal properties.
摘要翻译： 式（I）的O-烷基-S- [3-氧代-1,2,4-三唑并苯并吡嗪（2） - 甲基] - （硫杂）硫醇磷酸（膦酸）酸酯其中R是烷基 具有1至4个碳原子，R 1是具有1至4个碳原子的烷基或烷氧基，X是氧或硫，具有无害的杀虫剂性质。
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公开(公告)号：US4567168A
公开(公告)日：1986-01-28
申请号：US344268
申请日：1982-01-28
申请人： Bernd-Wieland Kruger , Hans-Jochem Riebel , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
发明人： Bernd-Wieland Kruger , Hans-Jochem Riebel , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N57/02 , A01N57/10 , A01N57/18 , A01N57/26 , C07F9/165 , C07F9/173 , C07F9/177 , C07F9/18 , C07F9/24 , C07F9/40 , C07F9/58 , C07F9/655 , C07F9/6553
CPC分类号： C07F9/655345 , A01N57/02 , C07F9/1651 , C07F9/1653 , C07F9/173 , C07F9/177 , C07F9/18 , C07F9/2408 , C07F9/2429 , C07F9/4075 , C07F9/4078 , C07F9/4081 , C07F9/4087 , C07F9/582 , C07F9/65517
摘要： A cyanohydrin phosphate of the formula ##STR1## wherein R represents a hydrogen atom or an optionally substituted radical selected from alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl, or an optionally substituted heterocyclic radical,R.sup.1 and R.sup.2 are identical or different and individually represent optionally substituted radicals selected from alkyl, alkenyl, alkynyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, alkenylthio, alkinylthio, arylthio, aralkylthio, alkylamino (monoalkylamino or dialkylamino), arylamino and aralkylamino, or together represent alkanediyl, alkanedioxy, aminoalkyloxy or alkanediamino, andX represents oxygen or sulphur,are obtained by the reaction of a phosphoric acid chloride of the general formula ##STR2## wherein X, R.sup.1 and R.sup.2 have the meaning given above, with an aldehyde of the general formulaR--CHO (III)wherein R has the meaning given above, in the presence of an approximately equimolar quantity of water-soluble cyanides. Some of the compounds of the formula (I) are new. They can be used as insectides and acaricides.
摘要翻译： 式（I）的氰基磷酸酯，其中R表示氢原子或选自烷基，烯基，炔基，环烷基，环烯基，芳烷基，芳烯基和芳基或任选取代的杂环基的任选取代的基团R 1和 R 2相同或不同，并且各自独立地表示任选取代的选自烷基，烯基，炔基，芳基，芳烷基，烷氧基，芳氧基，芳烷氧基，烷硫基，烯硫基，炔基硫基，芳硫基，芳烷硫基，烷基氨基（单烷基氨基或二烷基氨基） 或者一起表示烷二基，烷二氧基，氨基烷氧基或烷二氨基，X表示氧或硫，通过通式（II）的磷酰氯与其中X，R 1和R 2具有上述含义的反应获得， 与通式为R-CHO（III）的醛，其中R具有上述含义，在约等摩尔量的水溶液存在下 有氰化物。 一些式（I）的化合物是新的。 它们可以用作杀虫剂和杀螨剂。
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公开(公告)号：US4548931A
公开(公告)日：1985-10-22
申请号：US538856
申请日：1983-10-04
CPC分类号： A01N57/22 , A01N57/20 , C07F9/4075
摘要： O-(2,2,2-trihalogenoethyl) S-alkyl (di)thiophosphonates of the formula ##STR1## in which X is oxygen or sulphur,Y is halogen,R.sup.1 is alkyl or optionally substituted aryl, andR.sup.2 is alkyl.which exhibit insecticidal, acaricidal and nematocidal activity. Intermediates therefor of the formulas ##STR2## in which Z is one equivalent of an alkali metal or ammonium ion, andR.sup.3 is C.sub.1 -C.sub.4 -alkyl, are also new.
摘要翻译： 其中X是氧或硫，Y是卤素，R 1是烷基或任选被取代的芳基，且R 2是烷基的式（I）的O-（2,2,2-三卤代乙基）S-烷基（二）硫代膦酸酯。 其具有杀虫，杀螨和杀线虫活性。 其中Z为1当量碱金属或铵离子，R3为C1-C4烷基的式“IMAGE”的中间体也是新的。
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57.发明授权
公开(公告)号：US4485252A
公开(公告)日：1984-11-27
申请号：US375061
申请日：1982-05-05
IPC分类号： C07C69/747 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/06 , A01N53/08 , C07C61/37 , C07C67/00 , C07C67/08 , C07C67/14 , C07C69/757 , C07C201/00 , C07C205/55 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/62 , C07C69/743 , C07C61/04
CPC分类号： A01N53/00
摘要： 2-Phenyl-alk-1-enyl-cyclopropane-carboxylic acid esters of the formula ##STR1## in which R each independently is hydrogen, halogen, cyano, nitro and, in each case optionally halogen-substituted, alkyl, alkoxy, alkylenedioxy or alkylthio,R.sup.1 is optionally halogen-substituted alkyk, andR.sup.2 is a radical customary in the alcohol part of pyrethroidswhich exhibit insecticidal and acaricidal activity. They are made from the corresponding alkyl esters which are new and made by novel processes.
摘要翻译： 其中R各自独立地为氢，卤素，氰基，硝基，并且在任何情况下均为卤素取代的烷基，烷氧基，亚烷基二氧基或亚烷基二氧基的2-苯基 - 烷-1-烯基 - 环丙烷 - 羧酸酯 烷硫基，R1任选为卤素取代的烷基，R 2为拟除虫菊酯的醇部分中常见的基团，其具有杀虫活性和杀螨活性。 它们由相应的新的烷基酯制成，并通过新方法制成。
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公开(公告)号：US4416832A
公开(公告)日：1983-11-22
申请号：US344263
申请日：1982-01-28
申请人： Bernd-Wieland Kruger , Hans-Jochem Riebel , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
发明人： Bernd-Wieland Kruger , Hans-Jochem Riebel , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
CPC分类号： C07F9/425 , C07F9/14 , C07F9/1651 , C07F9/20 , C07F9/26 , C07F9/4075
摘要： New cyanoalkylphosphoric acid ester chlorides of the general formula ##STR1## in which R represents a hydrogen atom, an optionally substituted radical selected from alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl, or an optionally substituted heterocyclic radical,R.sup.1 represents an optionally substituted radical selected from alkyl, alkenyl, alkinyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, alkenylthio, alkinylthio, arylthio, aralkylthio, alkylamino (monoalkylamino or dialkylamino), arylamino or aralkylamino and X represents oxygen or sulphurare obtained by the reaction of a phosphoric acid dichloride of the general formula ##STR2## with an aldehyde of the general formulaR--CHO (III)in the presence of an approximately equimolar quantity of a water-soluble cyanide. The compounds of the formula (I) can be used as intermediate products for the preparation of insecticides.
摘要翻译： 通式为“IMAGE”的新的氰基烷基磷酸酯氯化物，其中R表示氢原子，任选取代的选自烷基，烯基，炔基，环烷基，环烯基，芳烷基，芳烯基和芳基或任选取代的杂环基的基团，R1 表示选自烷基，烯基，炔基，芳基，芳烷基，烷氧基，芳氧基，芳烷氧基，烷硫基，烯硫基，炔基硫基，芳硫基，芳烷硫基，烷基氨基（单烷基氨基或二烷基氨基），芳基氨基或芳烷基氨基，X表示氧或硫的任选取代的基团 通过在通式R-CHO（III）的醛与大约等摩尔量的水溶性氰化物的存在下，使通式为“IMAGE”（II）的磷酸二氯化物反应得到。 式（I）的化合物可用作制备杀虫剂的中间产物。
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59.发明授权2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl esters and pesticidal use 失效2,2-二甲基-3-（2-溴-2-苯基 - 乙烯基） - 环丙烷甲酸3-苯氧基苄酯和杀虫剂
公开(公告)号：US4279920A
公开(公告)日：1981-07-21
申请号：US74045
申请日：1979-09-10
IPC分类号： C07C69/747 , A01N53/00 , A01N53/08 , A01P7/02 , A01P7/04 , B01J27/00 , B01J27/232 , B01J31/00 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/14 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/62 , C07D317/52 , C07D317/62 , C07F9/40 , A01N43/30 , C07C69/743 , C07C121/75
CPC分类号： A01N53/00 , C07C61/40 , C07F9/4056
摘要： 2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl ester of the formula ##STR1## which possess arthropodicidal properties. In addition, the new intermediate of the formula ##STR2## is produced by reacting an .alpha.-bromo-benzyl-phosphonic acid ester of the formula ##STR3## in which R.sup.6 each independently is alkyl or phenyl, or the two radicals R.sup.6 together are alkanediyl, with a 3-formyl-2,2-dimethyl-cyclopropanecarboxylic acid ester and saponifying. Also the compounds of the formula ##STR4## which are new when R.sup.1 is not alkyl, are produced by reacting triphenylphosphine and bromine to form dibromo-triphenylphosphorane, and reacting the dibromo-triphenylphosphorane without isolation with an .alpha.-hydroxy-benzyl-phosphonic acid ester of the formula ##STR5##
摘要翻译： 具有节肢动物特性的式“IMAGE”的2,2-二甲基-3-（2-溴-2-苯基 - 乙烯基） - 环丙烷甲酸3-苯氧基苄基酯。 此外，式“IMAGE”的新中间体是通过使式“IMAGE”的α-溴 - 苄基膦酸酯反应，其中R6各自独立地为烷基或苯基，或两个基团R6一起为烷二基 ，与3-甲酰基-2,2-二甲基 - 环丙烷甲酸酯和皂化。 另外，当R1不是烷基时，新的化合物“IMAGE”也是通过使三苯基膦和溴反应形成二溴 - 三苯基正膦而制备的，并且不分离的二溴 - 三苯基正膦与α-羟基 - 苄基膦酸酯 的公式
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60.发明授权Combating pests with O-alkyl-O-trifluoromethylsulphinylphenyl-thiono(thiol)-phosphoric acid esters 失效用O-烷基-O-三氟甲基亚磺酰基苯硫基（硫醇） - 磷酸酯防治害虫
公开(公告)号：US4164575A
公开(公告)日：1979-08-14
申请号：US883001
申请日：1978-03-03
摘要： O-Alkyl-O-trifluoromethylsulphinylphenyl-thiono (thiol)-phosphoric acid esters of the formula ##STR1## wherein R and R.sup.1 each independently is alkyl,R.sup.2 is hydrogen, halogen or alkyl, andX is oxygen or sulphur,Which possess arthropodicidal and nematicidal properties.
摘要翻译： 其中R和R 1各自独立地为烷基，R 2为氢，卤素或烷基，且X为氧或硫，其为无定形的抗坏血酸的化合物及其盐， NEMATICIDAL属性。
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