Carboxamides and their use as herbicides
    51.
    发明授权
    Carboxamides and their use as herbicides 失效
    羧甲酰胺及其作为除草剂的用途

    公开(公告)号:US5201934A

    公开(公告)日:1993-04-13

    申请号:US592287

    申请日:1990-10-03

    摘要: Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, or one of the groups stated for R.sup.1 ;R.sup.3 and R.sup.4 are nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y.dbd.O,S);R.sup.6 is hydrogen, cycloalkyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkenyl or phenyl,phthalimido, tetrahydrophthalimido, succinimido, maleimido, benzotriazolyl ora group --N.dbd.CR.sup.7 R.sup.8, whereR.sup.7 and R.sup.8 are hydrogen or alkyl, and R.sup.8 may also be cycloalkyl, phenyl, or R.sup.7 and R.sup.8 together form a 4- to 7-membered alkylene chain;and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.2 is hydrogen, R.sup.3 is not hydrogen and R.sup.4 is not hydrogen or methyl, and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.4 is hydrogen, R.sup.3 is not hydrogen or R.sup.2 is not one of the following groups: hydrogen, C.sub.1 -C.sub.4 -alkyl, phenyl, 2-(3,4-dimethoxyphenyl)ethyl or 2,5-dichlorothien-3-yl;processes for the manufacture of compounds I and herbicidal agents containing them.

    摘要翻译: 式Ia至Ic的酰胺酰胺其中X是氧或硫; R1是氢或取代或未取代的环烷基或烷基; R2是羟基,烷氧基,氰基烷基,取代或未取代的链烯基,炔基,苯基或萘基,或为R1所述的一个基团; R3和R4是硝基,氰基,卤素,取代或未取代的氨基,烷氧基,烷硫基,取代或未取代的烯基,炔基,苯基,苯氧基或苯硫基,或为R1表示的基团之一; R5是甲酰基,4,5-二氢恶唑-2-基或COYR 6(Y = O,S); R 6是氢,环烷基,取代或未取代的烷基,烯基,炔基,环烯基或苯基,邻苯二甲酰亚氨基,四氢邻苯二甲酰亚胺基,琥珀酰亚胺基,马来酰亚胺基,苯并三唑基或基团-N = CR 7 R 8,其中R 7和R 8是氢或烷基, 环烷基,苯基或R7和R8一起形成4-至7-元亚烷基链; 如果R5是羧基,甲氧基羰基或乙氧基羰基,R2是氢,R3不是氢,R4不是氢或甲基,如果R5是羧基,甲氧基羰基或乙氧基羰基,R4是氢,R3不是氢或R2不是 以下基团:氢,C 1 -C 4 - 烷基,苯基,2-(3,4-二甲氧基苯基)乙基或2,5-二氯噻吩-3-基; 制备化合物I和含有它们的除草剂的方法。

    N-aryltetrahydrophthalimides and herbicidal compositions thereof
    52.
    发明授权
    N-aryltetrahydrophthalimides and herbicidal compositions thereof 失效
    N-三氟甲磺酰嘧啶及其除草剂组合物

    公开(公告)号:US5133799A

    公开(公告)日:1992-07-28

    申请号:US697036

    申请日:1991-05-08

    摘要: R.sup.1 is C.sub.1 -C.sub.4 -alkyl which may carry from one to five halogen atoms or one of the groups stated for X;R.sup.2 is a heteroaromatic structure bonded via a nitrogen atom, which has a 5-membered ring and contains, in addition to carbon ring members, from one to three nitrogen atoms, andR.sup.3 is halogen, C.sub.1 -C.sub.4 -alkylthio, one of the groups stated for R.sup.2 or phenylthio which in turn may carry from one to three of the following radicals: halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy or C.sub.1 -C.sub.4 -alkylthio, and where the phenylthio group may also carry halogen atoms such that the total number of radicals is 4 or 5,and salts thereof which can be used in agriculture, are suitable as herbicides. 2

    摘要翻译: 其中X是氢或卤素; R 1是可以携带1至5个卤素原子的C1-C4-烷基或为X表示的基团之一; R2是通过氮原子键合的杂芳族结构,其具有5元环,并且除了碳环成员之外还含有一个至三个氮原子,并且R 3是卤素,C 1 -C 4 - 烷硫基,其中一个基团 对于R2或苯硫基,其又可以携带1-3个以下基团:卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷氧基或C 1 -C 4 - 烷硫基 并且苯硫基也可以携带卤素原子使得基团的总数为4或5,并且其可用于农业的盐适用作除草剂。

    Herbicidal 3-(3,4,5,6-tetrahydrophthalimido)-cinnamic esters
    55.
    发明授权
    Herbicidal 3-(3,4,5,6-tetrahydrophthalimido)-cinnamic esters 失效
    除草剂3-(3,4,5,6-四氢邻苯二甲酰亚胺基) - 肉桂酯

    公开(公告)号:US5296452A

    公开(公告)日:1994-03-22

    申请号:US525035

    申请日:1990-05-18

    CPC分类号: C07D209/48 A01N37/46

    摘要: 3-(N-3,4,5,6-Tetrahydrophthalimido)-cinnamic esters of the general formula I ##STR1## where n is 1 or 2 and the substituents have the following meanings:R.sup.1 is hydrogen or fluorine,R.sup.2 is halogen,R.sup.3 is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl,R.sup.4 is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or benzyl,R is C.sub.1 -C.sub.4 -alkyl,processes for their manufacture, and herbicidal agents containing them.

    摘要翻译: 3-(N-3,4,5,6-四氢邻苯二甲酰亚氨基) - 肉桂酸酯,其中n为1或2,并且取代基具有以下含义:R 1为氢或氟,R 2为卤素 R3是氢,卤素或C1-C4-烷基,R4是氢,取代或未取代的C1-C6-烷基,C3-C7-环烷基,C3-C6-烯基,C3-C6-炔基或苄基,R是C1- C4烷基,其制备方法和含有它们的除草剂。

    Carboxamides, their preparation and their use as herbicides
    56.
    发明授权
    Carboxamides, their preparation and their use as herbicides 失效
    羧甲酰胺,它们的制备及其作为除草剂的用途

    公开(公告)号:US5258357A

    公开(公告)日:1993-11-02

    申请号:US947538

    申请日:1992-09-21

    摘要: Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, a substituted or unsubstituted 5- to 6-membered heterocyclic structure or one of the groups stated for R.sup.1, orR.sup.1 and R.sup.2 together are a 4- to 7-membered chain which contains, in addition to methylene groups, one of the following groups as ring member: oxygen, sulfur, N-methyl or carbonyl;R.sup.3 and R.sup.4 are each nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, a substituted or unsubstituted 5- to 6 -membered heterocyclic structure, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y=O,S);R.sup.6 is hydrogen, cycloalkyl, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkenyl or phenyl,a 5- to 6-membered heterocyclic structure, phthalimido, tetrahydrophthalimido, succinimido, maleimido, benzotriazolyl ora group --N.dbd.CR.sup.7 R.sup.8, whereR.sup.7 and R.sup.8 are hydrogen or alkyl, and R.sup.8 may also be cycloalkyl, phenyl, furyl or R.sup.7 and R.sup.8 together form a 4- to 7 -membered alkylene chain; and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.2 is hydrogen, R.sup.3 is not hydrogen and R.sup.4 is not hydrogen or methyl, and if R.sup.5 is carboxyl, methoxycarbonyl or ethoxycarbonyl and R.sup.4 is hydrogen, R.sup.3 is not hydrogen or R.sup.2 is not one of the following groups: hydrogen; C.sub.1 -C.sub.4 -alkyl, phenyl; 2-(3,4-dimethoxyphenyl)ethyl or 2,5 -dichlorothien-3-yl;processes for the manufacture of compounds I and herbicidal agents containing them.

    摘要翻译: 式Ia至Ic的酰胺酰胺其中X是氧或硫; R1是氢或取代或未取代的环烷基或烷基; R 2是羟基,烷氧基,氰基烷基,取代或未取代的烯基,炔基,苯基或萘基,取代或未取代的5至6元杂环结构或对于R1表示的基团之一,或R 1和R 2一起为4- 除了亚甲基之外,还含有以下基团之一的环元素:氧,硫,N-甲基或羰基的7-元链; R 3和R 4各自为硝基,氰基,卤素,取代或未取代的氨基,烷氧基,烷硫基,取代或未取代的5-至6-元杂环结构,取代或未取代的烯基,炔基,苯基,苯氧基或苯硫基, R1表示的组; R5是甲酰基,4,5-二氢恶唑-2-基或COYR 6(Y = O,S); R 6是氢,环烷基,取代或未取代的烷基,烯基,炔基,环烯基或苯基,5-至6-元杂环结构,邻苯二甲酰亚氨基,四氢邻苯二甲酰亚胺基,琥珀酰亚胺基,马来酰亚胺基,苯并三唑基或基团-N = CR 7 R 8,其中R 7和R 8 R 8也可以是环烷基,苯基,呋喃基,或者R 7和R 8一起形成4-7个亚烷基链; 如果R5是羧基,甲氧基羰基或乙氧基羰基,R2是氢,R3不是氢,R4不是氢或甲基,如果R5是羧基,甲氧基羰基或乙氧基羰基,R4是氢,R3不是氢或R2不是 以下组:氢; C 1 -C 4 - 烷基,苯基; 2-(3,4-二甲氧基苯基)乙基或2,5-二氯噻吩-3-基; 制备化合物I和含有它们的除草剂的方法。

    5-amino-6-pyridazone derivatives, their preparation and herbicidal
mixtures containing these derivatives
    58.
    发明授权
    5-amino-6-pyridazone derivatives, their preparation and herbicidal mixtures containing these derivatives 失效
    5-氨基-6-吡啶酮衍生物,其制备和除草剂混合物含有这些衍生物

    公开(公告)号:US5123952A

    公开(公告)日:1992-06-23

    申请号:US378798

    申请日:1989-07-12

    摘要: 5-Amino-6-pyridazones of the general formulae Ia and Ib ##STR1## where R.sup.1 is C.sub.1 -C.sub.4 -alkyl which may carry up to three halogen atoms, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or C.sub.3 -C.sub.6 -alkenyl, where these groups may carry up to two phenyl radicals, or C.sub.3 -C.sub.6 -alkynyl, A is --CO-- or --SO.sub.2 --, B is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, where these groups may carry up to three of the following radicals: halogen, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio and/or phenyl; an isocyclic or heterocyclic C.sub.3 -C.sub.7 -cycloalkyl group or an isocyclic or heterocyclic C.sub.3 -C.sub.7 -cycloalkenyl group, where these groups may be fused with one or two cycloalkyl groups of this type or with one or two benzene nuclei, where the total number of ring members is from 3 to 16 and these cyclic radicals may carry up to three of the following groups: halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 - C.sub.6 -alkynyl and/or phenyl; a mononuclear to trinuclear aromatic or heteroaromatic radical which may carry up to three of the following groups: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, cyano, nitro, carbo-C.sub.1 -C.sub.4 -alkoxy, N,N-di-C.sub.1 -C.sub.4 -alkylcarbamido and/or halogen.These compounds are used as herbicidal active ingredients.

    摘要翻译: 通式Ia和Ib的5-氨基-6-哒嗪酮其中R 1是可以带有三个卤素原子的C 1 -C 4 - 烷基,R 2是C 1 -C 4 - 烷基或C 3 -C 6 - 烯基,其中这些基团可以带有两个苯基或C 3 -C 6 - 炔基,A是-CO-或-SO 2 - ,B是C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基 其中这些基团可以带有三个以下基团:卤素,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基和/或苯基; 一个环状或杂环的C 3 -C 7 - 环烷基或者是一个或多个杂环的C 3 -C 7 - 环烯基,其中这些基团可以与一个或两个这样的环烷基或一个或两个苯核稠合, 环成员为3至16,并且这些环状基团可以带有三个以下基团:卤素,C 1 -C 4 - 烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基和/或苯基; 可以携带三个以下基团的单核到三核芳族或杂芳族基团:C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基,C 1 C 1-4烷基亚磺酰基,C 1 -C 4 - 烷基磺酰基,氰基,硝基,C 1 -C 4 - 烷氧基,N,N-二-C 1 -C 4烷基氨基甲酰基和/或卤素。 这些化合物用作除草活性成分。

    2,3-substituted 1,8-naphthyridines, their preparation and their use as
antidotes
    59.
    发明授权
    2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes 失效
    2,3-取代的1,8-萘啶,其制备及其作为抗体使用

    公开(公告)号:US5059240A

    公开(公告)日:1991-10-22

    申请号:US486867

    申请日:1990-03-01

    摘要: 2,3-substituted 1,8-naphthyridines of the general formula I ##STR1## where: R is hydrogen or C.sub.1 -C.sub.4 -alkyl (n=1 or 2)R.sup.1 is amino or substituted amino,XR.sup.5, where X is oxygen or sulfur and R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-((C.sub.1 -C.sub.4)-alkyl, C.sub.5 -C.sub.8 -cycloakyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl-(C.sub.1 -C.sub.3)-alkyl,halogen,isothiorhonium halide,C.sub.1 -C.sub.12 -alkyl,C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkyl,substituted or unsubstituted phenyl or phenyl-(C.sub.1 -C.sub.3)-alkyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, cyano, carboxyl or a group ##STR2## where X is oxygen or sulfur,B is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or alkylthio, amino, mono- or dialkylamino, where each alkyl radical is of 1 to 4 carbon atoms, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl,D is C.sub.1 -C.sub.4 alkyl or NH.sub.2 andR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or alkylcarbonyl,or R.sup.1 and R.sup.2 together are --NH--N.dbd.C(CH.sub.2)--,and their environmentally tolerated saltswith the proviso that R.sup.2 is not cyano, carboxyl or a carboxamido or carboxylic ester group when R.sup.1 is methyl, hydroxyl or amino (NH.sub.2), processes for their manufacture, and herbicidal agents containing a naphthyridine I as safener and at least one herbicidal active ingredient selected from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives andb) cyclohexenone derivatives.

    摘要翻译: 具有通式I的2,3-取代的1,8-萘啶,其中:R是氢或C 1 -C 4 - 烷基(n = 1或2)R 1是氨基或取代的氨基,XR 5,其中X是氧 或(C 1 -C 4) - 烷基,C 5 -C 8 - 环烷基,取代或未取代的苯基,取代或未取代的苯基 - (C 1 -C 3) - 烷基,卤素,异卤卤化物,C 1 -C 12 - 烷基,C 1 -C 4 - 烷氧基羰基-C 1 -C 4烷基,取代或未取代的苯基或苯基 - (C 1 -C 3) - 烷基,R 2为C 1 -C 4烷基,氰基, 羧基或基团,其中X为氧或硫,B为C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基或烷硫基,氨基,单或二烷基氨基,其中每个烷基为1至4个碳原子,吗啉代 ,哌啶基,氯,溴或取代或未取代的苯基,D是C 1 -C 4烷基或NH 2,R 6是氢,C 1 -C 8 - 烷基或烷基羰基,或者R 1和R 2一起是-NH-N = C(CH 2) 其环境耐受性盐,条件是R2不是氰基,羧基或a 当R1是甲基,羟基或氨基(NH2)时,羧酰胺基或羧酸酯基,其制备方法和含有萘啶I作为安全剂的除草剂和至少一种除草活性成分,其选自a)2-(4 - 杂芳氧基) - 或2-(4-芳氧基) - 苯氧基乙酸衍生物和b)环己烯酮衍生物。

    Thiophene-2-carboxylic acid derivatives, their preparation and their use
for controlling undesirable plant growth
    60.
    发明授权
    Thiophene-2-carboxylic acid derivatives, their preparation and their use for controlling undesirable plant growth 失效
    噻吩-2-羧酸衍生物,其制备及其用于控制​​不期望的植物生长的用途

    公开(公告)号:US5034049A

    公开(公告)日:1991-07-23

    申请号:US463163

    申请日:1990-01-09

    CPC分类号: C07D333/38 A01N43/10

    摘要: Thiophene-2-carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 to R.sup.3 are each hydrogen, halogen, branched or straight-chain C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -haloalkoxy, nitro, cyano, unsubstituted phenyl or phenyl which is mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.5 -haloalkoxy;X is --OR.sup.4 or --NH--OR.sup.5,R.sup.4 being branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen; andR.sup.5 being branched or straight-chain C.sub.1 -C.sub.5 -alkyl which is unsubstituted or substituted by halogen, or branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen;with the proviso that R.sup.4 is not propargyl when R.sup.2 and R.sup.3 are both hydrogen or when R.sup.2 is halogen or R.sup.3 is chlorine, methyl or methoxy.The compounds I are suitable for combating the growth of unwanted plants.

    摘要翻译: 通式I的噻吩-2-羧酸衍生物其中R 1至R 3各自为氢,卤素,支链或直链C 1 -C 6 - 烷基,C 1 -C 8 - 烷氧基,C 1 -C 6 - 卤代烷基,C 1 C 1-6卤代烷氧基,硝基,氰基,未取代的苯基或被C 1 -C 4 - 烷基,卤素,C 1 -C 5 - 卤代烷基,C 1 -C 4 - 烷氧基或C 1 -C 5 - 卤代烷氧基单 - X为-OR4或-NH-OR5,R4为未取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 并且R 5是未被取代或被卤素取代的支链或直链C 1 -C 5 - 烷基,或未被取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 条件是当R 2和R 3均为氢时或R 2为卤素或R 3为氯,甲基或甲氧基时,R 4不是炔丙基。 化合物I适用于对抗不想要的植物的生长。