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    Preparation of 1-aryloxy-methyl ketones
    55.
    发明授权
    Preparation of 1-aryloxy-methyl ketones 失效
    1-芳氧基 - 甲基酮的制备

    公开(公告)号：US4399309A

    公开(公告)日：1983-08-16

    申请号：US335942

    申请日：1981-12-30

    申请人： Manfred Jautelat ,  Jorg Stetter ,  Dieter Arlt

    发明人： Manfred Jautelat ,  Jorg Stetter ,  Dieter Arlt

    IPC分类号： C07C49/175 ,  C07C43/225 ,  C07C45/00 ,  C07C45/42 ,  C07C49/255 ,  C07C49/35 ,  C07C67/00 ,  C07C201/00 ,  C07C205/37 ,  C07C205/39 ,  C07C45/51

    CPC分类号： C07C41/16 ,  C07C45/42

    摘要： A process for the preparation of a 1-aryloxy-methyl ketone of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is hydrogen, optionally substituted alkyl, alkenyl, alkynyl or optionally substituted aryl, orR.sup.1 and R.sup.2 together are an alkylene chain,R.sup.4 each independently is halogen, alkyl, alkoxy, optionally substituted aryl or nitro, andn is 0, 1, 2 or 3,comprising hydrolyzing a 1-halogeno-2-aryloxy-1-alkene of the formula ##STR2## in which Hal is chlorine or bromine, under acidic conditions at a temperature from about 20.degree. to 150.degree. C. until it is about 95 to 100% complete, adding a base, and then bringing the reaction to completion under weakly alkaline conditions at about 20.degree. to 150.degree. C. Advantageously all stages of the reaction are effected in a single vessel at a temperature from about 40.degree. to 100.degree. C. and in the presence of an inert organic solvent, optionally in admixture with water as a solution or as a two-phase system, about 1 mol of a monobasic acid and 2 mols of alkali metal carbonate being employed per mol of the 1-halogeno-2-aryloxy-1-alkene. The end products are known intermediates for fungicides.

    摘要翻译： 制备式“IMAGE”的1-芳氧基甲基酮的方法，其中R 1，R 2和R 3各自独立地为氢，任选取代的烷基，烯基，炔基或任选取代的芳基，或者R 1和R 2一起是 亚烷基链，R4各自独立地为卤素，烷基，烷氧基，任选取代的芳基或硝基，n为0,1,2或3，包括水解式IMAMA的1-卤代-2-芳氧基-1-烯烃， 其中Hal为氯或溴，在酸性条件下，在约20℃至150℃的温度下，直到其完全达到约95-100％，加入碱，然后使反应在弱碱性条件下在约 有利的是，反应的所有阶段在单一容器中在约40℃至100℃的温度下进行，并且在惰性有机溶剂的存在下，任选与水作为溶液的混合物或 作为两相体系，约1摩尔一元酸 每摩尔1-卤代-2-芳氧基-1-烯烃使用2摩尔碱金属碳酸盐。 最终产品是已知的杀真菌剂中间体。

    Acylated triazolyl-.gamma.-fluoropinacolyl derivatives and their use as fungicides
    58.
    发明授权
    Acylated triazolyl-.gamma.-fluoropinacolyl derivatives and their use as fungicides 失效
    酰化三唑基-γ-氟哌啶基衍生物及其作为杀真菌剂的用途

    公开(公告)号：US4359470A

    公开(公告)日：1982-11-16

    申请号：US187866

    申请日：1980-09-17

    申请人： Wolfgang Kramer ,  Karl Buchel ,  Jorg Stetter ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    发明人： Wolfgang Kramer ,  Karl Buchel ,  Jorg Stetter ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    IPC分类号： A01N43/653 ,  A01N47/06 ,  A01N47/12 ,  A01N47/20 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64 ,  C07F1/08 ,  C07F3/06

    CPC分类号： C07D231/12 ,  A01N43/653 ,  A01N47/06 ,  A01N47/12 ,  A01N47/20 ,  C07D233/56 ,  C07D249/08

    摘要： Fungicidally active acylated triazolyl-.gamma.-fluoropinacolyl derivatives of the formula ##STR1## in which Az represents 1,2,4-triazol-1-yl or 1,2,4-triazol-4-yl,R represents alkyl, alkenyl, alkynyl, alkoxy, alkoxyalkyl, cycloalkyl, halogenoalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, optionally substituted phenoxyalkyl, alkylamino, dialkylamino, optionally substituted phenylamino, halogenoalkylamino, alkoxycarbonylamino or alkoxyalkylamino,X represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl, cyano or nitro, each Z being selected independently, andn represents 0 or an interger from 1 to 5, or a physiologically acceptable acid addition salt or metal salt complex thereof.

    摘要翻译： 其中Az表示1,2,4-三唑-1-基或1,2,4-三唑-4-基的式“IMAGE”的杀真菌活性的酰化三唑基-γ-氟磷酰基吲哚基衍生物，R表示烷基，烯基，炔基 ，烷氧基，烷氧基烷基，环烷基，卤代烷基，任选取代的苯基，任选取代的苯基烷基，任选取代的苯氧基烷基，烷基氨基，二烷基氨基，任选取代的苯基氨基，卤代烷基氨基，烷氧基羰基氨基或烷氧基烷基氨基，X表示卤素，烷基，环烷基，烷氧基，卤代烷基，烷硫基， ，任选取代的苯基，任选取代的苯氧基，任选取代的苯基烷基，氰基或硝基，每个Z独立选择，n代表0或1至5的整数，或其生理上可接受的酸加成盐或金属盐络合物。