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78 条记录 (耗时 0.046 秒)

    Low-sulfur polysulfide silanes and process for preparation
    51.
    发明授权
    Low-sulfur polysulfide silanes and process for preparation 有权
    低硫多硫硅烷及其制备方法

    公开(公告)号：US06452034B2

    公开(公告)日：2002-09-17

    申请号：US09477394

    申请日：2000-01-04

    申请人： Richard W. Cruse

    发明人： Richard W. Cruse

    IPC分类号： C07F708

    CPC分类号： C07F7/1892 ,  C07F7/1804

    摘要： An improvement on existing methods to desulfurize oligosulfide silanes generates no added raw materials or waste streams in addition to the sodium chloride which is generated as a byproduct in the current manufacturing process for polyusulfide silanes. This is accomplished by using mercaptosilane salts as desulfurizing agents, which yield more product in addition to that already obtained from the desulfurized silane of higher sulfur rank. The process simply entails reacting an oligosulfide silane with a mercaptosilane salt to thereby obtain an oligosulfide silane whose average sulfur rank is less than the starting oligosulfide silane. Coproduct sulfide salts can be recycled back to the oligosulfide manufacturing process. The mercaptosilane salts are novel materials as well.

    摘要翻译： 除了在目前的多硫化硅硅烷的制造过程中作为副产物产生的氯化钠之外，改进现有的硫代硫硅烷脱硫方法不产生添加的原料或废物流。 这是通过使用巯基硅烷盐作为脱硫剂来实现的，除了已经从较高硫等级的脱硫硅烷获得的产物之外，还产生更多的产物。 该方法简单地使寡硫代硅烷与巯基硅烷盐反应，从而获得平均硫等级低于起始的低聚硫硅烷的低硫硅烷。 副产物硫化物盐可以循环回到寡硫化物制造过程中。 巯基硅烷盐也是新型材料。

    Process for the preparation of thiocarboxylate silane
    55.
    发明授权
    Process for the preparation of thiocarboxylate silane 有权
    硫代羧酸硅烷的制备方法

    公开(公告)号：US08008520B2

    公开(公告)日：2011-08-30

    申请号：US10881839

    申请日：2004-06-30

    申请人： Richard W. Cruse ,  Tiberiu L. Simandan

    发明人： Richard W. Cruse ,  Tiberiu L. Simandan

    IPC分类号： C07F7/08

    CPC分类号： C07F7/1892

    摘要： An aqueous process is described in which thiocarboxylate silane is produced from haloalkyl silane by reaction of the haloalkyl silane with an aqueous solution of thiocarboxylate salt. Also described is a process for the preparation of aqueous thiocarboxylate salt from a sulfide and/or hydrosulfide and an acid chloride and/or acid anhydride.

    摘要翻译： 描述了一种水性方法，其中由卤代烷基硅烷与硫代羧酸盐水溶液的反应由卤代烷基硅烷制备硫代羧酸盐硅烷。 还描述了从硫化物和/或氢硫化物和酰氯和/或酸酐制备硫代羧酸盐水溶液的方法。

    Hydrocarbon core polysulfide silane coupling agents for filled elastomer compositions
    57.
    发明授权
    Hydrocarbon core polysulfide silane coupling agents for filled elastomer compositions 有权
    用于填充弹性体组合物的烃芯聚硫硅烷偶联剂

    公开(公告)号：US06359046B1

    公开(公告)日：2002-03-19

    申请号：US09657934

    申请日：2000-09-08

    申请人： Richard W. Cruse

    发明人： Richard W. Cruse

    IPC分类号： C08K334

    CPC分类号： C08K5/548 ,  C07F7/1804 ,  C08L21/00

    摘要： The present invention discloses novel hydrocarbon core polysulfide silanes and methods of preparing the hydrocarbon core polysulfide silanes. Preferably, the silanes of the present invention contain assemblies of a single unit of a hydrolyzable silane group, tethered to one end of a chain of sulfur atoms, and several of these assemblies are bound to a common central hydrophobic core via the other end of the sulfur atoms chain. The hydrocarbon core polysulfide silanes may be incorporated into filled elastomeric compositions providing improved dispersiblity of the filler materials. Mineral fillers may be pre-treated with the hydrocarbon core polysulfide silanes prior to use in elastomeric compositions.

    摘要翻译： 本发明公开了新型烃核聚硫硅烷及其制备方法。 优选地，本发明的硅烷含有与水解性硅烷基团的单一单元的组合，其结合到硫原子链的一端，并且这些组合中的几个通过另一端结合到共同的中心疏水性核心 硫原子链。 烃核心多硫化硅烷可以加入到填充的弹性体组合物中，从而提供填料材料的改进的分散性。 矿物填料可以在用于弹性体组合物之前用烃核心多硫化硅烷预处理。

    TRIVINYLCYCLOHEXANE STEREOISOMERIC COMPOSITIONS AND METHODS FOR PREPARING SAME
    59.
    发明申请
    TRIVINYLCYCLOHEXANE STEREOISOMERIC COMPOSITIONS AND METHODS FOR PREPARING SAME 有权
    TRIVINYLCYCLOHEXANE STEREOISOMERIC COMPOSITIONS AND METHODS FOR PREPARTING SAME

    公开(公告)号：US20130018212A1

    公开(公告)日：2013-01-17

    申请号：US13547703

    申请日：2012-07-12

    申请人： Richard W. Cruse ,  Vivek Khare ,  Jozef Kowalski ,  Wlodzimierz Stanczyk

    发明人： Richard W. Cruse ,  Vivek Khare ,  Jozef Kowalski ,  Wlodzimierz Stanczyk

    IPC分类号： C07C5/29 ,  C07C13/19

    CPC分类号： C07C5/22 ,  C07B2200/07 ,  C07C5/29 ,  C07C2601/14 ,  C07C13/19

    摘要： Disclosed herein is a process for making 1,2,4-trivinylcyclohexane that is enriched in a particular geometric isomer. The process involves the thermal isomerization of 1,5,9-cyclododecatriene at temperature between 400° C. and 600° C. followed by an equilibration of the resultant intermediate in either the gas phase or liquid phase at temperature between 180° C. and 375° C. and at pressures ranging from 0.101 kPa to 1.013 kPa. Also disclosed are 1,2,4-trivinylcyclohexane compositions that are enriched in a particular geometric isomer.

    摘要翻译： 本文公开了一种制备富含特定几何异构体的1,2,4-三乙烯基环己烷的方法。 该方法涉及在400℃和600℃之间的温度下1,5,9-环十二碳三烯的热异构化，然后在180℃和180℃之间的温度下在气相或液相中平衡所得中间体 375℃，压力范围为0.101kPa至1.013kPa。 还公开了富含特定几何异构体的1,2,4-三乙烯基环己烷组合物。

    Hybrid silicon-containing coupling agents for filled elastomer compositions
    60.
    发明授权
    Hybrid silicon-containing coupling agents for filled elastomer compositions 有权
    用于填充弹性体组合物的混合含硅偶联剂

    公开(公告)号：US07629430B2

    公开(公告)日：2009-12-08

    申请号：US11640736

    申请日：2006-12-18

    申请人： Richard W. Cruse

    发明人： Richard W. Cruse

    IPC分类号： C08G77/28

    CPC分类号： C08K5/5415 ,  B60C1/00 ,  C07F7/045 ,  C07F7/1804 ,  C08K5/48 ,  C08K5/549 ,  C08L21/00

    摘要： This invention describes novel chemical compounds whose structures are hybrids between sulfur-containing and non-sulfur-containing silanes wherein the two types of silanes are linked by siloxane bonds. The invention includes methods of preparation for the hybrid silanes as well as their use in filled rubbers as coupling agents. The hybrid silanes described are unique in that a certain amount of water in their preparation leads to superior performance in their intended application, and that they can thus be produced more efficiently and safely than coupling agents currently used in the art, from readily available hydrated raw materials.

    摘要翻译： 本发明描述了新型化合物，其结构是含硫和不含硫的硅烷之间的杂化物，其中两种类型的硅烷通过硅氧烷键连接。 本发明包括制备混合硅烷的方法以及它们在填充橡胶中作为偶联剂的用途。 所描述的混合硅烷是独特的，因为其制备中的一定量的水导致其预期应用中的优异性能，因此可以比现有技术中所用的偶联剂从易得的水合原料 材料