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    Tetrafluoropropene production processes
    52.
    发明授权
    Tetrafluoropropene production processes 有权
    四氟丙烯生产工艺

    公开(公告)号：US07722781B2

    公开(公告)日：2010-05-25

    申请号：US12301070

    申请日：2007-06-22

    申请人： Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

    发明人： Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

    IPC分类号： C09K5/04 ,  C07C17/25

    CPC分类号： B01J37/26 ,  B01J21/04 ,  B01J27/125 ,  C07C17/25 ,  C07C17/386 ,  C07C21/18 ,  C07C19/08

    摘要： A process is disclosed for the manufacture of CF3CF═CH2 and CF3CH═CHF. The process involves dehydrofluorinating CF3CHFCH2F in the presence of a dehydrofluorination catalyst to produce a product mixture comprising CF3CF═CH2 and CF3CH═CHF, and recovering said CF3CF═CH2 and CF3CH═CHF from the product mixture. The present invention also provides a composition comprising (a) the Z-isomer of CF3CH═CHF and (b) HF; wherein the HF is present in an effective amount to form an azeotropic combination with the Z—CF3CH═CHF.

    摘要翻译： 公开了用于制造CF 3CF≡CH2和CF 3 CH = CHF的方法。 该方法包括在脱氟化氢催化剂存在下对CF 3 CHFCH 2 F进行脱氟化氢，以产生包含CF 3CF≡CH2和CF 3 CH = CHF的产物混合物，并从产物混合物中回收所述CF 3CF≡CH2和CF 3 CH = CHF。 本发明还提供了包含（a）CF 3 CH = CHF的Z-异构体和（b）HF的组合物; 其中HF以有效量存在以与Z-CF 3 CH = CHF形成共沸组合。

    AZEOTROPIC COMPOSITIONS COMPRISING FLUORINATED OLEFINS FOR CLEANING APPLICATIONS
    53.
    发明申请
    AZEOTROPIC COMPOSITIONS COMPRISING FLUORINATED OLEFINS FOR CLEANING APPLICATIONS 失效
    包含用于清洁应用的氟化油的AZEOPTRIC组合物

    公开(公告)号：US20100056412A1

    公开(公告)日：2010-03-04

    申请号：US12618907

    申请日：2009-11-16

    申请人： Melodie A. Schweitzer ,  Allen Capron Sievert ,  Joan Ellen Bartelt ,  Barbara Haviland Minor

    发明人： Melodie A. Schweitzer ,  Allen Capron Sievert ,  Joan Ellen Bartelt ,  Barbara Haviland Minor

    IPC分类号： C11D7/50

    CPC分类号： C11D7/5068 ,  C11D7/504 ,  C11D11/0029 ,  C23G5/02803 ,  C23G5/02809

    摘要： The present invention relates to azeotropic or azeotrope-like compositions comprising a fluorinated olefin having the formula E- or Z—C3F7CH═CHC3F7, and at least one alcohol, halocarbon, hydrofluorocarbon, fluoroether, or alkanes and combinations thereof. In one embodiment, the one compound selected from the group consisting of alcohols, halocarbons, fluoroalkyl ethers, hydrofluorocarbons, alkanes is either methanol, ethanol, iso-propanol, n-propanol, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, n-propyl bromide, C4F9OCH3, C4F9OC2H5, HFC-43-10mee, HFC-365mfc, heptane, or combinations thereof. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.

    摘要翻译： 本发明涉及包含具有式E-或Z-C 3 F 7 CH = CHC 3 F 7的氟化烯烃和至少一种醇，卤代烃，氢氟烃，氟醚或其烷烃及其组合的共沸或类共沸组合物。 在一个实施方案中，选自醇，卤代烃，氟代烷基醚，氢氟烃，烷烃的一种化合物是甲醇，乙醇，异丙醇，正丙醇，反式-1,2-二氯乙烯，顺式-1,2 二氯乙烯，正丙基溴，C 4 F 9 OCH 3，C 4 F 9 OC 2 H 5，HFC-43-10mee，HFC-365mfc，庚烷或其组合。 在另一个实施方案中，这些组合物可用于清洁用作脱脂剂或去除剂，用于从表面除去油和/或其它残余物。

    PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3- TETRAFLUOROPROPENE
    54.
    发明申请
    PROCESSES FOR PRODUCING AND COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE AND/OR 1,2,3,3- TETRAFLUOROPROPENE 失效
    包含2,3,3,3-四氢呋喃和/或1,2,3,3-四氢呋喃的生产和组合物的方法

    公开(公告)号：US20100025620A1

    公开(公告)日：2010-02-04

    申请号：US12442952

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Mallikarjuna Nott Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Mallikarjuna Nott Rao ,  Allen Capron Sievert

    IPC分类号： C09K5/00 ,  C07C17/23

    CPC分类号： C07C21/18 ,  C07C17/23 ,  C07C17/25 ,  C07C17/278 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C07C19/10

    摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF═CFCHF2. The process involves contacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a catalyst including a catalytically effective amount of palladium supported on a support of alumina, fluorided alumina and/or aluminum fluoride, to produce a product mixture including CH2═CFCF3 (and when CCl2FCF2CClF2 is present, CHF═CFCHF2); recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture; and optionally, separating at least a portion of any CHF═CFCHF2 in the product mixture from the CH2═CFCF3 in the product mixture. The mole ratio of H2 to the total of CCl3CF2CF3 and CCl2FCF2CClF2 fed to the reaction zone is between about 1:1 and about 5:1. The present invention also provides another process for making CH2═CFCF3 or mixtures thereof with CHF═CFCHF2 This process involves (a) reacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a catalytically effective amount of a hydrogenation catalyst to form CH3CF2CF3 (and when CCl2FCF2CClF2 is present, CH2FCF2CHF2); (b) dehydrofluorinating CH3CF2CF3 and optionally any CH2FCF2CHF2 from (a) to form a product mixture including CH2═CFCF3, and if CH2FCF2CHF2 is present, CHF═CFCHF2; (c) recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture formed in (b); and optionally (d) separating at least a portion of any CHF═CFCHF2 in the product mixture formed in (b) from the CH2═CFCF3 in the product mixture formed in (b).The present invention also provides compositions involving CH2═CFCF3 and/or CHF═CFCHF2, including compositions useful as refrigerants, foam blowing agents, cleaning agents and aerosols and azeotropic compositions involving (a) CF2HCF═CFH and (b) HF.

    摘要翻译： 公开了制备CF 3 CF-CH 2或其与CHF-CFCHF 2的混合物的方法。 该方法包括在催化剂存在下使CCl 3 CF 2 CF 3和任选的CCl 2 CFF 2 CClF 2与H 2接触，所述催化剂包括负载在氧化铝，氟化氧化铝和/或氟化铝的载体上的催化有效量的钯，以产生包含CH 2 -CFCF 3的产物混合物 CCl 2 CFF 2 CClF 2，CHF-CFCHF 2）; 从产物混合物中回收CH2-CFCF3或其与CHF-CFCHF2的混合物; 并且任选地，将产物混合物中的任何CHF-CFCHF 2的至少一部分与产物混合物中的CH 2 -CFCF 3分离。 供给到反应区的H 2与CCl 3 CF 2 CF 3和CCl 2 FCF 2 CClF 2的总量的摩尔比为约1:1至约5:1。 本发明还提供另外一种制备CH2-CFCF3或其与CHF-CFCHF2的混合物的方法。该方法包括（a）在催化有效量的氢化催化剂存在下使CCl 3 CF 2 CF 3和任选的CCl 2 FCF 2 CClF 2与H 2反应以形成CH 3 CF 2 CF 3 CCl 2 FCF 2 CClF 2存在，CH 2 CFF 2 CHF 2）; （b）从（a）中将CH 3 CF 2 CF 3和任选的任何任何CH 2 CFF 2 CHF 3脱氟氟化，形成包含CH2-CFCF3的产物混合物，如果存在CH 2 CF 2 CHF 2，则CHF-CFCHF 2; （c）从（b）中形成的产物混合物中回收CH 2 CFCF 3或其与CHF-CFCHF 2的混合物; 和任选地（d）将（b）中形成的产物混合物中的任何CHF-CFCHF 2的至少一部分与（b）中形成的产物混合物中的CH 2 -CFCF 3分离。 本发明还提供了包含CH 2 -CFCF 3和/或CHF-CFCHF 2的组合物，包括可用作制冷剂的组合物，泡沫发泡剂，清洁剂和气溶胶以及涉及（a）CF 2 HCF-CFH和（b）HF的共沸组合物。

    Azeotropic compositions comprising fluorinated olefins for cleaning applications
    55.
    发明授权
    Azeotropic compositions comprising fluorinated olefins for cleaning applications 失效
    包含用于清洁应用的氟化烯烃的共沸组合物

    公开(公告)号：US07641808B2

    公开(公告)日：2010-01-05

    申请号：US11897086

    申请日：2007-08-29

    申请人： Melodie A. Schweitzer ,  Allen Capron Sievert ,  Joan Ellen Bartelt ,  Barbara Haviland Minor

    发明人： Melodie A. Schweitzer ,  Allen Capron Sievert ,  Joan Ellen Bartelt ,  Barbara Haviland Minor

    IPC分类号： C09K5/04 ,  C11D7/30

    CPC分类号： C11D7/5068 ,  C11D7/504 ,  C11D11/0029 ,  C23G5/02803 ,  C23G5/02809

    摘要： The present invention relates to azeotropic or azeotrope-like compositions comprising a fluorinated olefin having the formula E- or Z-C3F7CH═CHC3F7, and at least one alcohol, halocarbon, hydrofluorocarbon, fluoroether, or alkanes and combinations thereof. In one embodiment, the one compound selected from the group consisting of alcohols, halocarbons, fluoroalkyl ethers, hydrofluorocarbons, alkanes is either methanol, ethanol, iso-propanol, n-propanol, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, n-propyl bromide, C4F9OCH3, C4F9OC2H5, HFC-43-10mee, HFC-365mfc, heptane, or combinations thereof. In another embodiment, these compositions are useful in cleaning applications as a degreasing agent or defluxing agent for removing oils and/or other residues from a surface.

    摘要翻译： 本发明涉及包含具有式E-或Z-C 3 F 7 CH-CHC 3 F 7的氟化烯烃和至少一种醇，卤代烃，氢氟烃，氟代醚或其烷烃及其组合的共沸或类共沸组合物。 在一个实施方案中，选自醇，卤代烃，氟代烷基醚，氢氟烃，烷烃的一种化合物是甲醇，乙醇，异丙醇，正丙醇，反式-1,2-二氯乙烯，顺式-1,2 二氯乙烯，正丙基溴，C 4 F 9 OCH 3，C 4 F 9 OC 2 H 5，HFC-43-10mee，HFC-365mfc，庚烷或其组合。 在另一个实施方案中，这些组合物可用于清洁用作脱脂剂或去除剂，用于从表面除去油和/或其它残余物。

    1,2,3,3,3-PENTAFLUOROPROPENE PRODUCTION PROCESSES
    56.
    发明申请
    1,2,3,3,3-PENTAFLUOROPROPENE PRODUCTION PROCESSES 有权
    1,2,3,3,3-苯甲酮生产工艺

    公开(公告)号：US20090306438A1

    公开(公告)日：2009-12-10

    申请号：US12440046

    申请日：2007-09-05

    申请人： Allen Capron Sievert ,  Mario Joseph Nappa ,  Barry Asher Mahler

    发明人： Allen Capron Sievert ,  Mario Joseph Nappa ,  Barry Asher Mahler

    IPC分类号： C07C17/23

    CPC分类号： C07C17/25 ,  Y02P20/582 ,  C07C21/18

    摘要： The present disclosure relates to a new and efficient manufacturing process for the production of HFC-1225ye. The process involves contacting at least one hexafluoropropane selected from the group consisting of 1,1,1,2,2,3-hexafluoropropane and 1,1,1,2,3,3-hexafluoropropane with a suitable catalyst in a reactor to obtain a product mixture containing HFC-1225ye (1,2,3,3,3-pentafluoropropene) where the pressure in the reactor ranges from about 0.5 psig to about 100 psig.

    摘要翻译： 本公开涉及用于生产HFC-1225ye的新的和有效的制造方法。 该方法包括将至少一种选自1,1,1,2,2,3-六氟丙烷和1,1,1,2,3,3-六氟丙烷的六氟丙烷与合适的催化剂在反应器中接触以获得 含有HFC-1225ye（1,2,3,3,3-五氟丙烯）的产物混合物，其中反应器中的压力为约0.5psig至约100psig。

    Process for the manufacture of halocarbons and selected compounds and azeotropes with HF
    59.
    发明授权
    Process for the manufacture of halocarbons and selected compounds and azeotropes with HF 有权
    用于制造卤代烃和所选化合物以及与HF共沸的方法

    公开(公告)号：US07241928B2

    公开(公告)日：2007-07-10

    申请号：US10956672

    申请日：2004-10-01

    申请人： Velliyur N.Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Velliyur N.Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C19/10 ,  C07C19/01 ,  C07C19/08

    CPC分类号： C07C19/10 ,  C01B7/191 ,  C07C17/206 ,  C07C17/275 ,  C07C17/278 ,  C07C17/38 ,  C07C17/386 ,  C07C19/08 ,  Y02P20/582 ,  C07C19/01 ,  C07C19/16

    摘要： A liquid phase process is disclosed for producing halogenated alkane adducts of the formula CAR1R2CBR3R4 (where A, B, R1, R2, R3, and R4 are as defined in the specification) which involves contacting a corresponding halogenated alkane, AB, with a corresponding olefin, CR1R2═CR3R4 in a dinitrile or cyclic carbonate ester solvent which divides the reaction mixture into two liquid phases and in the presence of a catalyst system containing (i) at least one catalyst selected from monovalent and divalent copper; and optionally (ii) a promoter selected from aromatic or aliphatic heterocyclic compounds which contain at least one carbon-nitrogen double bond in the heterocyclic ring. When hydrochlorofluorocarbons are formed, the chlorine content may be reduced by reacting the hydrochlorofluorocarbons with HF.New compounds disclosed include CF3CF2CCl2CH2CCl3, CF3CCl2CH2CH2Cl and CF3CCl2CH2CHClF. These compounds are useful as intermediates for producing hydrofluorocarbons.Azeotropes of CClF2CH2CF3 with HF and azeotropes of CF3CH2CHF2 with HF are also disclosed; as are process for producing such azeotropes.A process for purification of certain hydrofluorocarbons and/or chloro-precursors thereof from mixtures of such compounds with HF is also disclosed.

    摘要翻译： 公开了一种液相法，用于生产下列化合物的卤化烷烃加合物：其中R 1，R 2，R 2，R 3，R 4， （其中A，B，R 1，R 2，R 3和R 4如在 涉及使相应的卤化烷烃AB与相应的烯烃接触，其中R 1， 在二腈或环状碳酸酯溶剂中，将反应混合物分成两个液相，并且在含有（i）至少一种选自一价和二价铜的催化剂的催化剂体系的存在下， 和任选地（ii）选自在杂环中含有至少一个碳 - 氮双键的芳族或脂族杂环化合物的促进剂。 当形成氢氯氟烃时，可以通过氢氯氟烃与HF反应来降低氯含量。 所公开的新化合物包括CF 3 CO 2 CCl 2，CH 2 CCl 3， CF 3 3 CCl 2 CH 2 CH 2 Cl和CF 3 CCl > 2 还公开了具有HF的SUB> CHF 2 生产这种共沸物的方法也是如此。 还公开了从这种化合物与HF的混合物中纯化某些氢氟烃和/或其氯前体的方法。