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    Fungicidally active 3-substituted 1-azolyl-3-methyl-1-phenoxy-butan-2-ones and -ols
    53.
    发明授权
    Fungicidally active 3-substituted 1-azolyl-3-methyl-1-phenoxy-butan-2-ones and -ols 失效
    杀真菌活性3-取代的1-噻唑基-3-甲基-1-苯氧基 - 丁-2-酮和醇

    公开(公告)号：US4629732A

    公开(公告)日：1986-12-16

    申请号：US600581

    申请日：1984-04-17

    申请人： Udo Kraatz ,  Erich Klauke ,  Gerhard Jager ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    发明人： Udo Kraatz ,  Erich Klauke ,  Gerhard Jager ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    IPC分类号： A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07C323/00 ,  C07D233/56 ,  C07D249/08

    摘要： New 3-substituted 1-azolyl-3-methyl-1-phenoxy-butan-2-ones and -ols of the general formula ##STR1## in which Az represents 1,2,4-triazol-1-yl, 1,2,4-triazol-4-yl or imidazol-1-yl,B represents the keto group or the CH(OH) group,Y represents oxygen or sulphur,R represents halogenoalkyl, optionally substituted phenyl or optionally substituted benzyl, or provided Y represents sulphur, may represent alkyl andX.sup.1, X.sup.2 and X.sup.3 are selected independently and each represent hydrogen, halogen, alkyl, halogenoalkyl, alkoxy, alkylthio, alkylsulphonyl, nitro, cyano, alkoxycarbonyl or optionally substituted phenyl,are obtained if halogenoether ketones are reacted with 1,2,4-triazole or imidazole in the presence of a diluent and of an acid-binding agent, and, if appropriate, the keto derivatives thus obtained are reduced. The compounds, as such or as their acid-addition salts or metal-salt complexes, have fungicidal activity, for example against those fungi which cause powdery mildew diseases or cause rice diseases.

    摘要翻译： 新的3-取代的1-吡唑基-3-甲基-1-苯氧基 - 丁-2-酮和通式为其中的Az表示1,2,4-三唑-1-基的 - 1,2,4-三唑-4-基或咪唑-1-基，B表示酮基或CH（OH）基，Y表示氧或硫，R表示卤代烷基，任选取代的苯基或任选取代的苄基，或 提供Y表示硫，可以代表烷基，X 1，X 2和X 3独立选择，各自代表氢，卤素，烷基，卤代烷基，烷氧基，烷硫基，烷基磺酰基，硝基，氰基，烷氧基羰基或任选取代的苯基， 与1,2,4-三唑或咪唑在稀释剂和酸结合剂的存在下反应，如果合适，则所得到的酮衍生物被还原。 化合物本身或其酸加成盐或金属盐络合物具有杀真菌活性，例如针对引起白粉病或引起水稻病的那些真菌。

    Fungicidal phosphorylated azolyl derivatives
    56.
    发明授权
    Fungicidal phosphorylated azolyl derivatives 失效
    杀真菌性磷酸化唑基衍生物

    公开(公告)号：US4535074A

    公开(公告)日：1985-08-13

    申请号：US593323

    申请日：1984-03-26

    申请人： Reinhard Preuss ,  Hermann Perrey ,  Helmut Ritter ,  Paul Reinecke ,  Wilhelm Brandes

    发明人： Reinhard Preuss ,  Hermann Perrey ,  Helmut Ritter ,  Paul Reinecke ,  Wilhelm Brandes

    IPC分类号： A01N57/32 ,  A01N57/24 ,  C07F9/6506 ,  C07F9/6518 ,  C07F9/65

    CPC分类号： A01N57/24 ,  C07F9/65061 ,  C07F9/65181

    摘要： Fungicidally active novel phosphorylated azolyl derivatives of the formula ##STR1## in which A represents a nitrogen atom or the CH group,R represents optionally substituted phenyl or the grouping ##STR2## wherein X and Y are identical or different and represent hydrogen or halogen,R.sup.1 represents hydrogen andR.sup.2 represents hydrogen, optionally substituted phenoxy or optionally substituted benzyl, orR.sup.1 and R.sup.2 together represent the grouping .dbd.CH--Z, wherein Z represents optionally substituted cycloalkyl or optionally substituted phenyl,R.sup.3 represents alkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.4 represents hydrogen or alkyl andR.sup.5 represents hydrogen or alkyl,or salts or addition products thereof with metal salts.

    摘要翻译： 其中A表示氮原子或CH基团，R表示任选取代的苯基或分组，其中X和Y相同或不同，表示氢或卤素，R1， 表示氢，R 2表示氢，任选取代的苯氧基或任选取代的苄基，或R 1和R 2一起代表基团= CH-Z，其中Z表示任选取代的环烷基或任选取代的苯基，R 3表示烷基，任选取代的苯基或任选取代的苄基 R4代表氢或烷基，R5代表氢或烷基，或其盐或其加成产物与金属盐。