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    INTEGRATION OF OTO PROCESS WITH DIRECT DME SYNTHESIS
    51.
    发明申请
    INTEGRATION OF OTO PROCESS WITH DIRECT DME SYNTHESIS 有权
    OTO过程与直接DME合成的整合

    公开(公告)号：US20090326298A1

    公开(公告)日：2009-12-31

    申请号：US12164946

    申请日：2008-06-30

    申请人： Andrea G. Bozzano

    发明人： Andrea G. Bozzano

    IPC分类号： C07C1/02 ,  B01J10/00

    CPC分类号： C07C1/20 ,  Y02P30/42 ,  Y10S585/91 ,  C07C11/02

    摘要： Processes and systems for utilizing products from DME synthesis in converting oxygenates to olefins are provided that include removing a DME-reactor effluent from a DME reactor, wherein the DME effluent includes DME, water, and methanol; separating carbon dioxide gas from the DME reactor effluent in a liquid gas separator to produce a degassed effluent stream. The processes and systems can include feeding the degassed effluent stream to an oxygenate to olefin reactor to produce an olefin containing effluent, wherein the olefin containing effluent further includes oxygenates. Alternatively, the processes and systems can include providing the degassed effluent stream to a DME column to produce a DME feedstock and a solvent stream, wherein the solvent stream includes methanol and water; feeding the DME feedstock to an oxygenate to olefin reactor to produce an olefin containing effluent, wherein the olefin containing effluent further includes oxygenates; and contacting at least a portion of the olefin containing effluent with the solvent stream in a solvent contacting zone to produce an olefin containing raffinate stream and an oxygenate containing extract.

    摘要翻译： 提供了利用DME合成产物将氧化物转化为烯烃的方法和系统，其包括从DME反应器中除去DME反应器流出物，其中DME流出物包括DME，水和甲醇; 在液体气体分离器中分离来自DME反应器流出物的二氧化碳气体以产生脱气的流出物流。 该方法和系统可以包括将脱气的流出物流进料到含氧化合物至烯烃反应器以产生含烯烃的流出物，其中含烯烃的流出物还包括含氧化合物。 或者，方法和系统可以包括将脱气流出物流提供到DME柱以产生DME原料和溶剂流，其中溶剂流包括甲醇和水; 将DME原料进料到含氧化合物至烯烃反应器以产生含烯烃的流出物，其中含烯烃的流出物还包含含氧化合物; 以及使至少一部分含烯烃流出物与溶剂流在溶剂接触区中接触以产生含烯烃的萃余液流和含氧化合物的萃取物。

    Integrated Processing of Methanol to Olefins
    55.
    发明申请
    Integrated Processing of Methanol to Olefins 审中-公开
    甲醇与烯烃的综合加工

    公开(公告)号：US20090005624A1

    公开(公告)日：2009-01-01

    申请号：US12129020

    申请日：2008-05-29

    申请人： Andrea G. Bozzano

    发明人： Andrea G. Bozzano

    IPC分类号： C07C1/20

    CPC分类号： C07C41/09 ,  C07C1/20 ,  C07C6/04 ,  C07C2523/28 ,  C07C2523/30 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/06 ,  C07C43/043

    摘要： Processing schemes and arrangements for the production of olefins and, more particularly, for the production of light olefins from a methanol feedstock are provided. Such processing schemes and arrangements integrate oxygenate conversion at higher pressures and with subsequent heavy olefins conversion processing to produce additional light olefin products. In particular, this invention provides an efficient method for removal of heavy oxygenate materials such as aldehydes and ketones through the recirculation of a mixed water/methanol solvent from a reactor in which methanol is converted into dimethyl ether and water.

    摘要翻译： 提供了用于生产烯烃，特别是用于从甲醇原料生产轻质烯烃的加工方案和装置。 这种处理方案和装置将氧化合物转化率与较高压力和随后的重质烯烃转化处理相结合以产生额外的轻质烯烃产物。 特别地，本发明提供了一种通过混合水/甲醇溶剂从甲醇转化成二甲醚和水的反应器再循环来除去重含氧物质如醛和酮的有效方法。

    Aromatics Co-Production in a Methanol-To-Propylene Unit
    56.
    发明申请
    Aromatics Co-Production in a Methanol-To-Propylene Unit 有权
    甲醇 - 丙烯单元中的芳烃共生产

    公开(公告)号：US20080161620A1

    公开(公告)日：2008-07-03

    申请号：US11955610

    申请日：2007-12-13

    申请人： Andrea G. Bozzano ,  Timur V. Voskoboynikov ,  Tom N. Kalnes ,  Paul T. Barger ,  Gavin P. Towler ,  Bryan K. Glover

    发明人： Andrea G. Bozzano ,  Timur V. Voskoboynikov ,  Tom N. Kalnes ,  Paul T. Barger ,  Gavin P. Towler ,  Bryan K. Glover

    IPC分类号： C07C15/04 ,  C07C15/08 ,  C07C1/02 ,  B01J8/04

    CPC分类号： C07C2/66 ,  C07C1/24 ,  C07C2/864 ,  C07C6/126 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06 ,  C07C15/08

    摘要： The present invention provides a reactor system having: (1) a first reactor receiving an oxygenate component and a hydrocarbon component and capable of converting the oxygenate component into a light olefin and the hydrocarbon component into alkyl aromatic compounds; (2) a separator system for providing a first product stream containing a C3 olefin, a second stream containing a C7 aromatic, and a third stream containing C8 aromatic compounds; (3) a first line connecting the separator to the inlet of the first reactor for conveying the second stream to the first reactor; (4) a second line in fluid communication with the separator system for conveying the C3 olefin to a propylene recovery unit, and (4) a third line in fluid communication with the separator system for conveying the C8 aromatic compounds to a xylene recovery unit.

    摘要翻译： 本发明提供了一种反应器系统，其具有：（1）第一反应器，其接收含氧化合物组分和烃组分，并且能够将含氧化合物组分转化为轻质烯烃并将烃组分转化为烷基芳族化合物; （2）一种分离器系统，用于提供含有C 3 O 3烯烃的第一产物流，含有C 7芳族的第二料流和含有C 3 O 3芳烃的第三料流， 8芳族化合物; （3）将分离器连接到第一反应器的入口的第一管线，用于将第二流输送到第一反应器; （4）与用于将C 3 O 3烯烃输送到丙烯回收单元的分离器系统流体连通的第二管线，以及（4）与分离器系统流体连通的第三管线，用于输送C 将芳香族化合物加入到二甲苯回收装置中。

    Dehydrogenation process using layered catalyst composition
    58.
    发明授权
    Dehydrogenation process using layered catalyst composition 失效
    使用层状催化剂组合物的脱氢方法

    公开(公告)号：US06756515B2

    公开(公告)日：2004-06-29

    申请号：US10281420

    申请日：2002-10-25

    申请人： Dean E. Rende ,  Andrew W. Broerman ,  Andrea G. Bozzano ,  R. Joe Lawson ,  Karl Z. Steigleder ,  Masao Takayama

    发明人： Dean E. Rende ,  Andrew W. Broerman ,  Andrea G. Bozzano ,  R. Joe Lawson ,  Karl Z. Steigleder ,  Masao Takayama

    IPC分类号： C07C532

    CPC分类号： B01J23/626 ,  B01J37/0223 ,  C07C5/3337 ,  C07C2523/14 ,  C07C2523/42

    摘要： This invention relates to a dehydrogenation process using a layered catalyst composition. The catalyst composition comprises an inner core such as alpha-alumina, and an outer layer bonded to the inner core composed of an outer refractory inorganic oxide such as gamma-alumina. The outer layer has uniformly dispersed thereon a platinum group metal such as platinum and a promoter metal such as tin. The composition also contains a modifier metal such as lithium. The catalyst composition shows improved durability and selectivity for dehydrogenating hydrocarbons, especially at dehydrogenation conditions comprising a low water concentration.

    摘要翻译： 本发明涉及使用层状催化剂组合物的脱氢方法。 催化剂组合物包含内核如α-氧化铝，和外层结合到内核，由外部难熔无机氧化物如γ-氧化铝组成。 外层在其上均匀分散有铂族金属如铂和助催化剂金属如锡。 该组合物还含有改性金属如锂。 催化剂组合物显示改进的耐烃性和对脱氢烃的选择性，特别是在包含低水浓度的脱氢条件下。