Wollastonite-reinforced polyoxymethylene molding materials and their
preparation
    52.
    发明授权
    Wollastonite-reinforced polyoxymethylene molding materials and their preparation 失效
    硅灰石增强聚甲醛成型材料及其制备

    公开(公告)号:US4987176A

    公开(公告)日:1991-01-22

    申请号:US221517

    申请日:1988-07-20

    摘要: Reinforced polyoxymethylene materials containing(A) one or more polyoxymethylene homopolymers and/or copolymers and(B) wollastonite, advantageously in a weight ratio of components (A) to (B) of from 95:50 to5:50, with or without(C) additives in effective amounts, the wollastonite crystals (B) have a mean thickness equal to or smaller than 5 .mu.m and a mean length/thickness ratio equal to or greater than 5. The molding materials are prepared by introducing the wollastonite crystals (B) into the melt of component (A) at from 180.degree. to 260.degree. C., advantageously by means of an extruder.

    摘要翻译: 含有(A)一种或多种聚甲醛均聚物和/或共聚物的增强聚甲醛材料和(B)硅灰石,有利地是组分(A)至(B)的重量比为95:50至5:50,具有或不具有(C )添加剂,硅灰石晶体(B)的平均厚度等于或小于5μm,平均长度/厚度比等于或大于5.成型材料通过将硅灰石晶体(B )有利地通过挤出机在180℃至260℃进入组分(A)的熔体中。

    Fiber-reinforced materials
    54.
    发明授权
    Fiber-reinforced materials 失效
    纤维增强材料

    公开(公告)号:US4649080A

    公开(公告)日:1987-03-10

    申请号:US731719

    申请日:1985-05-08

    摘要: Fiber-reinforced materials are produced by a process in which a heat-stable thermoplastic aromatic polyether A which contains reactive groups, preferably nitrile groups and/or sulfur bridges and/or arylthio or alkylthio groups, if necessary together with a heat-stable thermoplastic polymer B which does not contain any reactive groups, is applied onto reinforcing fibers, the resulting semi-finished product is molded and, in the molding obtained, the plastic matrix is crosslinked so that the glass transition temperature increases and it becomes virtually insoluble.

    摘要翻译: 纤维增强材料是通过一种方法制备的,其中如果必要,含有反应性基团,优选腈基和/或硫桥基和/或芳硫基或烷硫基的热稳定的热塑性芳族聚醚A与热稳定的热塑性聚合物 不含任何反应性基团的B被施加到增强纤维上,所得到的半成品被模塑,并且在获得的模制品中,塑料基质被交联,使得玻璃化转变温度升高并且几乎不溶解。

    Impact-resistant polyoxymethylene molding materials and their preparation
    55.
    发明授权
    Impact-resistant polyoxymethylene molding materials and their preparation 失效
    耐冲击聚甲醛成型材料及其制备方法

    公开(公告)号:US4639488A

    公开(公告)日:1987-01-27

    申请号:US795128

    申请日:1985-11-05

    摘要: Impact-resistant polyoxymethylene molding materials containing(A) from 30 to 95% by weight of one or more polyoxymethylenes and(B) from 5 to 70% by weight of one or more elastomeric graft polymers which are prepared by emulsion polymerization, are dispersed in component A, have a mean particle diameter of from 0.08 to 2 .mu.m and are composed of1. from 60 to 90% by weight of a grafting base of crosslinked polybutadiene in which not more than 30% by weight of the butadiene may be replaced with isoprene, 2,3-dimethylbutadiene, styrene, p-methylstyrene, .alpha.-methylstyrene and/or (meth)acrylonitrile, and2. from 10 to 40% by weight of one or more grafted shells consisting of polymers of styrene and/or methyl methacrylate, in which not more than 15% by weight of the said monomers 2 may be replaced with acrylonitrile or a C.sub.1 -C.sub.8 -alkyl acrylate,the percentages A and B and the percentages 1 and 2 summing to 100, with or without(C) effective amounts of assistants,and a process for their preparation.

    摘要翻译: 含有(A)30至95重量%的一种或多种聚甲醛的抗冲击聚甲醛成型材料和(B)5-70重量%的通过乳液聚合制备的一种或多种弹性体接枝聚合物分散在 组分A的平均粒径为0.08至2μm,并由1.60至90重量%的交联聚丁二烯接枝碱组成,其中不超过30重量%的丁二烯可被替换 与异戊二烯,2,3-二甲基丁二烯,苯乙烯,对甲基苯乙烯,α-甲基苯乙烯和/或(甲基)丙烯腈,以及2.10至40重量%的一种或多种接枝壳,其由苯乙烯和/或 甲基丙烯酸甲酯,其中不超过15重量%的所述单体2可以被丙烯腈或丙烯酸C1-C8烷基酯代替,百分比A和B以及百分比1和2相加到100,有或没有( C)有效数量的助理,以及他们p 赔偿。

    Production of fiber-reinforced materials
    56.
    发明授权
    Production of fiber-reinforced materials 失效
    生产纤维增强材料

    公开(公告)号:US4590104A

    公开(公告)日:1986-05-20

    申请号:US701535

    申请日:1985-02-14

    IPC分类号: D06M15/39 C08J5/24 B05D3/02

    CPC分类号: C08J5/24 C08J2381/02

    摘要: Fiber-reinforced materials are produced by impregnating continuous filaments with a melt of a polyarylene sulfide ketone, preferably one having a reduced viscosity .eta..sub.red of from 0.1 to 0.5 [dl.g.sup.-1 ], shaping the resulting semi-finished product to give a finished article and heating the latter for not less than 15 minutes at above the crystallite melting point of the polyarylene sulfide ketone, the latter undergoing crosslinking and its glass transition temperature Tg increasing by not less than 5.degree. C.

    摘要翻译: 通过用聚亚芳基硫醚酮的熔体浸渍连续长丝来制造纤维增强材料,优选具有0.1至0.5 [dl.g-1]的具有降低的粘度等级的熔融物,使得到的半成品成形 在聚亚芳基硫醚酮的微晶熔点以上,后者进行交联并且其玻璃化转变温度Tg增加不低于5℃,加热后者不少于15分钟。

    Photopolymerizable compositions containing elastomers and photo-curable
elements made therefrom
    57.
    发明授权
    Photopolymerizable compositions containing elastomers and photo-curable elements made therefrom 失效
    含有由其制成的弹性体和可光固化元件的光聚合组合物

    公开(公告)号:US4320188A

    公开(公告)日:1982-03-16

    申请号:US197790

    申请日:1980-10-17

    摘要: Photopolymerizable compositions based on an elastomeric styrene-diene block polymer, one or more photopolymerizable olefinically unsaturated monomers and one or more photopolymerization initiators exhibit improved properties if they contain, as an essential constituent, an elastomeric block copolymer of the general structure A-B-C, where A is a thermoplastic, non-elastomeric polymer block based on styrene compounds and having a second order transition point above +25.degree. C., B is an elastomeric polymer block based on butadiene and/or isoprene and having a second order transition point below -20.degree. C. and C is a polymer block, different from B, having a second order transition point of from -30.degree. C. to +15.degree. C., C being either a homopolymer or copolymer block based on butadiene or isoprene or a random copolymer block based on conjugated dienes and styrene compounds. The photopolymerizable compositions may be used, inter alia, for the production of photo-curable adhesives, resilient and flexible sheet material and, in particular, flexographic relief printing plates.

    摘要翻译: 基于弹性体苯乙烯 - 二烯嵌段聚合物,一种或多种光聚合性烯属不饱和单体和一种或多种光聚合引发剂的光聚合组合物如果含有一般结构ABC的弹性体嵌段共聚物作为必要成分,则表现出改进的性能,其中A为 基于苯乙烯化合物的热塑性非弹性体聚合物嵌段,并且具有高于+ 25℃的二级转变点,B是基于丁二烯和/或异戊二烯并且具有低于-20℃的二级转变点的弹性体聚合物嵌段 C.和C是不同于B的聚合物嵌段,其二级转变点为-30℃至+ 15℃,C为基于丁二烯或异戊二烯的均聚物或共聚物嵌段或无规共聚物 基于共轭二烯和苯乙烯化合物的嵌段。 可光聚合组合物尤其可用于制备光固化粘合剂,弹性和柔性片材,特别是柔性版印刷版。