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    Low Temperature Curable Epoxy Compositions Containing Urea Curatives
    51.
    发明申请
    Low Temperature Curable Epoxy Compositions Containing Urea Curatives 有权
    含有尿素固化剂的低温可固化环氧组合物

    公开(公告)号：US20110065958A1

    公开(公告)日：2011-03-17

    申请号：US12557824

    申请日：2009-09-11

    申请人： Atteye Houssein Abdourazak ,  Gamini Ananda Vedage

    发明人： Atteye Houssein Abdourazak ,  Gamini Ananda Vedage

    IPC分类号： C08G65/333 ,  C07C273/02

    CPC分类号： C08G18/325 ,  C08G59/4021 ,  C08G59/686

    摘要： A heat curable epoxy composition comprising the contact product of an epoxy resin, an epoxy curing agent and an accelerator for the epoxy curing agent, the curing agent or the accelerator comprising a urea compound which is the reaction product of an isocyanate and an alkylated polyalkylenepolyamine having one primary or secondary amine and at least two tertiary amines of the general formula: where R1, R2, R3, R4 and R5 independently represent hydrogen, methyl or ethyl, n and m independently are integers from 1 to 6 and; X is an integer from 1 to 10.

    摘要翻译： 一种热可固化环氧组合物，其包含环氧树脂，环氧固化剂和用于环氧固化剂的促进剂的接触产物，固化剂或促进剂，其包含作为异氰酸酯和烷基化聚亚烷基多胺的反应产物的脲化合物，其具有 一个伯胺或仲胺和至少两个具有以下通式的叔胺：其中R 1，R 2，R 3，R 4和R 5独立地表示氢，甲基或乙基，n和m独立地为1至6的整数; X为1〜10的整数。

    LOW TEMPERATURE CURABLE EPOXY COMPOSITIONS CONTAINING PHENOLIC-BLOCKED UREA CURATIVES
    52.
    发明申请
    LOW TEMPERATURE CURABLE EPOXY COMPOSITIONS CONTAINING PHENOLIC-BLOCKED UREA CURATIVES 有权
    低温可固化环氧组合物含有酚醛封端的尿素曲线

    公开(公告)号：US20110065837A1

    公开(公告)日：2011-03-17

    申请号：US12557930

    申请日：2009-09-11

    申请人： Gamini Ananda Vedage ,  Atteye Houssein Abdourazak

    发明人： Gamini Ananda Vedage ,  Atteye Houssein Abdourazak

    IPC分类号： C08L63/04 ,  C08G65/32

    CPC分类号： C08G59/621 ,  C08G59/4021 ,  C08G59/686 ,  C08K5/17 ,  C08K2201/014 ,  C09J163/00

    摘要： A heat curable epoxy composition comprising the contact product of an epoxy resin, an epoxy curing agent and an accelerator for the epoxy curing agent, the curing agent or the accelerator comprising the reaction product of (a) a phenolic resin and (b) a urea compound which is the reaction product of an isocyanate and an alkylated polyalkylenepolyamine having one primary or secondary amine and at least two tertiary amines of the general formula: where R1, R2, R3, R4 and R5 independently represent hydrogen, methyl or ethyl; n and m are independently integers from 1 to 6 and; X is an integer from 1 to 10.

    摘要翻译： 一种热固性环氧组合物，其包含环氧树脂，环氧固化剂和用于环氧固化剂的促进剂的接触产物，固化剂或促进剂，其包含（a）酚醛树脂和（b）脲 化合物，其是异氰酸酯和具有一个伯胺或仲胺和至少两个以下通式的叔胺的烷基化聚亚烷基多胺的反应产物：其中R1，R2，R3，R4和R5独立地表示氢，甲基或乙基; n和m独立地为1至6的整数; X为1〜10的整数。

    Hydrogenation of methylenedianiline
    57.
    发明授权
    Hydrogenation of methylenedianiline 有权
    亚甲基二苯胺的氢化

    公开(公告)号：US06998507B1

    公开(公告)日：2006-02-14

    申请号：US10925105

    申请日：2004-08-24

    申请人： Hao Ding ,  Anthony Rocco Cartolano ,  Vipul P. Dholakia ,  Gamini Ananda Vedage

    发明人： Hao Ding ,  Anthony Rocco Cartolano ,  Vipul P. Dholakia ,  Gamini Ananda Vedage

    IPC分类号： C07C209/77

    CPC分类号： C07C209/72 ,  C07C2601/14 ,  C07C211/36

    摘要： The invention is directed to an improvement in a catalytic process for the ring hydrogenation of a methylenedianiline feedstock, including crude methylenedianiline. One component of the improvement is a pretreatment process which resides in passing the crude methylenedianiline feedstock over a ruthenium catalyst carried on a fixed bed support, cooling without venting, and then hydrogenation of the pretreated crude methylenedianiline feedstock over a rhodium catalyst or a mixed Rh/Ru catalyst carried on a monolith support and carrying out the ring hydrogenation in a batch reaction. Another component in the improvement is the employment of a catalyst comprised of rhodium and ruthenium carried on a monolith support.

    摘要翻译： 本发明涉及甲基二苯胺原料（包括粗亚甲基二苯胺）的环加氢催化方法的改进。 改进的一个组成部分是将粗亚甲基二苯胺原料通过负载在固定床载体上的钌催化剂，冷却而不排气，然后在铑催化剂或混合的Rh / Ru催化剂承载在整料载体上并在间歇反应中进行环加氢。 改进的另一个组成部分是使用承载在整料支架上的由铑和钌构成的催化剂。

    Hydrogenation of methylenedianiline homologs and epoxy resins cured with same
    58.
    发明授权
    Hydrogenation of methylenedianiline homologs and epoxy resins cured with same 有权
    亚甲基二苯胺同系物的氢化和用相同固化的环氧树脂

    公开(公告)号：US06962964B2

    公开(公告)日：2005-11-08

    申请号：US10359450

    申请日：2003-02-06

    申请人： Michael Ulman ,  Gamini Ananda Vedage ,  David Alan Dubowik ,  Stephen Michael Boyce

    发明人： Michael Ulman ,  Gamini Ananda Vedage ,  David Alan Dubowik ,  Stephen Michael Boyce

    IPC分类号： C08G59/50 ,  C08G59/00

    CPC分类号： C07C211/49 ,  C08G59/5026

    摘要： This invention relates to improved polyepoxide resins cured with a mixture of methylene bridged poly(cycloaliphatic-aromatic)amines and a process for preparing such polyepoxide resins as well as to the methylene bridged poly(cycloaliphatic-aromatic)amine compositions and a method of making them. The improvement resides in using a curative (herein referred to as “Heavy MPCA”) comprised of the partially hydrogenated condensation product of formaldehyde and aniline or methyl substituted aniline containing a substantial amount (from 35 to 85% by weight, preferably 40 to 60% by weight) of oligomers in the form of 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14 and 15 aniline or methyl substituted aniline derivatives.

    摘要翻译： 本发明涉及用亚甲基桥连的聚（脂环族 - 芳族）胺的混合物固化的改进的聚环氧化物树脂和制备这种聚环氧化物树脂的方法以及亚甲基桥连的聚（脂环族 - 芳族）胺组合物及其制备方法 。 改进在于使用由部分氢化的甲醛缩合产物和苯胺或甲基取代的苯胺组成的固化剂（以下称为“重MPCA”），其含有相当量的（35至85重量％，优选40至60重量％ （重量）的3,4,5,6,7,8,9,10,11,12,13,14和15苯胺或甲基取代的苯胺衍生物形式的低聚物。

    Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts
    59.
    发明授权
    Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts 失效
    芳香胺的氢化生成它们的环氢化对应物

    公开(公告)号：US06140540A

    公开(公告)日：2000-10-31

    申请号：US43646

    申请日：1993-04-06

    申请人： Gamini Ananda Vedage ,  Richard Scott Myers ,  John Nelson Armor

    发明人： Gamini Ananda Vedage ,  Richard Scott Myers ,  John Nelson Armor

    IPC分类号： B01J23/89 ,  C07C209/72 ,  C07C209/00

    CPC分类号： B01J23/8913 ,  C07C209/72

    摘要： This invention relates to an improved hydrogenation and isomerization process wherein aromatic amines are hydrogenated to their ring hydrogenated counterparts and substantially isomerized to their thermodynamic form. These aromatic amines are presented by the formulas: ##STR1## wherein R is hydrogen or C.sub.1-6 alkyl, R1 and R2 are hydrogen or C.sub.1-6 aliphatic, A is C.sub.1-4 or NH; n is 0-2, x is 1-3 and y is 0 to 2 except the sum of the y groups must be at least 1.

    摘要翻译： 本发明涉及改进的氢化和异构化方法，其中芳族胺被氢化成它们的环氢化对应物并基本上异构化成它们的热力学形式。 这些芳族胺由下式表示：其中R是氢或C 1-6烷基，R 1和R 2是氢或C 1-6脂族基，A是C 1-4或NH; n为0-2，x为1-3且y为0至2，除了y基团之和必须至少为1。

    Amination of allylic alcohols
    60.
    发明授权
    Amination of allylic alcohols 失效
    烯丙醇的胺化

    公开(公告)号：US5639916A

    公开(公告)日：1997-06-17

    申请号：US564666

    申请日：1995-11-29

    申请人： John William Mitchell ,  Gamini Ananda Vedage

    发明人： John William Mitchell ,  Gamini Ananda Vedage

    IPC分类号： C07C209/16 ,  C07C211/21

    CPC分类号： C07C211/21 ,  C07C209/16

    摘要： This invention relates to an improvement in a process for the catalytic amination of an allylic alcohol of the formula:CH.sub.2 .dbd.CR--CH.sub.2 OHwhere R is hydrogen or methyl with ammonia or an amine of the formula R.sub.1 R.sub.2 NH where R.sub.1 and R.sub.2 represent hydrogen or a C.sub.1-5 hydrocarbyl group in the presence of an effective amount of a phosphorous containing catalyst to effect reaction between the allylic alcohol and the ammonia or amine to produce an allylic amine. The improvement in the process resides in utilizing a neutral group IIA metal phosphate as a catalyst component. Calcium phosphate is preferred and the catalyst.

    摘要翻译： 本发明涉及用于下式的烯丙醇催化胺化的方法：CH 2 = CR-CH 2 OH，其中R是氢或甲基与氨或式R 1 R 2 NH的胺，其中R 1和R 2表示氢或C1 -5烃基，在有效量的含磷催化剂存在下进行烯丙醇与氨或胺之间的反应以产生烯丙基胺。 该方法的改进在于利用中性IIA族金属磷酸盐作为催化剂组分。 优选的是磷酸钙和催化剂。