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公开(公告)号：US4317923A
公开(公告)日：1982-03-02
申请号：US189386
申请日：1980-09-19
申请人： Tamotsu Imai
发明人： Tamotsu Imai
IPC分类号： B01J23/36 , C07C51/487 , C07C51/42
CPC分类号： C07C51/487 , B01J23/36
摘要： Dicarboxylic aromatic acids containing impurities such as aldehydes may be purified by treating the acids at an elevated temperature in the presence of a catalyst containing metallic rhenium whereby the impurities may be removed and the purified acids recovered.
摘要翻译： 含有杂质如醛的二羧酸芳族酸可以通过在含有金属铼的催化剂存在下在升高的温度下处理酸来纯化，由此可以除去杂质并回收纯化的酸。
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公开(公告)号：US4207260A
公开(公告)日：1980-06-10
申请号：US971283
申请日：1978-12-20
申请人： Tamotsu Imai
发明人： Tamotsu Imai
CPC分类号： C07C209/26 , B01J31/2291 , B01J2231/4283 , B01J2531/821 , B01J2531/822 , Y02P20/582
摘要： Tertiary amines may be prepared by reacting an aldehyde, hydrogen and a nitrogen-containing compound such as ammonia, a primary amine or a secondary amine in the presence of a rhodium- or ruthenium-containing catalyst at temperatures in the range of from about 50.degree. to about 350.degree. C. and a pressure in the range of from about 10 to about 300 atmospheres.
摘要翻译： 叔胺可以通过使醛，氢和含氮化合物如氨，伯胺或仲胺在含铑或钌的催化剂存在下在约50℃的温度下反应来制备 至约350℃，压力范围为约10至约300大气压。
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公开(公告)号：US4179469A
公开(公告)日：1979-12-18
申请号：US971285
申请日：1978-12-20
申请人： Tamotsu Imai
发明人： Tamotsu Imai
IPC分类号： C07B43/04 , B01J23/00 , B01J31/00 , C07B31/00 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/60 , C07C85/18
CPC分类号： C07C209/60
摘要： Amines, which may be utilized in various chemical processes, may be prepared in a combination process wherein the product mixture resulting from the dehydrogenation of a paraffin feed stock may be reacted with a nitrogen-containing compound, carbon monoxide and hydrogen, without separating the olefins in the product mixture, in the presence of certain catalytic compositions of matter to prepare the aforesaid amines.
摘要翻译： 可以用于各种化学方法的胺可以以组合方法制备，其中由石蜡原料脱氢产生的产物混合物可以与含氮化合物，一氧化碳和氢气反应而不分离烯烃 在产物混合物中，在某些催化组合物的存在下制备上述胺。
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公开(公告)号：US4152361A
公开(公告)日：1979-05-01
申请号：US889761
申请日：1978-03-24
申请人： Tamotsu Imai
发明人： Tamotsu Imai
CPC分类号： C07C4/18 , C07C2101/16 , C07C2529/08 , Y10S208/02
摘要： Cyclohexene may be produced from phenylcyclohexane by treating the latter compound at an elevated temperature in the presence of certain solid acidic catalysts such as zeolite or silica-alumina to produce the desired compound.
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55.发明授权Process for reforming NAPHTHA feedstock using selective multimetallic-multigradient reforming catalyst 有权使用选择性多金属 - 多元转化催化剂重整NAPHTHA原料的方法
公开(公告)号：US6048449A
公开(公告)日：2000-04-11
申请号：US177345
申请日：1998-10-23
申请人： Paula L. Bogdan , Tamotsu Imai
发明人： Paula L. Bogdan , Tamotsu Imai
CPC分类号： B01J23/622 , B01J37/0201 , C10G35/09
摘要： A novel catalyst and the use thereof in a reforming process is disclosed. The dual-function catalyst comprises a refractory inorganic oxide, indium, Group IVA(IUPAC 14) metal, and a platinum-group metal concentrated in the surface layer of each catalyst particle. Utilization of this catalyst in the conversion of hydrocarbons, especially in reforming, results in significantly improved selectivity to the desired gasoline or aromatics product.
摘要翻译： 公开了一种新型催化剂及其在重整过程中的应用。 双功能催化剂包括耐火无机氧化物，铟，IVA族（IUPAC 14）金属和浓缩在每个催化剂颗粒的表面层中的铂族金属。 这种催化剂在烃的转化中的应用，特别是在重整过程中，导致对所需汽油或芳烃产物的显着提高的选择性。
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公开(公告)号：US5858908A
公开(公告)日：1999-01-12
申请号：US840562
申请日：1997-04-17
申请人： Paula L. Bogdan , Tamotsu Imai
发明人： Paula L. Bogdan , Tamotsu Imai
IPC分类号： B01J23/62 , B01J35/00 , B01J37/02 , C10G35/09 , B01J27/06 , B01J27/125 , B01J27/13 , B01J27/135
CPC分类号： B01J37/0201 , B01J23/62 , B01J35/0006 , C10G35/09
摘要： A novel catalyst and the use thereof in a reforming process is disclosed. The dual-function catalyst comprises a refractory inorganic oxide, indium, Group IVA(IUPAC 14) metal, and a platinum-group metal concentrated in the surface layer of each catalyst particle. Utilization of this catalyst in the conversion of hydrocarbons, especially in reforming, results in significantly improved selectivity to the desired gasoline or aromatics product.
摘要翻译： 公开了一种新型催化剂及其在重整过程中的应用。 双功能催化剂包括耐火无机氧化物，铟，IVA族（IUPAC 14）金属和浓缩在每个催化剂颗粒的表面层中的铂族金属。 这种催化剂在烃的转化中的应用，特别是在重整过程中，导致对所需汽油或芳烃产物的显着提高的选择性。
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公开(公告)号：US4962261A
公开(公告)日：1990-10-09
申请号：US208910
申请日：1988-06-20
申请人： Hayim Abrevaya , Tamotsu Imai
发明人： Hayim Abrevaya , Tamotsu Imai
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/02 , C07C2523/04 , C07C2523/06 , C07C2523/14 , Y10S585/943
摘要： Methane is upgraded to higher molecular weight hydrocarbons in a process using a novel catalyst comprising boron, tin and zinc. The feed admixture also comprises oxygen. The novel catalyst may comprise one or more Group I-A or II-A elements, preferably potassium.
摘要翻译： 在使用包含硼，锡和锌的新型催化剂的方法中，将甲烷升级为较高分子量的烃。 进料混合物还包含氧气。 新型催化剂可以包含一种或多种I-A族或II-A族元素，优选钾。
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公开(公告)号：US4886928A
公开(公告)日：1989-12-12
申请号：US249057
申请日：1988-09-26
申请人： Tamotsu Imai , Robert J. Schmidt
发明人： Tamotsu Imai , Robert J. Schmidt
CPC分类号： B01J23/63 , B01J23/622 , C07C5/325 , C07C5/3337 , Y02P20/52
摘要： A novel dehydrogenation process is disclosed which utilizes a catalyst comprising a platinum group component, a component selected from the group comprising scandium, yttrium, lanthanum, and actinium, a component selected from the group comprising tin, lead, and germanium, less than 0.3 wt. % of a halogen component, and an optional Group IA or IIA component, all on a refractory inorganic oxide support.
摘要翻译： 公开了一种新的脱氢方法，其使用包含铂族组分，选自钪，钇，镧和锕的组分的催化剂，选自锡，铅和锗的组分，小于0.3重量％ 。 ％的卤素组分和任选的IA或IIA组分，全部在耐火无机氧化物载体上。
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公开(公告)号：US4857666A
公开(公告)日：1989-08-15
申请号：US247810
申请日：1988-09-21
CPC分类号： C07C6/126 , C07C15/02 , C07C2/70 , C07C2527/173 , C07C2529/06 , Y02P20/582
摘要： An alkylation-transalkylation process for the production of a monoalkylated aromatic compound is disclosed which maximizes the production of desirable monoalkylaromatic compounds, while limiting transalkylation catalyst deactivation. The process entails the combination of an alkylation reaction zone, a first seperation zone, a second separation zone, and a transalkylation reaction zone wherein the alkylation catalyst and transalkylation catalyst are dissimilar and where the alkylation catalyst is comprised of phosphoric acid material and the transalkylation catalyst is comprised of a crystalline aluminosilicate material. The transalkylation catalyst deactivation is reduced by transalkylating only dialkylated aromatic compounds. Additionally, the transalkylation catalyst is regenerable utilizing a hot liquid hydrocarbon wash.
摘要翻译： 公开了用于制备单烷基化芳族化合物的烷基化 - 烷基转移方法，其使所需的单烷基芳族化合物的产生最大化，同时限制了烷基转移催化剂失活。 该方法需要烷基化反应区，第一分离区，第二分离区和烷基转移反应区的组合，其中烷基化催化剂和烷基转移催化剂是不相似的，其中烷基化催化剂由磷酸材料和烷基转移催化剂 由结晶硅铝酸盐材料组成。 通过仅烷基化二烷基化芳族化合物来降低烷基转移催化剂的失活。 另外，烷基转移催化剂可利用热液体烃洗涤再生。
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60.发明授权
公开(公告)号：US4827072A
公开(公告)日：1989-05-02
申请号：US221977
申请日：1988-07-20
IPC分类号： B01J23/62 , B01J23/656 , B01J35/00 , C10G45/00 , C07C5/32
CPC分类号： B01J23/6567 , B01J23/622 , B01J35/0006 , C10G45/00
摘要： A novel catalytic composite comprising a platinum group metal component; a modifier metal component selected from the group consisting of a tin component, germanium component, rhenium component and mixtures thereof; an optional alkali or alkaline earth metal component or mixtures thereof, an optional halogen component, and an optional catalytic modifier component on a refractory oxide support having a nominal diameter of at least about 850 microns. The distribution of the platinum group metal component is such that the platinum group component is surface-impregnated where substantially all of the platinum group metal component is located at most within a 400 micron exterior layer of the support. The effective amount of the modifier metal component is uniformly dispersed throughout the refractory oxide support. The distribution of the surface-impregnated platinum metal component is such that the novel catalyst has particular utility as a hydrocarbon dehydrogenation catalyst in a hydrocarbon dehydrogenation process.
摘要翻译： 一种包含铂族金属组分的新型催化复合材料; 选自锡组分，锗组分，铼组分及其混合物的改性金属组分; 任选的碱金属或碱土金属组分或其混合物，任选的卤素组分和在耐火氧化物载体上的任选的催化改性剂组分，其标称直径为至少约850微米。 铂族金属组分的分布使得铂基组分被表面浸渍，其中基本上所有的铂族金属组分位于载体的400微米外层内。 改性金属组分的有效量均匀分散在整个难熔氧化物载体上。 表面浸渍的铂金属组分的分布使得新型催化剂在烃脱氢方法中作为烃脱氢催化剂具有特别的用途。
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