公开(公告)号：US20080063946A1

公开(公告)日：2008-03-13

申请号：US11575533

申请日：2005-09-21

申请人： Tadahiko Kubota ,  Hiroyuki Yamaguchi ,  Masayuki Ihara

发明人： Tadahiko Kubota ,  Hiroyuki Yamaguchi ,  Masayuki Ihara

IPC分类号： H01M10/40

CPC分类号： H01M10/0569 ,  H01M4/0404 ,  H01M4/0495 ,  H01M4/134 ,  H01M4/1395 ,  H01M10/052 ,  H01M10/0567 ,  H01M2300/0042 ,  Y02E60/122

摘要： An electrolytic solution and a battery capable of improving high temperature characteristics are provided. A separator (23) is impregnated with an electrolytic solution. The electrolytic solution includes a solvent including 4,5-difluoro-1,3-dioxolane-2-one. The content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 wt % to 50 wt %, or in the case where 4,5-difluoro-1,3-dioxolane-2-one is mixed and used with 4-fluoro-1,3-dioxolane-2-one, the content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 vol ppm to 2000 vol ppm.

摘要翻译： 提供了能够提高高温特性的电解液和电池。 用电解液浸渍分离器（23）。 电解液包括包含4,5-二氟-1,3-二氧戊环-2-酮的溶剂。 4,5-二氟-1,3-二氧戊环-2-酮的含量优选在5重量％〜50重量％的范围内，或者在4,5-二氟-1,3-二氧戊环-2 - 酮混合并与4-氟-1,3-二氧戊环-2-酮一起使用，4,5-二氟-1,3-二氧戊环-2-酮的含量优选在5体积ppm至2000的范围内 体积ppm。

公开(公告)号：US5237031A

公开(公告)日：1993-08-17

申请号：US652759

申请日：1991-02-08

申请人： Tadahiko Kubota ,  Shoichiro Yasunami

发明人： Tadahiko Kubota ,  Shoichiro Yasunami

IPC分类号： H01B1/12 ,  H01M6/16 ,  H01M10/052 ,  H01M10/0565

CPC分类号： H01M10/052 ,  H01B1/122 ,  H01M10/0565 ,  H01M6/164

摘要： An organic solid electrolyte is disclosed, which comprises a high molecular compound having a recurring unit represented by following formula (I), a nonprotonic polar solvent, and a salt of a metal ion belonging to group Ia or group IIa of the Periodic Table: ##STR1## wherein R.sub.1 represents a hydrogen atom, a lower alkyl group, a cyano group, or a chlorine atom; R.sub.2 represents a lower alkyl group, an alkenyl group, an aryl group, or an aralkyl group; X represents --CO.sub.2 --, ##STR2## --OCO--, or --O--, (wherein R.sub.3 represents a hydrogen atom or a lower alkyl group); L represents an alkylene group; a represents 0 or 1; and m represents an integer of from 0 to 5.

摘要翻译： 公开了一种有机固体电解质，其包含具有由下式（I）表示的重复单元的高分子化合物，非质子极性溶剂和属于元素周期表第Ia族或第IIa族的金属离子的盐： （I）其中R1表示氢原子，低级烷基，氰基或氯原子; R2表示低级烷基，烯基，芳基或芳烷基; X表示-CO 2 - ， - OCO-或-O-，（其中R 3表示氢原子或低级烷基）。 L表示亚烷基; a表示0或1; m表示0〜5的整数。

公开(公告)号：US09825337B2

公开(公告)日：2017-11-21

申请号：US13378523

申请日：2010-06-17

申请人： Haruo Watanabe ,  Tomoyo Ooyama ,  Shunsuke Saito ,  Shinichi Katayama ,  Hideki Nakai ,  Yoshihiro Kudo ,  Yoshikazu Kato ,  Muneaki Ando ,  Koji Morita ,  Ichiro Yamada ,  Nobuya Okano ,  Noritoshi Araki ,  Shuhei Sugita ,  Kunihiko Hayashi ,  Yosuke Hosoya ,  Tadahiko Kubota ,  Shigeru Fujita

发明人： Haruo Watanabe ,  Tomoyo Ooyama ,  Shunsuke Saito ,  Shinichi Katayama ,  Hideki Nakai ,  Yoshihiro Kudo ,  Yoshikazu Kato ,  Muneaki Ando ,  Koji Morita ,  Ichiro Yamada ,  Nobuya Okano ,  Noritoshi Araki ,  Shuhei Sugita ,  Kunihiko Hayashi ,  Yosuke Hosoya ,  Tadahiko Kubota ,  Shigeru Fujita

IPC分类号： H01M4/131 ,  H01M6/14 ,  H01M10/42 ,  C01G51/00 ,  C01G53/00 ,  H01M2/16 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0587

CPC分类号： H01M10/4235 ,  C01G51/42 ,  C01G53/006 ,  C01G53/42 ,  C01P2002/52 ,  C01P2002/82 ,  C01P2002/89 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/40 ,  H01M2/16 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/621 ,  H01M4/623 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0587

摘要： A battery is composed of a positive electrode in which a positive electrode active material layer including a positive electrode active material is formed on a positive electrode collector, a negative electrode in which a negative electrode active material layer including a negative electrode active material is formed on a negative electrode collector, a separator provided between the positive electrode and the negative electrode, and an electrolyte impregnated in the separator. The battery further includes at least one of a heteropoly acid and a heteropoly acid compound as an additive at least in one of the positive electrode, the negative electrode, the separator, and the electrolyte.

公开(公告)号：US09742037B2

公开(公告)日：2017-08-22

申请号：US13011067

申请日：2011-01-21

申请人： Toru Odani ,  Akira Yamaguchi ,  Masahiro Miyamoto ,  Tadahiko Kubota

发明人： Toru Odani ,  Akira Yamaguchi ,  Masahiro Miyamoto ,  Tadahiko Kubota

IPC分类号： H01M4/13 ,  H01M10/0569 ,  H01M4/131 ,  H01M4/36 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0567

CPC分类号： H01M10/0569 ,  H01M4/131 ,  H01M4/366 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0567 ,  H01M2300/004 ,  Y02E60/122

摘要： A nonaqueous electrolyte battery includes: a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the positive electrode contains, as a positive electrode active material, a positive electrode material having a surface composition represented by the following formula (I); the nonaqueous electrolyte contains a halogenated carbonate represented by any of the following formulae (1) to (2) and an alkylbenzene represented by the following formula (3); a content of the halogenated carbonate is 0.1% by mass or more and not more than 50% by mass relative to the nonaqueous electrolyte; and a content of the alkylbenzene is 0.1% by mass or more and not more than 5% by mass relative to the nonaqueous electrolyte

公开(公告)号：US09685661B2

公开(公告)日：2017-06-20

申请号：US13452333

申请日：2012-04-20

申请人： Ichiro Yamada ,  Hideki Nakai ,  Toshio Nishi ,  Tadahiko Kubota

发明人： Ichiro Yamada ,  Hideki Nakai ,  Toshio Nishi ,  Tadahiko Kubota

IPC分类号： H01M6/16 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0568 ,  H01M4/13 ,  H01M10/0569 ,  H01M2/16

CPC分类号： H01M10/0525 ,  H01M2/1686 ,  H01M4/13 ,  H01M4/602 ,  H01M4/62 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/122 ,  Y02T10/7011

摘要： A secondary battery includes a cathode, an anode, and an electrolytic solution. The anode or the electrolytic solution, or both contain a metal salt including an unsaturated carbon bond.

公开(公告)号：US09543613B2

公开(公告)日：2017-01-10

申请号：US13602961

申请日：2012-09-04

申请人： Masayuki Ihara ,  Tadahiko Kubota

发明人： Masayuki Ihara ,  Tadahiko Kubota

IPC分类号： H01M6/12 ,  H01M10/052 ,  H01M10/0567 ,  H01M2/02 ,  H01M10/0568 ,  H01M10/48

CPC分类号： H01M10/0568 ,  B60L11/1851 ,  H01M2/0207 ,  H01M2/0217 ,  H01M2/1022 ,  H01M2/1077 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/48 ,  H01M10/486 ,  H01M2220/20 ,  H01M2300/0037 ,  Y02E60/122 ,  Y02T10/7011

摘要： A secondary battery includes: a cathode, an anode, and a nonaqueous electrolytic solution in a package member having a flat surface, in which the nonaqueous electrolytic solution includes a methylene cyclic carbonate represented by an expression (1): where R1 and R2 each are a hydrogen group, a halogen group, a monovalent hydrocarbon group, a monovalent halogenated hydrocarbon group, an oxygen-containing monovalent hydrocarbon group, or an oxygen-containing monovalent halogenated hydrocarbon group, and R1 and R2 may be bonded to each other.

摘要翻译： 二次电池包括：具有平坦表面的封装构件中的阴极，阳极和非水电解液，其中非水电解液包含由式（1）表示的亚甲基环状碳酸酯：其中R1和R2各自为 氢原子，卤素基团，一价烃基，一价卤代烃基，含氧一价烃基或含氧一价卤代烃基，R 1和R 2可以相互结合。

公开(公告)号：US09509015B2

公开(公告)日：2016-11-29

申请号：US12708227

申请日：2010-02-18

申请人： Shunsuke Saito ,  Masayuki Ihara ,  Atsumichi Kawashima ,  Takehiko Tanaka ,  Tadahiko Kubota

发明人： Shunsuke Saito ,  Masayuki Ihara ,  Atsumichi Kawashima ,  Takehiko Tanaka ,  Tadahiko Kubota

IPC分类号： H01M6/04 ,  H01M10/0525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M4/02

CPC分类号： H01M10/0525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/021 ,  H01M2300/0025 ,  Y02E60/122

摘要： A battery capable of improving the cycle characteristics even if the thickness of an anode active material layer is increased is provided. The battery includes a cathode, an anode and an electrolytic solution. The anode has an anode active material layer on an anode current collector, and the anode active material layer contains a carbon material and has a thickness of 30 μm or more. The electrolytic solution contains a solvent and an electrolyte salt, and the solvent contains at least one of sulfone compounds such as a cyclic disulfonic acid anhydride.

摘要翻译： 提供即使增加阳极活性物质层的厚度也能够改善循环特性的电池。 电池包括阴极，阳极和电解液。 阳极在阳极集电体上具有负极活性物质层，阳极活性物质层含有碳材料，其厚度为30μm以上。 电解液含有溶剂和电解质盐，溶剂含有环状二磺酸酐等砜化合物中的至少一种。

公开(公告)号：US09190666B2

公开(公告)日：2015-11-17

申请号：US11846819

申请日：2007-08-29

申请人： Tadahiko Kubota ,  Momoe Adachi ,  Shigeru Fujita

发明人： Tadahiko Kubota ,  Momoe Adachi ,  Shigeru Fujita

IPC分类号： H01M4/587 ,  H01M4/04 ,  H01M4/133 ,  H01M4/38 ,  H01M10/0565 ,  H01M10/0568 ,  H01M4/02

CPC分类号： H01M4/587 ,  H01M4/0404 ,  H01M4/0421 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/38 ,  H01M10/0565 ,  H01M10/0568 ,  H01M2004/021 ,  Y02E60/122

摘要： The invention provides a battery, which can improve battery characteristics such as high temperature storage characteristics. The battery comprises a battery device, wherein a cathode and an anode are wound with a separator in between. The anode contains an anode material capable of inserting and extracting Li as an anode active material. An electrolytic solution is impregnated in the separator. The electrolytic solution contains a solvent, and an electrolyte salt such as Li[B(CF3)4] dissolved in the solvent, which is expressed by a chemical formula of Li[B(RF1)(RF2)(RF3)RF4]. RF1, RF2, RF3, and RF4 represent a perfluoro alkyl group whose number of fluorine or carbon is from 1 to 12, respectively. Consequently, high temperature storage characteristics are improved.

摘要翻译： 本发明提供一种电池，其可以改善诸如高温存储特性的电池特性。 电池包括电池装置，其中阴极和阳极在其间缠绕有隔膜。 阳极包含能够插入和提取Li作为负极活性材料的阳极材料。 电解液浸渍在隔膜中。 电解液含有溶剂，溶解于Li [B（RF1）（RF2）（RF3）RF4]的化学式表示的溶剂中的Li [B（CF 3）4]等电解质盐。 RF1，RF2，RF3和RF4分别表示氟或碳数为1〜12的全氟烷基。 因此，提高了高温储存特性。

公开(公告)号：US09083059B2

公开(公告)日：2015-07-14

申请号：US13258109

申请日：2010-03-18

申请人： Yuko Hayakawa ,  Tadahiko Kubota ,  Masayuki Ihara

发明人： Yuko Hayakawa ,  Tadahiko Kubota ,  Masayuki Ihara

IPC分类号： H01M10/052 ,  H01M10/056 ,  H01M10/0566 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M4/133 ,  H01M4/134 ,  H01M4/1393 ,  H01M4/1395 ,  H01M4/36 ,  H01M4/38 ,  H01M4/587

CPC分类号： H01M10/0569 ,  H01M4/133 ,  H01M4/134 ,  H01M4/1393 ,  H01M4/1395 ,  H01M4/364 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/405 ,  H01M4/525 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M2220/30 ,  H01M2300/0025 ,  H01M2300/0034 ,  H01M2300/0037 ,  H01M2300/004 ,  Y02E60/122

摘要： A secondary battery capable of improving cycle characteristics is provided. The secondary battery includes a cathode 21, an anode 22, and an electrolytic solution. A separator 23 provided between the cathode 21 and the anode 22 is impregnated with the electrolytic solution. The electrolytic solution contains a solvent and an electrolyte salt. The solvent contains a cyclic compound having a disulfonic acid anhydride group (—S(═O)2—O—S(═O)2—) and succinonitrile. Compared to a case that the solvent does not contain both the cyclic compound having the disulfonic acid anhydride group and succinonitrile or a case that that the solvent contains at least one thereof, chemical stability of the electrolytic solution is improved. Thus, even if charge and discharge are repeated, electrolytic solution decomposition is inhibited.

摘要翻译： 提供能够改善循环特性的二次电池。 二次电池包括阴极21，阳极22和电解液。 设置在阴极21和阳极22之间的分离器23被电解液浸渍。 电解液含有溶剂和电解质盐。 溶剂含有具有二磺酸酐基团（-S（= O）2-O-S（= O）2 - ））和丁二腈的环状化合物。 与溶剂不含有二磺酸酐基的环状化合物和丁二腈的情况相比，溶剂含有至少一种的情况，电解液的化学稳定性提高。 因此，即使重复进行充放电，也可以抑制电解液分解。

公开(公告)号：US09029021B2

公开(公告)日：2015-05-12

申请号：US12762080

申请日：2010-04-16

申请人： Tadahiko Kubota

发明人： Tadahiko Kubota

IPC分类号： H01M10/0567 ,  H01M4/58 ,  H01M4/66 ,  H01M10/44 ,  H01M10/052 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/04 ,  H01M10/0569 ,  H01M4/02 ,  H01M10/42

CPC分类号： H01M10/052 ,  H01M4/0404 ,  H01M4/0471 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/386 ,  H01M4/661 ,  H01M10/0569 ,  H01M10/44 ,  H01M2004/021 ,  H01M2010/4292 ,  Y02E60/122

摘要： A method of charging and discharging a battery that includes an anode. The anode includes silicon and is capable of inserting and extracting lithium. At the time of charge, the potential of the anode vs. lithium metal as a reference potential is 0.04 V or more. At the time of discharge, the potential of the anode vs. lithium metal as a reference potential is 1.4 V or less.

摘要翻译： 一种对包括阳极的电池进行充电和放电的方法。 阳极包括硅并且能够插入和提取锂。 在充电时，阳极对锂金属作为参考电位的电位为0.04V以上。 在放电时，阳极对锂金属作为参考电位的电位为1.4V以下。