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    Long life lithium batteries with stabilized electrodes
    51.
    发明申请
    Long life lithium batteries with stabilized electrodes 有权
    长寿命的锂电池具有稳定的电极

    公开(公告)号：US20050019670A1

    公开(公告)日：2005-01-27

    申请号：US10857365

    申请日：2004-05-28

    申请人： Khalil Amine ,  Jaekook Kim ,  Donald Vissers

    发明人： Khalil Amine ,  Jaekook Kim ,  Donald Vissers

    IPC分类号： H01M4/52 ,  H01M4/525 ,  H01M6/16 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/36 ,  H01M10/40 ,  H01M4/50 ,  H01M4/58 ,  H01M4/60

    CPC分类号： H01M10/0567 ,  H01M4/525 ,  H01M6/166 ,  H01M10/052 ,  H01M10/0568

    摘要： The present invention relates to non-aqueous electrolytes having stabilization additives and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, a first additive that is a substituted or unsubstituted organoamine, substituted or unsubstituted alkane, substituted or unsubstituted alkene, or substituted or unsubstituted aryl compound, and/or a second additive that is a metal(chelato)borate. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes, the new electrolytes provide batteries with improved calendar and cycle life.

    摘要翻译： 本发明涉及具有稳定添加剂的非水电解质和含有它们的电化学装置。 因此，本发明提供了包含碱金属盐，极性非质子溶剂，作为取代或未取代的有机胺的第一添加剂，取代或未取代的烷烃，取代或未取代的烯烃或取代或未取代的芳基化合物的电解质，和/或第二 作为金属（螯合）硼酸盐的添加剂。 当用于例如锂锰氧化物尖晶石电极的电化学装置中时，新的电解质提供具有改善的日历和循环寿命的电池。

    Long life lithium batteries with stabilized electrodes
    53.
    发明授权
    Long life lithium batteries with stabilized electrodes 有权
    长寿命的锂电池具有稳定的电极

    公开(公告)号：US09012096B2

    公开(公告)日：2015-04-21

    申请号：US11338902

    申请日：2006-01-24

    申请人： Khalil Amine ,  Jun Liu ,  Donald R. Vissers ,  Wenquan Lu

    发明人： Khalil Amine ,  Jun Liu ,  Donald R. Vissers ,  Wenquan Lu

    IPC分类号： H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

    CPC分类号： H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

    摘要： The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In certain electrolytes, the alkali metal salt is a bis(chelato)borate and the additives include substituted or unsubstituted linear, branched or cyclic hydrocarbons comprising at least one oxygen atom and at least one aryl, alkenyl or alkynyl group. In other electrolytes, the additives include a substituted aryl compound or a substituted or unsubstituted heteroaryl compound wherein the additive comprises at least one oxygen atom. There are also provided methods of making the electrolytes and batteries employing the electrolytes. The invention also provides for electrode materials. Cathodes of the present invention may be further stabilized by surface coating the particles of the spinel or olivine with a material that can neutralize acid or otherwise lessen or prevent leaching of the manganese or iron ions. In some embodiments the coating is polymeric and in other embodiments the coating is a metal oxide such as ZrO2, TiO2, ZnO, WO3, Al2O3, MgO, SiO2, SnO2 AlPO4, Al(OH)3, a mixture of any two or more thereof.

    摘要翻译： 本发明涉及具有电极稳定添加剂，稳定电极和含有这些电极的电化学装置的非水电解质。 因此，本发明提供了含有碱金属盐，极性非质子溶剂和电极稳定添加剂的电解质。 在某些电解质中，碱金属盐是双（螯合）硼酸盐，并且添加剂包括取代或未取代的包含至少一个氧原子和至少一个芳基，烯基或炔基的直链，支链或环状烃。 在其他电解质中，添加剂包括取代的芳基化合物或取代或未取代的杂芳基化合物，其中添加剂包含至少一个氧原子。 还提供了使用电解质的电解质和电池的制造方法。 本发明还提供电极材料。 通过用可以中和酸或以其它方式减少或防止锰或铁离子浸出的材料表面涂覆尖晶石或橄榄石的颗粒，可以进一步稳定本发明的阴极。 在一些实施方案中，涂层是聚合物，并且在其它实施方案中，涂层是诸如ZrO 2，TiO 2，ZnO，WO 3，Al 2 O 3，MgO，SiO 2，SnO 2，AlPO 4，Al（OH）3的金属氧化物，其任何两种或更多种的混合物 。

    Lithium-ion batteries with intrinsic pulse overcharge protection
    55.
    发明授权
    Lithium-ion batteries with intrinsic pulse overcharge protection 有权
    具有固有脉冲过充保护的锂离子电池

    公开(公告)号：US08367253B2

    公开(公告)日：2013-02-05

    申请号：US11345947

    申请日：2006-02-02

    申请人： Zonghai Chen ,  Khalil Amine

    发明人： Zonghai Chen ,  Khalil Amine

    IPC分类号： H01M6/16 ,  H01M4/13

    CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1391 ,  H01M4/5825 ,  H01M2004/028

    摘要： The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

    摘要翻译： 本发明一般涉及锂可充电电池领域，更具体地涉及具有改进的高速率脉冲过充电保护的锂离子电池的正电极设计。 因此，本发明提供了含有包含至少一种初级正材料和至少一种次级正材料的阴极的电化学装置; 阳极; 和含有氧化还原穿梭添加剂的非水电解质; 其中所述氧化还原穿梭添加剂的氧化还原电位大于所述初级正材料的氧化还原电位; 氧化还原穿梭添加剂的氧化还原电位低于次级正材料的氧化还原电位; 并且氧化还原穿梭添加剂至少达到次级正材料的氧化还原电位稳定。